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低温燃烧法制备SrMgAl10O17:Eu2+,Er3+高亮度蓝光荧光粉及发光性能研究

刘丹 梁培 王乐 徐国堂 刘阳 李晓艳 董前民 黄杰

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低温燃烧法制备SrMgAl10O17:Eu2+,Er3+高亮度蓝光荧光粉及发光性能研究

刘丹, 梁培, 王乐, 徐国堂, 刘阳, 李晓艳, 董前民, 黄杰

Low-temperature combustion synthesis and luminescent properties of SrMgAl10O17:Eu2+, Er3+ high brightness blue phosphors

Liu Dan, Liang Pei, Wang Le, Xu Guo-Tang, Liu Yang, Li Xiao-Yan, Dong Qian-Min, Huang Jie
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  • 采用低温燃烧法合成SrMgAl10O17:Eu2+及SrMgAl10O17:Eu2+, Er3+蓝色发光材料, 通过X射线衍射仪 (XRD)、扫描电子显微镜 (SEM) 和荧光光谱仪 (PL) 等测试手段对所得样品进行表征. XRD及SEM测试结果表明: 利用低温燃烧法合成SrMgAl10O17材料具有较高的结晶度, 且微量的稀土元素掺杂不会破坏其晶体结构; PL测试结果表明: SrMgAl10O17:Eu2+ 荧光粉在300390 nm范围内可以被有效的激发, 该波长范围与近紫外LED芯片匹配, 发射光谱分布在430520 nm之间, 发射峰位于460 nm, 属蓝光发射材料. 共掺Er3+可显著增强SrMgAl10O17:Eu2+的发光强度, 且当Er3+的掺杂浓度为4%时,样品的发光强度最大, 较单掺Eu2+时样品的发光强度高出54.9%, 表明Er3+对Eu2+的发光具有良好的敏化作用, 该敏化作用的机理可以利用能量传递原理进行解释.
    The SrMgAl10O17:Eu2+ and SrMgAl10O17:Eu2+, Er3+ blue phosphors were synthesized by the combustion synthesis method. Their crystal structures and luminescent properties were analyzed by X-ray diffraction (XRD)、scanning electron microscope (SEM) and photoluminescence spectra, respectively. The XRD and SEM results indicate that the sample is well-crystallized in the combustion procedure, and its crystal structure has not changed when doped with low concentrations of rare-earth ions. PL results show that the phosphor of SrMgAl10O17:Eu2+ can be effectively excited by near UV LED chip with a broad emission spectrum extending from 430 nm to 520 nm, and has main peaks located at 460nm. Furthermore, the sample of the luminous intensity is the largest when the Er2+, Er3+ co-doped concentration is 4%, and the emission intensity of Sr0.95MgAl10O17:0.05Eu2+, Er3+ phosphor is significantly enhanced 54.9% higher than that of SrMgAl10O17:Eu2+ phosphor. It is indicated that Er3+has good sensitization effect for Eu2+ in luminescence, and this can be explained by the theory of energy transfer.
    • 基金项目: 国家自然科学基金青年基金(批准号:61006051,61177050);浙江省自然科学基金(批准号:Y407370,Y1110777)和浙江省重点科技创新团队(批准号:2010R50020)资助的课题.
    • Funds: Project supported by the National Natural Science Foundation of China (Grant Nos. 61006051, 61177050), the Natural Science Foundation of Zhejiang Pvovince, China (Grant Nos. Y407370, Y1110777), and the Key Scientific and Technological Innovation Team of Zhejiang Province, China (Grant No. 2010R50020).
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  • [1]

    Ponce F A, Bour D P 1997 Nature 386 351

    [2]

    Pimputkar S, Speck J S, DenBaars S P, Nakamura S 2009 Nature Photonics 3 180

    [3]

    Morkoc H, Mohammad S N 1995 Science 267 51

    [4]

    Muthu S, Schuurmans F J, Pashley M D 2002 IEEE Journal on Selected Topics in Quantum Electronics 8 333

    [5]

    Xiao D, Kim K, Bedair S, Zavada J 2004 Appl. Phys. Lett. 84 672

    [6]

    Hirosaki N, Xie R J, Kimoto K, Sekiguchi T, Yamamoto Y, Suehiro T, Mitomo M 2005 Appl. Phys. Lett. 86 211905

    [7]

    Ho Ryu J, Park Y G, Won H S, Suzuki H, Kim S H, Yoon C 2008 J. Ceram. Soc. Jpn. 11 6389

    [8]

    Onuma H, Tanno H, Suzuki A, Sahnoun R, Koyama M, Tsuboi H, Hatakeyama N, Endou A, Takaba H, Carpio C A 2010 J. Soc. Inf. display 18 211

    [9]

    Wanjun T, Donghua C, Ming W 2009 Optics & Laser Technology 41 81

    [10]

    Ju G, Hu Y, Chen L, Wang X 2012 J. Lumin. 132 1792

    [11]

    Mahakhode J, Dhoble S, Joshi C, Moharil S 2007 J. Alloys Compd. 438 293

    [12]

    Manjunathaa C, Sunitha D V, Nagabhushana H, Nagabhushana B M, Sharma S C, Chakradhar R P S 2012 Spectrochim. Acta Part. A 93 140

    [13]

    Ekambaram S, Maaza M 2005 J. Alloys Compd. 395 132

    [14]

    Singh V, Gundu Rao T, Zhu J J 2008 J. Lumin. 128 583

    [15]

    You Y 2010 M. E Dissertation (Wuhan: Huazhong University of Science and Technology) (in Chinese) [游燕 2010 硕士学位论文 (武汉: 华中科技大学)]

    [16]

    Song G H, Liao J W, Jiang B, Ji X M, Cui Y P 2011 Journal of Optoelectronics. Laser. 22 17791783 (in Chinese) [宋国华, 廖建文, 姜斌, 纪宪明, 崔一平 2011 光电子·激光 22 17791783]

    [17]

    Cao S X, Han T, Tu M J 2011 Acta Phys. Sin. 60 127802 (in Chinese) [曹仕秀, 韩涛, 涂铭旌 2011 物理学报 60 127802]

    [18]

    Wu Y, Shi C S 1994 chinese rare earths 15 37 (in Chinese) [吴郢, 石春山 1994 稀土 15 37]

    [19]

    Hong G Y 2011 Rare earth luminescent materials-basic and applied (beijing: Science Press) p200 (in Chinese) [洪广言 2011 稀土发光材料-基础与应用 (北京: 科学出版社) 第200页]

    [20]

    Ryu H, Bartwal K S 2008 Physica B: Condensed Matter 403 3195

    [21]

    Bartwal K S, Ryu H, Brik M G, Sildos I 2009 J. Phys. D: Appl. Phys. 42 245401

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出版历程
  • 收稿日期:  2013-05-08
  • 修回日期:  2013-06-29
  • 刊出日期:  2013-10-05

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