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中国物理学会期刊

源于团簇-共振模型的理想金属玻璃电子化学势均衡

CSTR: 32037.14.aps.61.036402

Electrochemical potential equilibrium of electrons in ideal metallic glasses based on the cluster-resonance model

CSTR: 32037.14.aps.61.036402
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  • 理想金属玻璃是指完全满足电子结构稳定性的金属玻璃. 在我们前期工作中提出的团簇加连接原子及理想金属玻璃的团簇-共振结构模型的 基础上, 本文指出理想金属玻璃应该满足电子化学势均衡判据, 可定量给出团簇与连接原子的比例, 最终确定了理想金属玻璃成分式团簇(连接原子)x. 运用此判据, 解析了Cu-Zr基和Co-B基块体金属玻璃, 实验确定的最佳形成能力成分满足电子化学势均衡.

     

    Ideal metallic glasses are the metallic glasses that satisfy electronic structure stability. Previously we have developed a so-calledcluster-plus-glue-atom modeland more recently acluster-resonance modelfor the ideal metallic glasses. Good metallic glass forming compositions always satisfy simple cluster formulas cluster (glue atoms), with x denoting the number of glue atoms matching one cluster. In this paper we present an electrochemical potential equilibrium criterion based on these models to obtain the number of glue atoms. By examples of Cu-Zr and Co-B bulk metallic glasses, it is confirmed that the experimentally determined good BMG-forming compositions well agree with the calculated composition formulas.

     

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