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本文报道用铂丝光热吸收池作为探测器得到了CF3CDCI2的红外多光子吸收谱。并发现在线性吸收谱中944cm-1处的吸收峰在多光子吸收谱中分裂为947cm-1和927cm-1两个吸收峰。这一现象与科里奥利力和非谐性引起的简正振动的耦合作用有关。这样,在用CF3CDCI2/CF3CHCI2体系分离氘同位素时,可以根据这一新结果选择更合适的激发波长。实验还发现在线性吸收谱中986cm-1处的吸收峰在多光子吸收谱中出现约6cm-2的红移。这种红移现象起源于分子振动能级的非谐性。The optothermal spectrum of infrared MPA of CF3CDC12 obtained by using optothermal cell with a platinum filament as a detector is reported here. It is found that the absorption peak at 944 cm-1 in infrared linear absorption spectrum splits into two peaks at 947 cm-1 and 927cm-1 in MPA spectrum. This phenomenon could be related to-the coupling of normal vibrations produced by Coriolis forces and anharmonisity. So one could select a more suitable excited wavelength according to this new result in laser separation of deuterium isotop. The absoption peak at 986 cm-1 in infrared linear absorption spectrum shows a red shift of 6cm-1 in MPA spectrum. This is due to the anhamonicity of vibrational levels of the molecule.
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