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有机无机杂化固态太阳能电池的研究进展

袁怀亮 李俊鹏 王鸣魁

有机无机杂化固态太阳能电池的研究进展

袁怀亮, 李俊鹏, 王鸣魁
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  • 近年来, 由于钙钛矿材料优良的光学吸收和电荷传导特性, 有机无机杂化固态太阳能电池取得了突破性的进展. 自2009年首次报道了光电转换效率为3.8%的钙钛矿太阳能电池以来, 该类电池的效率不断突破. 基于介孔薄膜的电池已取得了超过16.7%的认证光电转换效率, 基于平板异质结结构电池光电转换效率达到19.3%, 已接近传统硅基太阳能电池的光电转换效率. 本文将介绍有机无机杂化钙钛矿作为光电材料的光学物理结构特性, 以及在固态太阳能电池中的应用. 基于固态钙钛矿太阳能电池结构上的差异, 分别介绍其在多孔结构、平板异质结结构、柔性结构以及无空穴传导材料结构电池工作特性和各自优势, 以及影响电池特性的主要影响因素, 特别是钙钛矿成膜控制等. 并阐述对钙钛矿电池的理解和进一步提高固态钙钛矿电池光电转换效率需要关注的重点以及展望.
    • 基金项目: 国家重点基础研究发展计划(批准号: 2011CBA00703), 国家自然科学基金(批准号: 201173091)云南省财政厅、工信委2014年可再生能源发展专项和教育部新世纪优秀人才(批准号: NCET-10-0416)资助的课题.
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  • [1]

    Nelson J 2003 The Physics of Solar Cells (London: Imperial College Press)

    [2]

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    [3]

    Repins I, Contreras M, Egaas B, DeHart C, Scharf J, Perkins C, To B, Noufi R 2008 Progress in Photovoltaics: Research and applications 16 235

    [4]

    Britt J, Ferekides C1993 Applied Physics Letters 62 2851

    [5]

    Green M, Emery K 1993 Progress in Photovoltaics: Research and Applications 1 25

    [6]

    Yella A, Lee H, Tsao H, Yi C, Chandiran A, Nazeeruddin M, Diau E, Yeh C, S Zakeeruddin, M Grätzel 2011 Science 334 629

    [7]

    O'Regan B, Grätzel M 1991 Nature 353 737

    [8]

    Bach U, Lupo D, Comte P, Moser J, Weissörtel F, Salbeck J, Spreitzer H, Grätzel M 1998 Nature 395 583

    [9]

    Krger J, Plass R, Grätzel M, Cameron P, Peter L 2003 J. Phys. Chem. B 107 7536

    [10]

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    [11]

    Kim H, Im S, Park N 2013 J. Phys. Chem. C 118 5615

    [12]

    Beltran E, Prené P, Boscher C, Belleville P, Buvat P, Lambert S, Guillet F, Marcel C, Sanchez C 2008 Eur. J. Inorg. Chem. 6 903

    [13]

    Xia J, Masaki N, Cantu M, Kim Y, Jiang K, Yanagida S 2008 J. Am. Chem. Soc. 130 1258

    [14]

    O'Regan B, Lenzmann F 2004 J. Phys. Chem. B 108 4342

    [15]

    Snaith H, Mende L 2007 Adv. Mater. 19 3187

    [16]

    Chang J, Im S, Lee Y, Kim H, Lim C, Heo J, Seok S 2012 Nano Lett. 12 1863

    [17]

    Im S, Lim C, Chang J, Lee Y, Maiti N, Kim H, Nazeeruddin M, Grätzel M, Seok S 2011 Nano Lett. 11 4789

    [18]

    Grätzel M, Janssen R, Mitzi D, Sargent E 2012 Nature 488 304

    [19]

    Barkhouse D, Debnath R, Kramer I, Zhitomirsky D, Abraham A, Levina L, Etgar L, Grätzel M, Sargent E 2011 Adv. Mater. 23 3134

