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中国物理学会期刊

纳秒激光诱导C60分子碎裂中轻碎片离子C+n(n<30)的产生机理研究

CSTR: 32037.14.aps.57.5810

Formation mechanisms of small fragment ions in nanosecond laser induced fragmentation of C60

CSTR: 32037.14.aps.57.5810
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  • 采用飞行时间质谱计测量了纳秒激光诱导C60分子碎裂中轻碎片离子C+n(n≤11)的初始平均动能,结果显示轻碎片离子具有相同的初始平均动能(约为0.34eV),并且该动能在一定范围内不随激光通量的变化而明显改变.结合前人的实验结果,对纳秒激光诱导C60分子碎裂中轻碎片离子C+n(n<30)的主要产生模式作了新的阐述,即C<

     

    The time of flight mass spectrometric technique was used to determine the initial mean kinetic energy of small fragment ions C+n (n≤11) produced from C60 excited by 532nm nanosecond laser pulses. The measured kinetic energy shows little variation with the fragment mass and the laser fluence in a broad range. Based on the assumption that C+30 is produced predominantly by a single electron emission followed by successive C2 evaporation from hot C60 in the nanosecond laser field,the formation of small fragments is interpreted as the complete breakup of the unstable C+30 cage structure. The interpretation is consistent with the previously observed results.

     

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