金属塑料的研究进展

张博; 汪卫华

doi:10.7498/aps.66.176411

摘要

金属塑料是我国学者发现和命名的新材料.本文重点阐述金属塑料这类材料是如何发现的以及这类材料的设计思想与规则；总结了从金属塑料材料成分、典型材料的微观结构与物理化学特性等方面的最新研究成果；对于金属塑料类材料的潜在应用前景做了展望与分析.

关键词:

Metallic plastic, named and developed by Chinese scientists, is a kind of new material. Here in this paper we explain how this material was discovered and its design philosophy and principle. The chemical compositions, micro-structures, and typical physical and chemical properties of these metallic plastic materials are summarized in this paper. The potential applications of the metallic plastic materials are also analyzed.

Keywords:

作者及机构信息

张博¹,
汪卫华²

1.
合肥工业大学材料科学与工程学院, 合肥 230009;

2.
中科院物理研究所, 北京 100190

通信作者: 张博, bo.zhang@hfut.edu.cn;whw@aphy.iphy.ac.cn ; 汪卫华, bo.zhang@hfut.edu.cn;whw@aphy.iphy.ac.cn

基金项目: 国家重点基础研究发展计划（批准号：2015CB856800）、国家重点研发计划重点专项（批准号：2016YFB0300500）、国家自然科学基金（批准号：51322103，51571079）和中央高校基本科研业务费（批准号：JZ2016HGPB0671）资助的课题.

Authors and contacts

Zhang Bo¹,
Wang Wei-Hua²

1.
School of Materials Science and Engineering, Hefei University of Technology, Hefei 230009, China;

2.
Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China

Corresponding author: Zhang Bo, bo.zhang@hfut.edu.cn;whw@aphy.iphy.ac.cn ; Wang Wei-Hua, bo.zhang@hfut.edu.cn;whw@aphy.iphy.ac.cn

Funds: Project supported by the National Basic Research Program of China (Grant No. 2015CB856800), the National Key Research and Development Project, China (Grant No. 2016YFB0300500), the National Natural Science Foundation of China (Grant Nos. 51322103, 51571079), and the Fundamental Research Funds for the Central Universities, China (Grant No. JZ2016HGPB0671).

