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碳在低碳合金马氏体中微扩散所引起的内耗峰

葛庭燧 马应良

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碳在低碳合金马氏体中微扩散所引起的内耗峰

葛庭燧, 马应良

INTERNAL FRICTION PEAK ASSOCIATED WITH THE STRESSINDUCED DIFFUSION OF CARBON IN LOW-CARBON ALLOY MARTENSITE

KE TING-SUI, MA YING-LIANG
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  • 用扭摆测量淬硬低碳镍合金钢中的内耗,当振动频率约为每秒2周时,在155℃附近有一个内耗峰出现。这个内耗峰的出现条件是:钢中必须含有马氏体、合金元素和碳。在适当的条件下,铬钢和铬镍钢中也曾观察到这个内耗峰。用含镍29.7%的钢作了系统试验,观察到内耗峰高度与试样中的含碳量成正比。内耗峰的高度由于在较高温度(165℃以上)的回火处理而不断降低。由内耗测量所测得的激活能是25,000卡/克分子。以上的实验结果指出,所观测到的155℃新内耗峰是由于碳在合金马氏体中的应力感生微扩散所引起来的。提出了一个产生内耗峰的初步模型。假定碳在四角马氏体中是处于00(1/2)型的间隙位置。合金元素原子的存在引起晶体点阵中不均匀的畸变,因而应力的作用便改变了碳原子在热平衡状态下在Fe-C-Fe和B-C-Fe(B是合金元素原子)两种00(1/2)型间隙位置之间的跳动几率。这种应力感生的碳原子运动便引起内耗。用这个模型可以定性地解释所观测到的事实。关于这方面的定量研究正在进行中。
    Internal friction in hardened low-carbon nickel steel was measured with a torsion pendulum and an internal friction peak was observed around 155℃ with a frequency of vibration of about 2 cycles per second. The condition for the appearance of this internal friction peak is that the steel specimens contain martensite, alloying element and carbon. This internal friction peak has also been observed in chromium steel and chromium-nickel steel under suitable conditions. Systematic observations were made with steel specimens containing 29.7% Ni, and the height of internal friction peak was found to be proportional to the carbon content in the specimen. The experimental results mentioned above show that the new internal friction peak is associated with the stress-induced micro-diffusion of carbon in low-carbon alloy martensite.A preliminary model was suggested in which the carbon is assumed to be at the interstitial positions of 00(1/2) type. The presence of alloying atoms introduces an inhomogeneous distortion in the lattice, consequently the jumping probability of carbon atoms between two types of 00(1/2) interstial positions (Fe-C-Fe and B-C-Fe, where B represents an atom of alloying element) under conditions of thermal equilibrium is altered by the application of stress. Such a stress-induced movement of carbon atoms gives rise to internal friction. This model can explain qualitatively the observed experimental facts. A quantitative study on this subject is in progress.
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  • 文章访问数:  6396
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出版历程
  • 收稿日期:  1956-10-16
  • 刊出日期:  1957-01-20

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