A kind of midinfrared As2S3 chalcogenide glass photonic crystal fiber is proposed in this paper. The characteristics of this fiber are studied by multipole method, including high birefringence, chromatic dispersion, and high nonlinearity. Through numerical simulation, it is found that at midinfrared wavelength λ = 3.625 μm, the birefringence of this fiber reaches up to 0.098 and nonlinear parameters are 1.69 m-1 ·W-1 and 0.78 m-1 ·W-1 for x-polarized mode and y-polarized mode, respectively. In addition, the fiber keeps normal dispersion in a wavelength range from 3 to 7 μm . In conclusion, the band of transmitted wavelength extends into a midinfrared wavelength range of 3—10 μm, and high birefringence and high nonlinearity in this photonic crystal fiber are perfectly combined. The results are significant for the further development of new photonic devices.