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激发态电荷转移有机体的多铁性研究

袁国亮 李爽 任申强 刘俊明

激发态电荷转移有机体的多铁性研究

袁国亮, 李爽, 任申强, 刘俊明
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  • 随着人们对多铁性的深入了解,越来越多不同类型的有机多铁材料被合成出来.激发态电荷转移有机体的电荷转移网络是由一个提供电子的分子(给体donor,D+)和一个接受电子的分子(受体acceptor,A-)有序排列后构成的.D+A-长程有序排列,其激发态(激子)具有较长寿命和1/2自旋,这是产生室温铁电性和铁磁性的根本原因.激发态容易受外场刺激,因此光照、磁场、电场、应力等能够很好地调控这类材料的铁电极化、磁矩和相应的磁电耦合系数.激发态电荷转移有机体不仅大大丰富了室温多铁材料体系,而且可以为开发新型多功能电子器件提供材料基础和技术储备.
      通信作者: 袁国亮, yuanguoliang@njust.edu.cn;liujm@nju.edu.cn ; 刘俊明, yuanguoliang@njust.edu.cn;liujm@nju.edu.cn
    • 基金项目: 国家自然科学基金(批准号:51790492,51431006,51472118)和中央高校基本科研业务费专项资金(批准号:30916011104)资助的课题.
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  • [1]

    Gao W X, Brennan R, Hu Y, Wuttig M, Yuan G L, Quandt E, Ren S Q 2018 Mater. Today (In Press) DOI: 101016/j.mattod.201801032

    [2]

    Astrov D 1960 Sov. Phys. JETP 11 708

    [3]

    Dzyaloshinskii I E 1960 Sov. Phys. JETP 10 628

    [4]

    Greve H, Woltermann E, Quenzer H J, Wagner B, Quandt E 2010 Appl. Phys. Lett. 96 182501

    [5]

    Fiebig M 2005 J. Phys. D: Appl. Phys. 38 R123

    [6]

    Martins P, Lanceros-Mendez S 2013 Adv. Funct. Mater. 23 3371

    [7]

    Zavaliche F, Zhao T, Zheng H, Straub F, Cruz M P, Yang P L, Hao D, Ramesh R 2007 Nano Lett. 7 1586

    [8]

    Chou C C, Taran S, Her J L, Sun C P, Huang C L, Sakurai H, Belik A A, Takayama-Muromachi E, Yang H D 2008 Phys. Rev. B 78 092404

    [9]

    Wang J, Neaton J B, Zheng H, Nagarajan V, Ogale S B, Liu B, Viehland D, Vaithyanathan V, Schlom D G, Waghmare U V 2003 Science 34 1719

    [10]

    Ratcliff W, Lynn J W, Kiryukhin V, Jain P, Fitzsimmons M R 2016 npj Quantum Mater. 1 16003

    [11]

    Liu J M, Nan C W 2014 Physics 43 88 (in Chinese) [刘俊明, 南策文 2014 物理 43 88]

    [12]

    Wang F, Shen S P, Sun Y 2016 Chin. Phys. B 25 087503

    [13]

    Kimura T, Goto T, Shintani H, Ishizaka K, Arima T, Tokura Y 2003 Nature 426 55

    [14]

    Al Qahtani M S, Alshammari M S, Blythe H J, Fox A M, Gehring G A, Andreev N, Chichkov V, Mukovskii Y 2012 J. Phys.: Conf. Ser. 391 012083

    [15]

    Arkenbout A H, Palstra T T M, Siegrist T, Kimura T 2006 Phys. Rev. B 74 184431

    [16]

    Lawes G, Kenzelmann M, Rogado N, Kim K H, Jorge G A, Cava R J, Aharony A, Entin-Wohlman O, Harris A B, Yildirim T, Huang Q Z, Park S, Broholm C, Ramirez A P 2004 Phys. Rev. Lett. 93 247201

    [17]

