Abstract： The population on 6p23P2 metastable state and 6p23P0 ground state of Pb atoms are de-monstrated, which are originated from dissociating PbCl2 by the fourth harmonic of YAG lasers. The population ratio of 3P2 to 3P0 is measured in terms of laser-induced fluorescence. The results indicate that the dissociation of PbCl2 is a two photon process and the population inversion between 3P2 and 3P0 exists. The stimulated Raman radiation based on the population of 3P2 metastable state is observed. The possible way of dissociation is studied.