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中国物理学会期刊

碱金属掺杂富勒烯超导体的临界温度和约化能隙研究

CSTR: 32037.14.aps.43.1159

THEORY OF SUPERCONDUCTIVITY IN ALKALI-METAL-DOPED FULLERENES

CSTR: 32037.14.aps.43.1159
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  • 碱金属掺杂富勒烯与传统的超导体情况不同,它有一个很宽区域的声子谱,其最高频率和最低频率分别与费密能EF和零温超导能隙△0为同一数量级,这必将导致对原来强耦合超导电性理论的修正。本文在此情况下求解Eliashberg方程,得到Tc和△0的表达式。结果表明,分子间的低频振动模和分子上的高频振动模同样参与电声耦合,Tc主要取决于声子谱中高频成份的贡献,而△0的增加主要取决于声子谱中

     

    It is different from the case of conventional superconductors that the alkali-metal-doped fullerenes have wide-frequency-range phonon spectra whose high-and low-frequency phonon modes are, respectively, comparable to the Fermi energy EF and the zero-temperature gap △0. This property will lead to a modification to the theory of conventional strong coupling superconductivity. In this paper, by solving the Eliash-berg equations, the expressions of Tc and △0 are obtained. The results show that both the intermolecular low-frequency modes and the intramolecular highfrequency modes participate the electron-phonon interactions; Tc mainly arise from the high-frequency modes while △0's enhancement mainly arise from the low-frequency modes. So, the experimental results can be explained, especially, the large ratio of 2△0/kBTc.

     

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