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本文研究准一维含铂卤素桥接混合价化合物(HMPC)中的激光诱导光吸收。在总结、分析实验事实的基础上,提出一个激光诱导光吸收机制,分别计算卤素(X)离子交替形变和描述极化子周围的X离子晶格形变这两种情况下的激光诱导光吸收谱,并与实验事实进行比较。Photo-induced absorption states in quasi-one-dimensional halogen-bridged mixed valence platinum complex is investigated. Based on the experimental data, a mechanism for photo-induced absorption is presented. Photo-induced absorption spectra both deformations of alternative and polaron induced for halogen ions are calculated. The comparison with experiments is made.
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