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控制纳米结构以调控氧化锌的发光、磁性和细胞毒性

章建辉 韩季刚

控制纳米结构以调控氧化锌的发光、磁性和细胞毒性

章建辉, 韩季刚
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  • 氧化锌(ZnO) 纳米材料因其在UV 激光器、发光二极管、太阳能电池、稀磁半导体、生物荧光标示、靶向药物等领域中的广泛应用而成为最热门的研究课题之一. 调节和优化ZnO 纳米结构的性质是ZnO 的实际应用迫切所需. 在此, 通过发展聚乙烯吡咯烷酮导向结晶法、微波加热强制水解法、表面活性剂后处理法, 成功地制备出了尺寸、表面电荷或成分可调的球、半球、棒、管、T 型管、三脚架、片、齿轮、两层、多层、带盖罐子、碗等一系列ZnO 纳米结构. 通过简单地改变ZnO 纳米粒子的尺寸、形貌和表面电荷或成分, 有效地调控ZnO 本身的发光强度和位置, 并近90 倍地增强了荧光素染料的荧光强度; 诱使了强度可调的室温铁磁性; 实现了对ZnO纳米颗粒的细胞毒性的系统性调控.
    • 基金项目: 国家重点基础研究发展计划(批准号:2012CB932304)、新世纪人才项目和自然科学基金地区项目(批准号:61264008)资助的课题.
    [1]

    Fierro J L G 2006 Metal Oxides: Chemistry & Applications (Boca Raton: Taylor & Francis Group) p182

    [2]

    Özgr , Alivov Ya I, Liu C, Teke A, Reshchikov M A, Doan S, Avrutin V, Cho S J 2005 J. Appl. Phys. 98 041301

    [3]

    Rossler U 1999 Landolt-Bornstein, New Series, Group III (Heidelberg: Springer) p41B

    [4]

    Klingshirn C F, Meyer B K, Waag A, Hoffmann A, Geurts J M M 2010 Zinc Oxide: From Fundamental Properties Towards Novel Applications (Springer) p9

    [5]

    Zhang J, Liu H, Wang Z, Ming N, Li Z, Biris A S 2007 Adv. Funct. Mater. 17 3897

    [6]

    Escudero R, Escamilla R 2011 Solid State Commun. 151 97

    [7]

    Zhang J, Liu H, Wang Z, Ming N 2008 J. Crystal Growth 310 2848

    [8]

    Zhang J, Liu H, Wang Z, Ming N 2007 Appl. Phys. Lett. 90 113117

    [9]

    Zhang J, Thurber A, Tenne D A, Rasmussen J W, Wingett D, Hanna C, Punnoose A 2010 Adv. Funct. Mater. 20 4358

    [10]

    Thurber A T, Beausoleil G L, Alanko G A, Anghel J J, Jones M S, Johnson L M, Zhang J, Hanna C B, Tenne D A, Punnoose A 2011 J. Appl. Phys. 109 07C305

    [11]

    Zhang J, Xiong S, Wu X, Thurber A, Jones M, Gu M, Pan Z, Tenne D A, Hanna C B, Du Y, Punnoose A 2013 Phys. Rev. B 88 085437

    [12]

    Zhang J, Dong G, Thurber A, Hou Y, Gu M, Tenne D A, Hanna C B, Punnoose A 2012 Adv. Mater. 24 1232

    [13]

    Hanley C, Thurber A, Hanna C, Punnoose A, Zhang J, Wingett D G 2009 Nanoscale Res. Lett. 4 1409

    [14]

    Thurber A, Wingett D G, Rasmussen J, Layne J, Johnson L, Tenne D A, Zhang J, Hanna C B, Punnoose A 2012 Nanotoxicology 6 440

    [15]

    Zhang J, Dong G, Thurber A, Hou Y, Tenne D A, Hanna C B, Gu M, Pan Z, Wang K, Du Y, Punnoose A 2014 Particle & Particle Systems Characterization, DOI: 10.1002/ppsc.201400188

    [16]

    Joo J, Kwon S G, Yu J H, Hyeon T 2005 Adv. Mater. 17 1873

    [17]

    Lao J Y, Wen J G, Ren Z F 2002 Nano Lett. 2 1287

    [18]

    Pradhan D, Su Z, Sindhwani S, Honek J F, Leung K T 2011 J. Phys. Chem. C 115 18149

    [19]

    Choy J H, Jang E S, Won J H, Chung J H, Jang D J, Kim Y W 2004 Appl. Phys. Lett. 84 287

    [20]

    Li F, Ding Y, Gao P, Xin X, Wang Z L 2004 Angew. Chem. Int. Ed. 43 5238

    [21]

    Ghosh M, Raychaudhuri A K 2008 Nanotechnology 19 445704

    [22]

    Norberg N S, Gamelin D R 2005 J. Phys. Chem. B 109 20810

    [23]

