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The bond breaking at high excitation of the HCN molecule with various couplings is studied along with Morse oscillator by the coset (phase) space method of Lie algebra. It is demonstrated that the couplings of higher orders, are prone to bo nd dissociation. We also note that couplings reduce the dissociation energy.
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Keywords:
- highly excited vibrational states /
- resonance /
- dissociation
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