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Effect of temperature on the (100) surface features of type Ib and type IIa large single crystal diamonds

Zhang He Li Shang-Sheng Su Tai-Chao Hu Mei-Hua Zhou You-Mo Fan Hao-Tian Gong Chun-Sheng Jia Xiao-Peng Ma Hong-An Xiao Hong-Yu

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Effect of temperature on the (100) surface features of type Ib and type IIa large single crystal diamonds

Zhang He, Li Shang-Sheng, Su Tai-Chao, Hu Mei-Hua, Zhou You-Mo, Fan Hao-Tian, Gong Chun-Sheng, Jia Xiao-Peng, Ma Hong-An, Xiao Hong-Yu
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  • In this paper, by choosing FeNiMnCo alloy as a catalyst and the (100) face of a seed crystal as the growth face, high quality type Ib and type IIa large diamond single crystals (diameter about 3-4 mm) can be successfully synthesized using temperature gradient method, at 5.6 GPa pressure and different temperatures between 1250-1340 ℃. To control the diamond crystal morphology, the growth temperature should be adjusted. Then the morphology of the synthesized large diamonds is plate-like at low temperatures, tower-like at medium temperatures, and spire tower-like at high temperatures. For the same crystal morphology, the synthetic temperature of type IIa diamond single crystals is about 30 ℃ higher than that of type Ib. The central and angularity regions of the top (100) surface, for the synthesized samples of type Ib and type IIa large diamond single crystals at different temperatures, are examined by laser Raman microscope respectively. It is found that the black lines of the type Ib and type IIa large diamond single crystals become dimmed and dense on the same top surface from center to the edge. It is indicated that the priority growth mechanism is in the angularity regions, compared with the central regions. Namely the solute of carbon is primarily precipitated in the angularity regions of the (100) surface. With increasing synthesis temperature, the black lines on the top surface (100) of type Ib diamond single crystals become gradually denser, and the characteristics of the lines are transformed from irregular distribution to typical dendritic distribution. The reason of the above results is that the rate of carbon deposition (the growth rate of diamond crystal), which is along the direction of the diamond crystal [100], will gradually rise as the synthesis temperature of the crystal is increased. The characteristics of the lines on the top surfaces (100) of type IIa large diamond single crystals, which are synthesized under different temperatures, are similar to that of type Ib. However, the lines on the top (100) surface of type IIa diamonds are not so obvious and denser than that of type Ib diamonds at different synthesis temperatures. Similar characteristics of lines on the top (100) surface of both types of diamond single crystals can be explained by the axis and radial growth rate variation at different temperatures. These different characteristics of the lines are due to the fact that the growth rate of type IIa diamonds is slower than that of type Ib diamonds, and the nitrogen concentrations in type IIa diamonds are lower than those of type Ib diamonds. Finally, the full width at half maximum (5.554 cm-1) of the tower-like type IIa diamond is narrower than that (5.842 cm-1) of tower-like type Ib diamond from the test of Raman spectra. It is shown that the quality of type IIa diamond single crystals is better than that of type Ib.
      Corresponding author: Li Shang-Sheng, lishsh@hpu.edu.cn
    • Funds: Project supported by the Open Project of State Key Laboratory of Superhard Materials (Jilin University), China (Grant No. 201203), the Education Department of Henan Province, China (Grant Nos. 12A430010, 13A140792), the Opening Project of Henan Key Discipline Open Laboratory of Mining Engineering Materials, China (Grant No. KLMEM 2014-15), and the Program for Innovative Research Team of Henan Polytechnic University, China (Grant No. T2013-4).
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    Sumiya H, Toda N, Satoh S 1971 J. Phys. Chem. 75 1838

    [2]

    Strong H M, Chrenko R M 1971 J. Phys. Chem. 75 1838

    [3]

    Sumiya H, Toda N, Satoh S 2002 Journal of Crystal Growth 237-239 1281

    [4]

    Sumiya H, Toda N, Nishibayashi Y, Satoh S 1997 Journal of Crystal Growth 178 485

    [5]

    Li Y, Jia X P, Shi W, Leng S L, Ma H A, Sun S S, Wang F b, Chen N, Long Y 2014 In. Journal of Refractory Metals and Hard Materials 43 147

    [6]

    Li S S, Ma H A, Li X L, Su T C, Huang G F, Li Y, Jia X P 2011 Chin. Phys. B 20 028103

    [7]

    Hu M H, Li S S, Ma H A, Su T C, Li X L, Hu Q, Jia X P 2012 Chin. Phys. B 21 098101

    [8]

    Li S S, Li X L, Ma H A, Su T C, Xiao H Y, Huang G F, Li Y, Zhang Y S, Jia X P 2011 Chin. Phys. Lett. 28 068101

    [9]

    Qin J M, Zhang Y, Cao J M, Tian L F 2011 Acta Phys. Sin. 60 058102(in Chinese) [秦杰明, 张莹, 曹建明, 田立飞 2011 物理学报 60 058102]

    [10]

    Liang Z Z, Liang J Q, Zheng N, Jia X P, Li G J 2009 Acta Phys. Sin. 58 8039(in Chinese) [梁中翥, 梁静秋, 郑娜, 贾晓鹏, 李桂菊 2009 物理学报 58 8039]