    Wang K F, Liu J M, Ren Z F 2009 Adv. Phys. 58 321

    [18]

    Cheong S W, Talbayev D, Kiryukhin V, Saxena A 2018 npj Quantum Mater. 3 19

    [19]

    Sergienko I A, Dagotto E 2006 Phys. Rev. B 73 094434

    [20]

    Hur N, Jeong I K, Hundley M F, Kim S B, Cheong S W 2009 Phys. Rev. B 79 134120

    [21]

    Bukhari S H, Ahmad J 2017 Chin. Phys. B 26 018103

    [22]

    Choi T, Horibe Y, Yi H T, Choi Y J, Wu W D, Cheong S W 2010 Nat. Mater. 9 253

    [23]

    Chatterji T, Ouladdiaf B, Henry P F, Bhattacharya D 2012 J. Phys.: Condens. Matter 24 336003

    [24]

    Zheng H, Wang J, Lofland S E, Ma Z, Mohaddes-Ardabili L, Zhao T, Salamanca-Riba L, Shinde S R, Ogale S B, Bai F 2004 Science 303 661

    [25]

    Pato-Doldan B, Gomez-Aguirre L C, Bermudez-Garcia J M, Sanchez-Andujar M, Fondado A, Mira J, Castro-Garcia S, Senaris-Rodriguez M A 2013 RSC Adv. 3 22404

    [26]

    Xu G C, Zhang W, Ma X M, Chen Y H, Zhang L, Cai H L, Wang Z M, Xiong R G, Gao S 2011 J. Am. Chem. Soc. 133 14948

    [27]

    Fu D W, Zhang W, Cai H L, Zhang Y, Ge J Z, Xiong R G, Huang S D, Nakamura T 2011 Angew. Chem. Int. Ed. Engl. 50 11947

    [28]

    Jain P, Stroppa A, Nabok D, Marino A, Rubano A, Paparo D, Matsubara M, Nakotte H, Fiebig M, Picozzi S, Choi E S, Cheetham A K, Draxl C, Dalal N S, Zapf V S 2016 npj Quantum Mater. 1 16012

    [29]

    Tian Y, Cong J Z, Shen S P, Chai Y S, Yan L Q, Wang S G, Sun Y 2014 Phys. Status Solidi RRL 8 91

    [30]

    Tian Y, Stroppa A, Chai Y S, Yan L Q, Wang S G, Barone P, Picozzi S, Sun Y 2014 Sci. Rep. 4 6062

    [31]

    Tian Y, Wang W, Chai Y S, Cong J Z, Shen S P, Yan L Q, Wang S G, Han X F, Sun Y 2014 Phys. Rev. Lett. 112 017202

    [32]

    Tayi A S, Shveyd A K, Sue A C, Szarko J M, Rolczynski B S, Cao D, Kennedy T J, Sarjeant A A, Stern C L, Paxton W F 2012 Nature 488 485

    [33]

    Wang Y, Liu J L, Tran H D, Mecklenburg M, Guan X N, Stieg A Z, Regan B C, Martin D C, Kaner R B 2012 J. Am. Chem. Soc. 134 9251

    [34]

    Zhang Z L, Li H S, Luo Z P, Chang S Q, Li Z, Guan M M, Zhou Z Y, Liu M, Grossman J C, Ren S Q 2017 Chem. Mater. 29 9851

    [35]

    Qin W, Jasion D, Chen X M, Wuttig M, Ren S Q 2014 ACS Nano 8 3671

    [36]

    Ren S Q, Wuttig M 2012 Adv. Mater. 24 724

    [37]

    Lohrman J, Liu Y Y, Duan S F, Zhao X Y, Wuttig M, Ren S Q 2013 Adv. Mater. 25 783

    [38]

    Qin W, Lohrman J, Ren S Q 2014 Angew. Chem. Int. Ed. Engl. 53 7316

    [39]