    Wang X, Summers C J, Wang Z L 2004 Nano Lett. 4 423

    [24]

    Huang M H, Mao S, Feick H, Yan H, Wu Y, Kind H, Webber E, Russo R, Yang P 2001 Science 292 1897

    [25]

    Park W I, Yi G C, Kim J W, Park S M 2003 Appl. Phys. Lett. 82 4358

    [26]

    Rensmo H, Keis K, Lindström H, Södergren S, Solbrand A, Hagfeldt A, Lindquist S E, Wang L N, Muhammed M 1997 J. Phys. Chem. B 101 2598

    [27]

    Song J, Zhou J, Wang Z L 2006 Nano Lett. 6 1656

    [28]

    Tian Z R, Voigt J A, Mckenzie B, Mcdermott M J 2002 J. Am. Chem. Soc. 124 12954

    [29]

    Degen A, Kosec M 2000 J. Eur. Ceram. Soc. 20 667

    [30]

    Xie R, Li D, Zhang H, Yang D, Jiang M, Sekiguchi T, Liu B, Bando Y 2006 J. Phys. Chem. B 110 19147

    [31]

    Das S C, Green R J, Podder J, Regier T Z, Chang G S, Moewes A 2013 J. Phys. Chem. C 117 12745

    [32]

    Richters J P, Voss T, Wischmeier L, Rckmann I, Gutowski J 2008 Appl. Phys. Lett. 92 011103

    [33]

    Helms V 2008 Principles of Computational Cell Biology (Weinheim: Wiley-VCH) p202

    [34]

    Liu E Z, Jiang J Z 2009 J. Phys. Chem. C 113 16116

    [35]

    Deng S, Loh K P, Yi J B, Ding J, Tan H R, Lin M, Foo Y L, Zheng M, Sow C H 2008 Appl. Phys. Lett. 93 193111

    [36]

    Yazaki Y, Suda M, Kameyama N, Einaga Y 2010 Chem. Lett. 39 594595

    [37]

    Ortega D, Chen S J, Suzuki K, Garitaonandia J S 2012 J. Appl. Phys. 111 07C314

    [38]

    Liu E Z, Jiang J Z 2009 J. Phys. Chem. C 113 16116

    [39]

    Xie R, Li D, Zhang H, Yang D, Jiang M, Sekiguchi T, Liu B, Bando Y 2006 J. Phys. Chem. B 110 19147

  • [1]

    Fierro J L G 2006 Metal Oxides: Chemistry & Applications (Boca Raton: Taylor & Francis Group) p182

    [2]

    Özgr , Alivov Ya I, Liu C, Teke A, Reshchikov M A, Doan S, Avrutin V, Cho S J 2005 J. Appl. Phys. 98 041301

    [3]

    Rossler U 1999 Landolt-Bornstein, New Series, Group III (Heidelberg: Springer) p41B

    [4]

    Klingshirn C F, Meyer B K, Waag A, Hoffmann A, Geurts J M M 2010 Zinc Oxide: From Fundamental Properties Towards Novel Applications (Springer) p9

    [5]

    Zhang J, Liu H, Wang Z, Ming N, Li Z, Biris A S 2007 Adv. Funct. Mater. 17 3897

    [6]

    Escudero R, Escamilla R 2011 Solid State Commun. 151 97

    [7]

    Zhang J, Liu H, Wang Z, Ming N 2008 J. Crystal Growth 310 2848

    [8]

    Zhang J, Liu H, Wang Z, Ming N 2007 Appl. Phys. Lett. 90 113117

    [9]

    Zhang J, Thurber A, Tenne D A, Rasmussen J W, Wingett D, Hanna C, Punnoose A 2010 Adv. Funct. Mater. 20 4358

    [10]

    Thurber A T, Beausoleil G L, Alanko G A, Anghel J J, Jones M S, Johnson L M, Zhang J, Hanna C B, Tenne D A, Punnoose A 2011 J. Appl. Phys. 109 07C305

    [11]

    Zhang J, Xiong S, Wu X, Thurber A, Jones M, Gu M, Pan Z, Tenne D A, Hanna C B, Du Y, Punnoose A 2013 Phys. Rev. B 88 085437

    [12]

    Zhang J, Dong G, Thurber A, Hou Y, Gu M, Tenne D A, Hanna C B, Punnoose A 2012 Adv. Mater. 24 1232

    [13]

    Hanley C, Thurber A, Hanna C, Punnoose A, Zhang J, Wingett D G 2009 Nanoscale Res. Lett. 4 1409

    [14]

    Thurber A, Wingett D G, Rasmussen J, Layne J, Johnson L, Tenne D A, Zhang J, Hanna C B, Punnoose A 2012 Nanotoxicology 6 440

    [15]

    Zhang J, Dong G, Thurber A, Hou Y, Tenne D A, Hanna C B, Gu M, Pan Z, Wang K, Du Y, Punnoose A 2014 Particle & Particle Systems Characterization, DOI: 10.1002/ppsc.201400188