参考文献

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[2]	Zhou C D 1994 Sci. Technol. Rev. 12 27 (in Chinese) [周传典 1994 科技导报 12 27]
[3]	Zhang H M 1989 History Research in Anhui 2 14 (in Chinese) [张宏明 1989 安徽史学 2 14]
[4]	Wang D Z, Yao G C 2009 Engineer. Sci. 4 9 (in Chinese) [王淀佐, 姚国成 2009 中国工程科学 4 9]
[5]	Zhao J W, Chen X W, Shi Y L, Zhang Q 2009 China Metalform. Equip. Manufact. Technol. 44 23 (in Chinese) [赵俊伟, 陈学文, 史宇麟, 张琪 2009 锻压装备与制造技术 44 23]
[6]	Pan Z R 1997 Polymer Chemistry (Beijing Chemical Industry Press) (in Chinese) [潘祖仁 1997 高分子化学 (北京: 化学工业出版社)]
[7]	He P S, Zhu P P, Yang H Y 2006 Chem. Bull. 69 154 (in Chinese) [何平笙, 朱平平, 杨海洋 2006 化学通报 69 154]
[8]	Zhang B, Zhao D Q, Pan M X, Wang W H, Greer A 2005 Phys. Rev. Lett. 94 205502
[9]	Ressmeyer R, Images G 2005 Nature 435 717
[10]	Castelvecchi D 2005 Phys. Rev. Focus 15 20
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[12]	Klement W, Willens R, Duwez P 1960 Nature 187 869
[13]	Inoue A, Zhang T, Tsai A P, Masumoto T 1989 Mater. Trans. JIM 30 378
[14]	Peter A, Johnson W L 1993 Appl. Phys. Lett. 63 2342
[15]	Inoue A, Zhang T, Masumoto T 1990 Mater. Trans. JIM 31 177
[16]	Inoue A 1995 Mater. Trans. JIM 36 866
[17]	Lin X H, Johnson W L 1995 J. Appl. Phys. 78 6514
[18]	Inoue A, Gook J S 1995 Mater. Trans. Japan. Inst. Metals 36 1180
[19]	Kim S G, Inoue A, Masumoto T 1990 Mater. Trans. JIM 31 929
[20]	Inoue A, Shen B L, Chang C T 2004 Acta Mater. 52 4093
[21]	Shen B L, Inoue A, Chang C T 2004 Appl. Phys. Lett. 85 4911
[22]	Zhao Z F, Zhao D Q, Pan M X, Wang W H 2003 Appl. Phys. Lett. 82 4699
[23]	Li S, Zhao D Q, Pan M X, Wang W H 2005 J. Non-Cryst. Solids 351 2568
[24]	Huo J T, Zhao D Q, Bai H Y, Axinte E, Wang W H 2008 J. Non-Crys. Solids 359 1
[25]	Li S, Wang R J, Pan M X, Zhao D Q, Wang W H 2006 Intermetallics 14 592
[26]	Li S, Wang R J, Pan M X, Zhao D Q, Wang W H 2008 J. Non-Cryst. Solids 354 1080
[27]	Tang M B, Zhao D Q, Pan M X, Wang W H 2004 Chin. Phys. Lett. 21 901
[28]	Meng D, Yi J, Zhao D Q, Ding D W, Bai H Y, Pan M X, Wang W H 2011 J. Non-Cryst. Solids 357 1787
[29]	Wang J Q, Qin J Y, Gu X N, Zheng Y F, Bai H Y 2011 J. Non-Cryst. Solids 357 1232
[30]	Wang W H 2013 Prog. Phys. 33 177 (in Chinese) [汪卫华 2013 物理学进展 33 177]
[31]	Nishiyama N, Inoue A 2007 MRS Bull. 32 651
[32]	Saotome Y, Miwa S, Zhang T, Inoue A 2001 J. Mater. Proc. Tech. 113 64
[33]	Zhang B, Wang W H 2007 Chin. Sci. Bull. 52 1477 (in Chinese) [张博, 汪卫华 2007 科学通报 52 1477]
[34]	Xi X K, Zhao D Q, Pan M X, Wang W H 2004 J. Non-Cryst. Solids 344 89
[35]	Zheng Q, Cheng S, Strader J H, Mab E, Xua J 2007 Scripta Mater. 56 161
[36]	Liu Z Q, Li R, Liu G, Su W H, Wang H, Li Y, Shi M J, Luo X K, Wu G J, Zhang T 2012 Acta Mater. 60 3128
[37]	Xu D, Duan G, Johnson W L 2004 Phys. Rev. Lett. 92 245504
[38]	Inoue A, Zhang T, Takeuchi A. 1997 Appl. Phys. Lett. 71 464
[39]	Cheney J, Khalifa H 2009 Mater. Sci. Eng. A 506 94
[40]	Sun B A, Pan M X, Zhao D Q, Wang W H, Xi X K, Sandor M T, Wu Y 2008 Scripta Mater. 59 1159
