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Na3Zr2-xInxSi2-xP1+xO12系统的组成、结构和离子电导的关系

田顺宝 林祖纕

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Na3Zr2-xInxSi2-xP1+xO12系统的组成、结构和离子电导的关系

田顺宝, 林祖纕

THE RELATIONSHIP AMONG CHEMICAL COMPOSITION,CRYSTAL STRUCTURE AND IONIC CONDUCTANCE IN Na3Zr2-xInxSi2-xP1+xO12 SYSTEM

TIAN SHUN-BAO, LIN ZU-XIANG
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  • 用固相反应、X射线衍射、金相显微镜观察、测定比热和复平面阻抗谱的方法研究了Na3Zr2-xInxSi2-xP1+xO12系统。在此系统中存在两种固溶体:单斜固溶体(0≤x3Zr2-xInxSi2-x
    Na3Zr2-x InxSi2-xP1+xO12 system has been investigated by means of solid state reaction, X-ray powder diffraction technique, microscopic observation, specific heat measurement and complex impedance measurement. There are two kinds of solid solutions in this system: monoclinic solid solution (0≤x3Zr2-xInxSi2-xP1+xO12 solid solution, which begins at the composition of x=0.8, has been stabilized at room temperature. The stabilized materials do not exhibit any phase transformation in the heating process. The electrical conductivities in Na3Zr2-xMxSi2-x P1+x O12 (M = Y, Yb and In) systems have been compared, and discussed from the point of view of crystal chemistry.
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  • 被引次数: 0
出版历程
  • 收稿日期:  1985-12-04
  • 刊出日期:  1986-04-05

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