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中国物理学会期刊

纳米TiO2多孔膜的微结构对染料敏化纳米薄膜太阳电池性能的影响

CSTR: 32037.14.aps.54.1914

Influence of microstructure of nanoporous TiO22 films on the perfor mance of dye-sensitized solar cells

CSTR: 32037.14.aps.54.1914
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  • 采用溶胶-凝胶方法,在不同的实验条件下获得平均粒径从15到25nm左右的纳米TiO22颗粒.利用这些颗粒制备出的纳米多孔薄膜,应用于染料敏化纳米薄膜太阳电池. 通过x射线 衍射仪分析,得到TiO22颗粒的晶相以及晶粒度大小,用透射电子显微镜观察 了纳米TiO22颗粒的形貌和尺寸.应用于太阳电池的纳米TiO22多 孔膜,经基于布朗诺尔-埃米特-泰 勒(BET)的多层吸附理论的比表面积测试和孔径分布测试,获得了多孔膜的微

     

    Nanosized TiO22 particles are prepared by sol-gel method, the avera ge size of which varies from 15 to 23nm. These nanoporous TiO22 films are ap plied to d ye-sensitized solar cell modules. The x-ray diffraction patterns are used to d etermine the phase and average nanocrystalline size of TiO22. The sh ape and pa rticles size of the crystal TiO22 are shown by transmission electron microscop e. The conditions of nanoporous films microstructure in solar cells are measured by testing the BET surface and the microscopy of titania films. The photovoltai c performance of dye-sensitized solar cell modules with the size of 15cm×20 cm (the active area is 187.2cm22) is discussed, at the same ti me, the eff ect of nanoporous TiO22 films microstructure and average particles s ize of nan ocrystalline TiO22 on dye-sensitized nanosized films solar cells is investigated in this paper.

     

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