[41]	Liu L, Inoue A, Zhang T 2005 Mater. Trans. 46 376
[42]	Dun C, Liu H, Shen B 2012 J. Non-Cryst. Solids 358 3060
[43]	Wang J F, Li R, Hua N B, Zhang T 2011 J. Mater. Res. 26 2072
[44]	Wang W H, Dong C, Shek C H 2004 Mater. Sci. Eng. R 44 45
[45]	Zhang Z, Wang R J, Pan M X, Wang W H 2003 J. Phys.: Condens. Matter 15 4503
[46]	Liu X F, Wang R J, Zhao D Q, Pan M X, Wang W H 2007 Appl. Phys. Lett. 91 041901
[47]	Zhao K, Liu K S, Li J F, Wang W H, Jiang L 2009 Scripta. Mater. 60 225
[48]	Wang J Q, Wang W H, Bai H Y 2009 Appl. Phys. Lett. 94 041910
[49]	Zhao K, Li J F, Zhao D Q, Pan M X, Wang W H 2009 Scripta Mater. 61 1091
[50]	Jiao W, Zhao K, Xi X K, Zhao D Q, Pan M X, Wang W H 2010 J. Non-Cryst. Solids 356 1867
[51]	Xu B C, Xue R J, Zhang B 2013 Intermetallics 32 1
[52]	Zhang B, Zhao D Q, Pan M X, Wang R J, Wang W H 2006 Acta Mater. 54 3025
[53]	Zhang B, R J, Wang Zhao D Q, Pan M X, Wang W H 2006 Phys. Rev. B 73 092201
[54]	Zhang B, Zhao D Q, Pan M X, Wang R J, Wang W H 2006 J. Non-Cryst. Solids 352 5687
[55]	Zhou Y, Zhao Y, Qu B Y, Wang L, Zhou R L, Zhang B 2014 Intermetallics 56 56
[56]	Gebert A, Eckert J, Schultz L 1998 Acta Mater. 46 5475
[57]	Guo F Q, Wang H, Poon S J, Shiflet G J 2005 Appl. Phys. Lett. 86 091907
[58]	Lu Z P, Liu C T, Thompson J R, Porter W D 2004 Phys. Rev. Lett. 92 245503
[59]	Xi X K, Li L L, Zhang B, Wang W H, Wu Y 2007 Phys. Rev. Lett. 99 095501
[60]	Zhao Y, Li D D, Qu B Y, Zhou R L, Zhang B, Sato K 2017 Intermetallics 84 25
[61]	Singh D, Basu S, Mandal R K, Srivastava O N, Tiwari R S 2015 Intermetallics 67 87
[62]	Singh D, Singh D, Srivastava O N, Tiwari R S 2016 Scripta. Mater. 118 24
[63]	Tang M B, Bai H Y, Wang W H, Bogdanov D, Winzer K, Samwer K, Egami T 2007 Phys. Rev. B 74 172201
[64]	Zhang B, Wang W J, Wang W H 2005 Phys. Rev. B 72 104205
[65]	Sheng H W, Liu H Z, Cheng Y Q, Wen J, Lee P L, Luo W K, Shastri S D, Ma E 2007 Nature Mater. 6 192
[66]	Zeng Q S, Li Y C, Feng C M, Liermann P, Somayazulu M, Shen G Y, Mao H K, Yang R, Liu J, Hu T D, Jiang J Z 2007 Proc. Natl. Acad. Sci. USA 104 13565
[67]	Zeng Q S, Ding Y, Mao W L, Yang W G, Sinogeikin S V, Shu J F, Mao H K, Jiang J Z 2010 Phys. Rev. Lett. 104 105702
[68]	Zeng Q S, Fang Y Z, Lou H B, Gong Y, Wang X D, Yang K, Li A G, Yan S, Lathe C, Wu F M, Yu X H, Jiang J Z 2010 J. Phys.: Condens. Matter 22 375404
[69]	Duarte M J, Bruna P, Pineda E, Crespo D, Garbarino G, Verbeni R, Zhao K, Wang W H, Romero A H, Serrano J 2011 Phys. Rev. B 84 224116
[70]	Decremps F, Morard G, Garbarino G, Casula M 2016 Phys. Rev. B 93 054209
[71]	Wang Y Y, Dong X, Song X H, Wang J F, Li G, Liu R P 2016 Mater. Lett. 162 203
[72]	Yavari A R 2007 Nature Mater. 6 181
[73]	Chu J P, Chiang C L, Wijaya H, Huang R T, Wu C W, Zhang B, Wang W H, Nieh T G 2006 Scripta Mater. 55 227
[74]	Kumar G, Tang H X, Schroers J 2009 Nature 457 868
[75]	Zhang B, Liu R T, Xu J J, Chen Y, Li Z, Wang M Y, Zhong L X 2016 China Patent 201510203536.8 (in Chinese) [张博, 刘任涛, 徐俊杰, 陈阳, 李正, 王明扬, 钟浪翔 2016 中国专利 CN 201510203536.8]