    [20]

    Chung I, Lee B, He J, Chang R, Kanatzidis M 2012 Nature 485 486

    [21]

    Lee M, Teuscher J, Miyasaka T, Murakami T, Snaith H 2012 Science 2 643

    [22]

    Kojima A, Teshima K, Shirai Y, Miyasaka T 2009 J. Am. Chem. Soc. 131 6050

    [23]

    Im J, Lee C, Lee J, Park S, Park N 2011 Nanoscale 3 4088

    [24]

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    [25]

    Burschka J, Pellet N, Moon S, Baker R, Gao P, Nazeeruddin M, Grätzel M 2013 Nature 499 316

    [26]

    Laban W, Etgar L 2013 Energy Environ. Sci. 6 3249

    [27]

    Wojciechowski K, Saliba M, Leijtens T, Abate A, Snaith H 2014 Energy Environ. Sci. 7 1142

    [28]

    Mei A, Li X, Liu L, Ku Z, Liu T, Rong Y, Xu M, Hu M, Chen J, Yang Y, Grätzel M, Han H 2014 Science 345 295

    [29]

    Zhu Z, Bai Y, Zhang T, Liu Z, Long X, Wei Z, Wang Z, Zhang L, Wang J, Yan F, Yang S 2014 Angew. Chem. 26 1

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    Wang K, Jeng J, Shen P, Chang Y, Diau E, Tsai C, Chao T, Hsu H, Lin P, Chen P, Guo T, Wen T 2014 2012 Sci. Rep. 4 04756

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    Jeng J, Chen K, Chiang T, Lin P, Tsai T, Chan Y, Guo T, Chen P, Wen T, Hsu Y 2014 Adv. Mater. 26 4107

    [32]

    Wang K, Shen P, Li M, Chen S, Lin M, Chen P, Guo T 2014 ACS Appl. Mater. Interfaces 6 11851

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    [34]

    Zhou H, Chen Q, Li G, Luo S, Song T, Duan H, Hong Z, You J, Liu Y, Yang Y 2014 Science 345 542

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    [36]

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    Aharon S, Cohen B, Etgar L 2014 J. Phys. Chem. C 118 17160

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  • 收稿日期:  2014-10-20
  • 修回日期:  2014-12-02
  • 刊出日期:  2015-02-05

有机无机杂化固态太阳能电池的研究进展

  • 1. 华中科技大学, 武汉光电国家实验室, 格兰泽尔太阳能电池研究中心, 武汉 430074;
  • 2. 昆明贵金属研究所, 昆明 650106
    基金项目: 

    国家重点基础研究发展计划(批准号: 2011CBA00703), 国家自然科学基金(批准号: 201173091)云南省财政厅、工信委2014年可再生能源发展专项和教育部新世纪优秀人才(批准号: NCET-10-0416)资助的课题.

摘要: 近年来, 由于钙钛矿材料优良的光学吸收和电荷传导特性, 有机无机杂化固态太阳能电池取得了突破性的进展. 自2009年首次报道了光电转换效率为3.8%的钙钛矿太阳能电池以来, 该类电池的效率不断突破. 基于介孔薄膜的电池已取得了超过16.7%的认证光电转换效率, 基于平板异质结结构电池光电转换效率达到19.3%, 已接近传统硅基太阳能电池的光电转换效率. 本文将介绍有机无机杂化钙钛矿作为光电材料的光学物理结构特性, 以及在固态太阳能电池中的应用. 基于固态钙钛矿太阳能电池结构上的差异, 分别介绍其在多孔结构、平板异质结结构、柔性结构以及无空穴传导材料结构电池工作特性和各自优势, 以及影响电池特性的主要影响因素, 特别是钙钛矿成膜控制等. 并阐述对钙钛矿电池的理解和进一步提高固态钙钛矿电池光电转换效率需要关注的重点以及展望.

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