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Er3(Fe, Co, M)29化合物(M=Cr, V, Ti, Mn, Ga, Nb)的结构与磁性

罗鸿志 贾 琳 李养贤 孟凡斌 申 江 陈难先 吴光恒 杨伏明

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Er3(Fe, Co, M)29化合物(M=Cr, V, Ti, Mn, Ga, Nb)的结构与磁性

罗鸿志, 贾 琳, 李养贤, 孟凡斌, 申 江, 陈难先, 吴光恒, 杨伏明

Structure and magnetic properties of Er3(Fe, Co, M)29 compounds (M=Cr, V, Ti, Mn, Ga, Nb)

Luo Hong-Zhi, Jia Lin, Li Yang-Xian, Meng Fan-Bin, Shen Jiang, Chen Nan-Xian, Wu Guang-Heng, Yang Fu-Ming
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  • 合成了Er3Fe29-x-yCoxMy化合物(M=Cr, V, Ti, Mn, Ga, Nb )并用x射线衍射和磁测量等手段研究了它们的结构和磁性. 发现Fe基Er3(Fe,M)29化合物结晶成哑铃对Fe-Fe无序替代的Th2Ni17型结构(P63/mmc空间群)而不能形成Nd3(Fe,Ti)29型结构,因此其化学式也可以用Er2-n(Fe,M)17+2n (n=0.2)表示. 当Er3Fe29化合物中部分Fe原子被M原子所取代时,其居里温度均有一定程度的提高. 所有Er3(Fe,M)29化合物在室温均为易面型各向异性. 当Er3(Fe,M)29 (M=Cr, V)中的部分Fe原子被Co原子取代且Co原子数与Fe原子数达到一定比值时,得到一个单斜结构的新相. 磁测量表明Er3Fe19.5Co6V3.5在室温可能为单轴各向异性,在162K出现自旋重取向,其各向异性由易轴型变为易面型. 在5K下于难磁化方向磁化时观察到一个一级磁化过程(FOMP).
    A series of Er3(Fe, Co, M)29 (M=Cr, V, Ti, Mn, Ga, Nb) compounds has been synthesized and their structure and magnetic properties have been investigates by means of x-ray diffraction and magnetic measurements. It is found that the Fe-based Er3(Fe,M)29 compounds crystallize in the Th2Ni17-type structure with disordered substitution of the dumbbell Fe-Fe, instead of Nd3(Fe,Ti)29-type structure, so its chemical formula can also be expressed as Er2-n(Fe,M)17+2n (n=0.2). Substitution of M for Fe in the Er3Fe29 compound leads to an increase in the Curie temperature. With the substitution of Co for Fe in the Er3(Fe,M)29 (M=Cr, V) compounds, a new phase was found which crystallizes in monoclinic symmetry. The anisotropy of the Er3Fe19.5Co6V3.5 compound at room temperature is of easy-axis type and a spin reorientation transition from the easy-axis type to the easy-plane type anisotropy occurs when temperature decreases to 162K. A first order magnetization process (FOMP) was observed in the HMD magnetization curve of Er3Fe19.5Co6V3.5 at 5K, the critical field of the FOMP was derived to be 3.8T.
    • 基金项目: 国家自然科学基金(批准号:TG2000067106)资助的课题.
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出版历程
  • 收稿日期:  2005-01-20
  • 修回日期:  2005-03-31
  • 刊出日期:  2005-11-20

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