LiBaBO3：Ce3+ phosphor was prepared by solid-state method，and its luminescence characteristics were investigated. LiBaBO3：Ce3+ phosphor shows one asymmetrical band at 440 nm. Monitored at 440 nm，the excitation spectrum has a broad band at 370 nm. The crystallographic sites of Ce3+ in LiBaBO3 were calculated by van Uitert formula，the results show that the emission band centered at 438 nm originates from the Ce3+ center of the nine compounds，and at 469 nm originates from the Ce3+ center of the eight compounds. The effect of Ce3+ concentration on luminescent intensity of LiBaBO3：Ce3+ phosphor was investigated，the result shows that the luminescent intensity firstly increases with increasing Ce3+ concentration，and reaches the maximal value at 3mol% Ce3+, then decreases. The concentration quenching mechanism is the dipole-dipole interaction by Dexter theory. Under the condition of doping charge compensator Li+，Na+ or K+，the emission intensity of LiBaBO3：Ce3+ was all heightened. The relative emission spectrum of the InGaN-based LiBaBO3：Ce3+ light emitting diode（LED） was investigated，and the CIE chromaticity of InGaN-based LiBaBO3：Ce3+ LED is （x=0.291，y=0.297），and shows the blue white emission.