搜索

x

留言板

尊敬的读者、作者、审稿人, 关于本刊的投稿、审稿、编辑和出版的任何问题, 您可以本页添加留言。我们将尽快给您答复。谢谢您的支持!

姓名
邮箱
手机号码
标题
留言内容
验证码
引用本文:
Citation:

应崇福

ON THE APPROXIMATE PARTITION FUNCTION IN THE STATISTICAL THEORY OF ADSORPTION

C.F.Ying
PDF
导出引用
  • Wang's theory for determining the approximate configurational partition function of the adsorbed layer is modified in two different ways. One is to assume that the configurational energy should be corrected: the other to advocate that the deficiency due to a wrong expression for the a priori probability of the. central site is more significant.The configurational partition function is evaluated is both methods and the adsorptipn isotherin and the beat of adsorption computed for the case of quadratic lattice With dipole interaction. values for the last two quantities when a uniform continuous distribution of the distant adsorbed particles is assumed are further given for comparison. The second method, which surpasses the first, is compared with Kirkwood's method. in the case of hexagonal lattice with neighbour interaction. Numerical work is also carried out in this case.
  • [1]
计量
  • 文章访问数:  5929
  • PDF下载量:  559
  • 被引次数: 0
出版历程
  • 收稿日期:  1944-12-05
  • 刊出日期:  1945-01-20

/

返回文章
返回