施引文献

[1]	He T K 2013 Studies in the History of Natural Sciences 16 273 (in Chinese) [何堂坤 2013 自然科学史研究 16 273]
[2]	Zhou C D 1994 Sci. Technol. Rev. 12 27 (in Chinese) [周传典 1994 科技导报 12 27]
[3]	Zhang H M 1989 History Research in Anhui 2 14 (in Chinese) [张宏明 1989 安徽史学 2 14]
[4]	Wang D Z, Yao G C 2009 Engineer. Sci. 4 9 (in Chinese) [王淀佐, 姚国成 2009 中国工程科学 4 9]
[5]	Zhao J W, Chen X W, Shi Y L, Zhang Q 2009 China Metalform. Equip. Manufact. Technol. 44 23 (in Chinese) [赵俊伟, 陈学文, 史宇麟, 张琪 2009 锻压装备与制造技术 44 23]
[6]	Pan Z R 1997 Polymer Chemistry (Beijing Chemical Industry Press) (in Chinese) [潘祖仁 1997 高分子化学 (北京: 化学工业出版社)]
[7]	He P S, Zhu P P, Yang H Y 2006 Chem. Bull. 69 154 (in Chinese) [何平笙, 朱平平, 杨海洋 2006 化学通报 69 154]
[8]	Zhang B, Zhao D Q, Pan M X, Wang W H, Greer A 2005 Phys. Rev. Lett. 94 205502
[9]	Ressmeyer R, Images G 2005 Nature 435 717
[10]	Castelvecchi D 2005 Phys. Rev. Focus 15 20
[11]	Zhang B, Zhao D Q, Pan M X, Wang W H 2006 Physics 35 91 (in Chinese) [张博, 赵德乾, 潘明祥, 汪卫华 2006 物理 35 91]
[12]	Klement W, Willens R, Duwez P 1960 Nature 187 869
[13]	Inoue A, Zhang T, Tsai A P, Masumoto T 1989 Mater. Trans. JIM 30 378
[14]	Peter A, Johnson W L 1993 Appl. Phys. Lett. 63 2342
[15]	Inoue A, Zhang T, Masumoto T 1990 Mater. Trans. JIM 31 177
[16]	Inoue A 1995 Mater. Trans. JIM 36 866
[17]	Lin X H, Johnson W L 1995 J. Appl. Phys. 78 6514
[18]	Inoue A, Gook J S 1995 Mater. Trans. Japan. Inst. Metals 36 1180
[19]	Kim S G, Inoue A, Masumoto T 1990 Mater. Trans. JIM 31 929
[20]	Inoue A, Shen B L, Chang C T 2004 Acta Mater. 52 4093
[21]	Shen B L, Inoue A, Chang C T 2004 Appl. Phys. Lett. 85 4911
[22]	Zhao Z F, Zhao D Q, Pan M X, Wang W H 2003 Appl. Phys. Lett. 82 4699
[23]	Li S, Zhao D Q, Pan M X, Wang W H 2005 J. Non-Cryst. Solids 351 2568
[24]	Huo J T, Zhao D Q, Bai H Y, Axinte E, Wang W H 2008 J. Non-Crys. Solids 359 1
[25]	Li S, Wang R J, Pan M X, Zhao D Q, Wang W H 2006 Intermetallics 14 592
[26]	Li S, Wang R J, Pan M X, Zhao D Q, Wang W H 2008 J. Non-Cryst. Solids 354 1080
[27]	Tang M B, Zhao D Q, Pan M X, Wang W H 2004 Chin. Phys. Lett. 21 901
[28]	Meng D, Yi J, Zhao D Q, Ding D W, Bai H Y, Pan M X, Wang W H 2011 J. Non-Cryst. Solids 357 1787
[29]	Wang J Q, Qin J Y, Gu X N, Zheng Y F, Bai H Y 2011 J. Non-Cryst. Solids 357 1232
[30]	Wang W H 2013 Prog. Phys. 33 177 (in Chinese) [汪卫华 2013 物理学进展 33 177]
[31]	Nishiyama N, Inoue A 2007 MRS Bull. 32 651
[32]	Saotome Y, Miwa S, Zhang T, Inoue A 2001 J. Mater. Proc. Tech. 113 64
[33]	Zhang B, Wang W H 2007 Chin. Sci. Bull. 52 1477 (in Chinese) [张博, 汪卫华 2007 科学通报 52 1477]
[34]	Xi X K, Zhao D Q, Pan M X, Wang W H 2004 J. Non-Cryst. Solids 344 89
[35]	Zheng Q, Cheng S, Strader J H, Mab E, Xua J 2007 Scripta Mater. 56 161
[36]	Liu Z Q, Li R, Liu G, Su W H, Wang H, Li Y, Shi M J, Luo X K, Wu G J, Zhang T 2012 Acta Mater. 60 3128
[37]	Xu D, Duan G, Johnson W L 2004 Phys. Rev. Lett. 92 245504
[38]	Inoue A, Zhang T, Takeuchi A. 1997 Appl. Phys. Lett. 71 464
[39]	Cheney J, Khalifa H 2009 Mater. Sci. Eng. A 506 94
[40]	Sun B A, Pan M X, Zhao D Q, Wang W H, Xi X K, Sandor M T, Wu Y 2008 Scripta Mater. 59 1159
