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通过研究HOCl分子高激发振动态的动力学势, 明确了该体系的动力学特点. 研究表明, 在OCl伸缩模式和HOCl弯曲模式间存在2:1 Fermi共振的动力学模型下, HO伸缩振动模式对于上述两种振动模式的动力学势有显著影响, 且这种影响随Polyad数呈现有规律的变化. 作为定量研究, 还研究了Polyad数为24时该分子体系的动力学势与各能级的相空间轨迹. 分析表明, 相空间轨迹与动力学势中的动力学不动点有很好的对应关系. 此外, 将该Polyad数下的动力学势中的能级按照相空间轨迹的作用量积分进行分类, 明确了这些能级所处的量子环境.
[1] Leu M T 1988 Geophys. Res. Lett. 15 17
[2] Jost R, Joyeux M, Skokov S, Bowman J 1999 J. Chem. Phys. 1116807
[3] Peterson K A, Skokov S, Bowman J M 1999 J. Chem. Phys. 1117446
[4] Joyeux M, Sugny D, Lombardi M, Jost R, Schinke R, Skokov S,Bowman J 2000 J. Chem. Phys. 113 9610
[5] Weiss J, Hauschildt J, Grebenshchikov S Y, Duren R, Schinke R,Koput J, Stamatiadis S, Farantos S C 2000 J. Chem. Phys. 112 77
[6] Joyeux M, Grebenshchikov S Y, Bredenbeck J, Schinke R , FarantosS C 2005 Geometric Structures of Phase Space in MultidimensionalChaos: a special volume of advances in Chemical Physics,part A, 130 chapter 5
[7] Zheng D S, Wu G Z 2002 Acta Phys. Sin. 51 2229 (in Chinese)[郑敦胜, 吴国祯 2002 物理学报 51 2229
[8] Zheng D S, Guo X K 2004 Acta Phys. Sin. 53 3347 (in Chinese)[郑敦胜, 郭锡坤 2004 物理学报 53 3347
[9] Fang C, Wu G Z 2009 J. Mol. Struct.: Theo. Chem. 910 147
[10] Fang C, Wu G Z 2009 Chin. Phys. B 18 0130
[11] Fang C, Wu G Z 2010 Chin. Phys. B 19 010509
[12] Fang C, Wu G Z 2010 Chin. Phys. B 19 110513
[13] Zhang W M , Feng D H , Gilmore, R 1990 Rev. Modern Phys. 62867
[14] Gilmore R 1974 Lie Algebras and Some of Their Applications(New York: Wiley)
[15] Biczysko M, Tarroni R 2002 Phys. Chem. Chem. Phys. 4 708
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[1] Leu M T 1988 Geophys. Res. Lett. 15 17
[2] Jost R, Joyeux M, Skokov S, Bowman J 1999 J. Chem. Phys. 1116807
[3] Peterson K A, Skokov S, Bowman J M 1999 J. Chem. Phys. 1117446
[4] Joyeux M, Sugny D, Lombardi M, Jost R, Schinke R, Skokov S,Bowman J 2000 J. Chem. Phys. 113 9610
[5] Weiss J, Hauschildt J, Grebenshchikov S Y, Duren R, Schinke R,Koput J, Stamatiadis S, Farantos S C 2000 J. Chem. Phys. 112 77
[6] Joyeux M, Grebenshchikov S Y, Bredenbeck J, Schinke R , FarantosS C 2005 Geometric Structures of Phase Space in MultidimensionalChaos: a special volume of advances in Chemical Physics,part A, 130 chapter 5
[7] Zheng D S, Wu G Z 2002 Acta Phys. Sin. 51 2229 (in Chinese)[郑敦胜, 吴国祯 2002 物理学报 51 2229
[8] Zheng D S, Guo X K 2004 Acta Phys. Sin. 53 3347 (in Chinese)[郑敦胜, 郭锡坤 2004 物理学报 53 3347
[9] Fang C, Wu G Z 2009 J. Mol. Struct.: Theo. Chem. 910 147
[10] Fang C, Wu G Z 2009 Chin. Phys. B 18 0130
[11] Fang C, Wu G Z 2010 Chin. Phys. B 19 010509
[12] Fang C, Wu G Z 2010 Chin. Phys. B 19 110513
[13] Zhang W M , Feng D H , Gilmore, R 1990 Rev. Modern Phys. 62867
[14] Gilmore R 1974 Lie Algebras and Some of Their Applications(New York: Wiley)
[15] Biczysko M, Tarroni R 2002 Phys. Chem. Chem. Phys. 4 708
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