    Wei Q, Gong M G, Chen X M, Shastry T A, Sakidja R, Yuan G L, Hersam M C, Wuttig M, Ren S Q 2015 Adv. Mater. 27 734

    [40]

    Kagawa F, Horiuchi S, Tokunaga M, Fujioka J, Tokura Y 2010 Nat. Phys. 6 169

    [41]

    Torrance J B, Girlando A, Mayerle J J, Crowley J I, Lee V Y, Batail P, Laplaca S J 1981 Phys. Rev. Lett. 47 1747

    [42]

    Lamola A A, Hammond G S 1965 J. Chem. Phys. 43 2129

    [43]

    Ding L J, Yao K L, Fu H H 2011 J. Mater. Chem. 21 449

    [44]

    Yu G, Gao J, Hummelen J C, Wudl F, Heeger A J 1995 Science 270 1789

    [45]

    Brdas J L, Beljonne D, Coropceanu V, Cornil J 2004 Chem. Rev. 104 4971

    [46]

    Hu B, Wu Y 2007 Nat. Mater. 6 985

    [47]

    Qin W, Gao K, Yin S, Xie S J 2013 J. Appl. Phys. 113 193301

    [48]

    Janssen P, Cox M, Wouters S H W, Kemerink M, Wienk M M, Koopmans B 2013 Nat. Commun. 4 2286

    [49]

    Majumdar S, Majumdar H S, Aarnio H, Vanderzande D, Laiho R, Osterbacka R 2009 Phys. Rev. B 79 201202

    [50]

    Baldo M A, OBrien D F, You Y, Shoustikov A, Sibley S, Thompson M E, Forrest S R 1998 Nature 395 151

    [51]

    Jariwala D, Sangwan V K, Lauhon L J, Marks T J, Hersam M C 2013 Chem. Soc. Rev. 42 2824

    [52]

    Chen X M 2016 Ph. D. Dissertation (Nanjing: Nanjing University of Science and Technology) (in Chinese) [陈孝敏 2016 博士学位论文 (南京: 南京理工大学)]

    [53]

    Armstrong J N, Hua S Z, Chopra H D 2013 Phys. Status Solidi B 250 387

    [54]

    Callen E R 1960 J. Appl. Phys. 31 S149

    [55]

    Qin W, Chen X M, Li H S, Gong M G, Yuan G L, Grossman J C, Wuttig M, Ren S Q 2015 ACS Nano 9 9373

    [56]

    Xu B B, Li H S, Hall A, Gao W X, Gong M G, Yuan G L, Grossman J, Ren S Q 2015 Sci. Adv. 1 e1501264

    [57]

    Jin J Z, Lu S G, Chanthad C, Zhang Q M, Haque M A, Wang Q 2011 Adv. Mater. 23 3853

    [58]

    Carvell J, Cheng R H, Dowben P A, Yang Q 2013 Appl. Phys. Lett. 103 072902

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  • 收稿日期:  2018-04-20
  • 修回日期:  2018-06-13
  • 刊出日期:  2018-08-05

激发态电荷转移有机体的多铁性研究

    基金项目: 

    国家自然科学基金(批准号:51790492,51431006,51472118)和中央高校基本科研业务费专项资金(批准号:30916011104)资助的课题.

摘要: 随着人们对多铁性的深入了解,越来越多不同类型的有机多铁材料被合成出来.激发态电荷转移有机体的电荷转移网络是由一个提供电子的分子(给体donor,D+)和一个接受电子的分子(受体acceptor,A-)有序排列后构成的.D+A-长程有序排列,其激发态(激子)具有较长寿命和1/2自旋,这是产生室温铁电性和铁磁性的根本原因.激发态容易受外场刺激,因此光照、磁场、电场、应力等能够很好地调控这类材料的铁电极化、磁矩和相应的磁电耦合系数.激发态电荷转移有机体不仅大大丰富了室温多铁材料体系,而且可以为开发新型多功能电子器件提供材料基础和技术储备.

English Abstract

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