[41]	Liu L, Inoue A, Zhang T 2005 Mater. Trans. 46 376
[42]	Dun C, Liu H, Shen B 2012 J. Non-Cryst. Solids 358 3060
[43]	Wang J F, Li R, Hua N B, Zhang T 2011 J. Mater. Res. 26 2072
[44]	Wang W H, Dong C, Shek C H 2004 Mater. Sci. Eng. R 44 45
[45]	Zhang Z, Wang R J, Pan M X, Wang W H 2003 J. Phys.: Condens. Matter 15 4503
[46]	Liu X F, Wang R J, Zhao D Q, Pan M X, Wang W H 2007 Appl. Phys. Lett. 91 041901
[47]	Zhao K, Liu K S, Li J F, Wang W H, Jiang L 2009 Scripta. Mater. 60 225
[48]	Wang J Q, Wang W H, Bai H Y 2009 Appl. Phys. Lett. 94 041910
[49]	Zhao K, Li J F, Zhao D Q, Pan M X, Wang W H 2009 Scripta Mater. 61 1091
[50]	Jiao W, Zhao K, Xi X K, Zhao D Q, Pan M X, Wang W H 2010 J. Non-Cryst. Solids 356 1867
[51]	Xu B C, Xue R J, Zhang B 2013 Intermetallics 32 1
[52]	Zhang B, Zhao D Q, Pan M X, Wang R J, Wang W H 2006 Acta Mater. 54 3025
[53]	Zhang B, R J, Wang Zhao D Q, Pan M X, Wang W H 2006 Phys. Rev. B 73 092201
[54]	Zhang B, Zhao D Q, Pan M X, Wang R J, Wang W H 2006 J. Non-Cryst. Solids 352 5687
[55]	Zhou Y, Zhao Y, Qu B Y, Wang L, Zhou R L, Zhang B 2014 Intermetallics 56 56
[56]	Gebert A, Eckert J, Schultz L 1998 Acta Mater. 46 5475
[57]	Guo F Q, Wang H, Poon S J, Shiflet G J 2005 Appl. Phys. Lett. 86 091907
[58]	Lu Z P, Liu C T, Thompson J R, Porter W D 2004 Phys. Rev. Lett. 92 245503
[59]	Xi X K, Li L L, Zhang B, Wang W H, Wu Y 2007 Phys. Rev. Lett. 99 095501
[60]	Zhao Y, Li D D, Qu B Y, Zhou R L, Zhang B, Sato K 2017 Intermetallics 84 25
[61]	Singh D, Basu S, Mandal R K, Srivastava O N, Tiwari R S 2015 Intermetallics 67 87
[62]	Singh D, Singh D, Srivastava O N, Tiwari R S 2016 Scripta. Mater. 118 24
[63]	Tang M B, Bai H Y, Wang W H, Bogdanov D, Winzer K, Samwer K, Egami T 2007 Phys. Rev. B 74 172201
[64]	Zhang B, Wang W J, Wang W H 2005 Phys. Rev. B 72 104205
[65]	Sheng H W, Liu H Z, Cheng Y Q, Wen J, Lee P L, Luo W K, Shastri S D, Ma E 2007 Nature Mater. 6 192
[66]	Zeng Q S, Li Y C, Feng C M, Liermann P, Somayazulu M, Shen G Y, Mao H K, Yang R, Liu J, Hu T D, Jiang J Z 2007 Proc. Natl. Acad. Sci. USA 104 13565
[67]	Zeng Q S, Ding Y, Mao W L, Yang W G, Sinogeikin S V, Shu J F, Mao H K, Jiang J Z 2010 Phys. Rev. Lett. 104 105702
[68]	Zeng Q S, Fang Y Z, Lou H B, Gong Y, Wang X D, Yang K, Li A G, Yan S, Lathe C, Wu F M, Yu X H, Jiang J Z 2010 J. Phys.: Condens. Matter 22 375404
[69]	Duarte M J, Bruna P, Pineda E, Crespo D, Garbarino G, Verbeni R, Zhao K, Wang W H, Romero A H, Serrano J 2011 Phys. Rev. B 84 224116
[70]	Decremps F, Morard G, Garbarino G, Casula M 2016 Phys. Rev. B 93 054209
[71]	Wang Y Y, Dong X, Song X H, Wang J F, Li G, Liu R P 2016 Mater. Lett. 162 203
[72]	Yavari A R 2007 Nature Mater. 6 181
[73]	Chu J P, Chiang C L, Wijaya H, Huang R T, Wu C W, Zhang B, Wang W H, Nieh T G 2006 Scripta Mater. 55 227
[74]	Kumar G, Tang H X, Schroers J 2009 Nature 457 868
[75]	Zhang B, Liu R T, Xu J J, Chen Y, Li Z, Wang M Y, Zhong L X 2016 China Patent 201510203536.8 (in Chinese) [张博, 刘任涛, 徐俊杰, 陈阳, 李正, 王明扬, 钟浪翔 2016 中国专利 CN 201510203536.8]

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