    [11]

    Yang Z J, Li H Z, Zhou Y Z, Wang X Y, Luo F 2015 In. Journal of Refractory Metals and Hard Materials 48 61

    [12]

    Hu M H, Bi N, Li S S, Su T C, Hu Q, Jia X P, Ma H A 2015 In. Journal of Refractory Metals and Hard Materials 48 61

    [13]

    Yan B M, Jia X P, Sun S S, Zhou Z X, Chao F, Chen N, Li Y D, Li Y, Ma H A, Wang F b, Chen N, Long Y 2015 In. Journal of Refractory Metals and Hard Materials 48 56

    [14]

    Xiao H Y, Li S S, Qin Y K, Liang Z Z, Zhang Y S, Zhang D M, Zhang Y S 2014 Acta Phys. Sin. 63 198101(in Chinese) [肖宏宇, 李尚升, 秦玉琨, 梁中翥, 张永胜, 张冬梅, 张义顺 2014 物理学报 63 198101]

    [15]

    Kanda H, Ohsawa, T, Fukunaga, O, Sunagawa, I 1989 Journal of Crystal Growth 94 115

    [16]

    Kanda H, Ohsawa T 1996 Diamond and Related Materials 5 8

    [17]

    Zang C Y, Huang G F, Ma H A, Jia X P 2007 Chin. Phys. Lett. 24 2991

    [18]

    Zang C Y, Chen K, Hu Q, Huang G F, Chen X Z, Jia X P 2009 Journal of Synthetic Crystals 38 677(in Chinese) [臧传义, 陈奎, 胡强, 黄国锋, 陈孝洲, 贾晓鹏 2009 人工晶体学报 38 677]

  • [1]

    Sumiya H, Toda N, Satoh S 1971 J. Phys. Chem. 75 1838

    [2]

    Strong H M, Chrenko R M 1971 J. Phys. Chem. 75 1838

    [3]

    Sumiya H, Toda N, Satoh S 2002 Journal of Crystal Growth 237-239 1281

    [4]

    Sumiya H, Toda N, Nishibayashi Y, Satoh S 1997 Journal of Crystal Growth 178 485

    [5]

    Li Y, Jia X P, Shi W, Leng S L, Ma H A, Sun S S, Wang F b, Chen N, Long Y 2014 In. Journal of Refractory Metals and Hard Materials 43 147

    [6]

    Li S S, Ma H A, Li X L, Su T C, Huang G F, Li Y, Jia X P 2011 Chin. Phys. B 20 028103

    [7]

    Hu M H, Li S S, Ma H A, Su T C, Li X L, Hu Q, Jia X P 2012 Chin. Phys. B 21 098101

    [8]

    Li S S, Li X L, Ma H A, Su T C, Xiao H Y, Huang G F, Li Y, Zhang Y S, Jia X P 2011 Chin. Phys. Lett. 28 068101

    [9]

    Qin J M, Zhang Y, Cao J M, Tian L F 2011 Acta Phys. Sin. 60 058102(in Chinese) [秦杰明, 张莹, 曹建明, 田立飞 2011 物理学报 60 058102]

    [10]

    Liang Z Z, Liang J Q, Zheng N, Jia X P, Li G J 2009 Acta Phys. Sin. 58 8039(in Chinese) [梁中翥, 梁静秋, 郑娜, 贾晓鹏, 李桂菊 2009 物理学报 58 8039]

    [11]

    Yang Z J, Li H Z, Zhou Y Z, Wang X Y, Luo F 2015 In. Journal of Refractory Metals and Hard Materials 48 61

    [12]

    Hu M H, Bi N, Li S S, Su T C, Hu Q, Jia X P, Ma H A 2015 In. Journal of Refractory Metals and Hard Materials 48 61

    [13]

    Yan B M, Jia X P, Sun S S, Zhou Z X, Chao F, Chen N, Li Y D, Li Y, Ma H A, Wang F b, Chen N, Long Y 2015 In. Journal of Refractory Metals and Hard Materials 48 56

    [14]

    Xiao H Y, Li S S, Qin Y K, Liang Z Z, Zhang Y S, Zhang D M, Zhang Y S 2014 Acta Phys. Sin. 63 198101(in Chinese) [肖宏宇, 李尚升, 秦玉琨, 梁中翥, 张永胜, 张冬梅, 张义顺 2014 物理学报 63 198101]

    [15]

    Kanda H, Ohsawa, T, Fukunaga, O, Sunagawa, I 1989 Journal of Crystal Growth 94 115

    [16]

    Kanda H, Ohsawa T 1996 Diamond and Related Materials 5 8

    [17]

    Zang C Y, Huang G F, Ma H A, Jia X P 2007 Chin. Phys. Lett. 24 2991

    [18]

    Zang C Y, Chen K, Hu Q, Huang G F, Chen X Z, Jia X P 2009 Journal of Synthetic Crystals 38 677(in Chinese) [臧传义, 陈奎, 胡强, 黄国锋, 陈孝洲, 贾晓鹏 2009 人工晶体学报 38 677]

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Publishing process
  • Received Date:  08 May 2015
  • Accepted Date:  23 June 2015
  • Published Online:  05 October 2015

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