    [16]

    Joo J, Kwon S G, Yu J H, Hyeon T 2005 Adv. Mater. 17 1873

    [17]

    Lao J Y, Wen J G, Ren Z F 2002 Nano Lett. 2 1287

    [18]

    Pradhan D, Su Z, Sindhwani S, Honek J F, Leung K T 2011 J. Phys. Chem. C 115 18149

    [19]

    Choy J H, Jang E S, Won J H, Chung J H, Jang D J, Kim Y W 2004 Appl. Phys. Lett. 84 287

    [20]

    Li F, Ding Y, Gao P, Xin X, Wang Z L 2004 Angew. Chem. Int. Ed. 43 5238

    [21]

    Ghosh M, Raychaudhuri A K 2008 Nanotechnology 19 445704

    [22]

    Norberg N S, Gamelin D R 2005 J. Phys. Chem. B 109 20810

    [23]

    Wang X, Summers C J, Wang Z L 2004 Nano Lett. 4 423

    [24]

    Huang M H, Mao S, Feick H, Yan H, Wu Y, Kind H, Webber E, Russo R, Yang P 2001 Science 292 1897

    [25]

    Park W I, Yi G C, Kim J W, Park S M 2003 Appl. Phys. Lett. 82 4358

    [26]

    Rensmo H, Keis K, Lindström H, Södergren S, Solbrand A, Hagfeldt A, Lindquist S E, Wang L N, Muhammed M 1997 J. Phys. Chem. B 101 2598

    [27]

    Song J, Zhou J, Wang Z L 2006 Nano Lett. 6 1656

    [28]

    Tian Z R, Voigt J A, Mckenzie B, Mcdermott M J 2002 J. Am. Chem. Soc. 124 12954

    [29]

    Degen A, Kosec M 2000 J. Eur. Ceram. Soc. 20 667

    [30]

    Xie R, Li D, Zhang H, Yang D, Jiang M, Sekiguchi T, Liu B, Bando Y 2006 J. Phys. Chem. B 110 19147

    [31]

    Das S C, Green R J, Podder J, Regier T Z, Chang G S, Moewes A 2013 J. Phys. Chem. C 117 12745

    [32]

    Richters J P, Voss T, Wischmeier L, Rckmann I, Gutowski J 2008 Appl. Phys. Lett. 92 011103

    [33]

    Helms V 2008 Principles of Computational Cell Biology (Weinheim: Wiley-VCH) p202

    [34]

    Liu E Z, Jiang J Z 2009 J. Phys. Chem. C 113 16116

    [35]

    Deng S, Loh K P, Yi J B, Ding J, Tan H R, Lin M, Foo Y L, Zheng M, Sow C H 2008 Appl. Phys. Lett. 93 193111

    [36]

    Yazaki Y, Suda M, Kameyama N, Einaga Y 2010 Chem. Lett. 39 594595

    [37]

    Ortega D, Chen S J, Suzuki K, Garitaonandia J S 2012 J. Appl. Phys. 111 07C314

    [38]

    Liu E Z, Jiang J Z 2009 J. Phys. Chem. C 113 16116

    [39]

    Xie R, Li D, Zhang H, Yang D, Jiang M, Sekiguchi T, Liu B, Bando Y 2006 J. Phys. Chem. B 110 19147

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出版历程
  • 收稿日期:  2015-03-16
  • 修回日期:  2015-04-23
  • 刊出日期:  2015-05-05

控制纳米结构以调控氧化锌的发光、磁性和细胞毒性

  • 1. 南京大学物理学院, 固体微结构物理国家重点实验室, 南京 210093
    基金项目: 

    国家重点基础研究发展计划(批准号:2012CB932304)、新世纪人才项目和自然科学基金地区项目(批准号:61264008)资助的课题.

摘要: 氧化锌(ZnO) 纳米材料因其在UV 激光器、发光二极管、太阳能电池、稀磁半导体、生物荧光标示、靶向药物等领域中的广泛应用而成为最热门的研究课题之一. 调节和优化ZnO 纳米结构的性质是ZnO 的实际应用迫切所需. 在此, 通过发展聚乙烯吡咯烷酮导向结晶法、微波加热强制水解法、表面活性剂后处理法, 成功地制备出了尺寸、表面电荷或成分可调的球、半球、棒、管、T 型管、三脚架、片、齿轮、两层、多层、带盖罐子、碗等一系列ZnO 纳米结构. 通过简单地改变ZnO 纳米粒子的尺寸、形貌和表面电荷或成分, 有效地调控ZnO 本身的发光强度和位置, 并近90 倍地增强了荧光素染料的荧光强度; 诱使了强度可调的室温铁磁性; 实现了对ZnO纳米颗粒的细胞毒性的系统性调控.

English Abstract

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