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浅析电子型掺杂铜氧化物超导体的退火过程

贾艳丽 杨桦 袁洁 于和善 冯中沛 夏海亮 石玉君 何格 胡卫 龙有文 朱北沂 金魁

浅析电子型掺杂铜氧化物超导体的退火过程

贾艳丽, 杨桦, 袁洁, 于和善, 冯中沛, 夏海亮, 石玉君, 何格, 胡卫, 龙有文, 朱北沂, 金魁
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  • 铜氧化物高温超导体的发现, 打破了基于电声子相互作用BCS理论所预言的超导转变温度极限, 掀开了高温超导材料探索和高温超导机理研究的序幕. 根据掺杂类型的不同, 铜氧化物超导材料可以分为空穴型掺杂和电子型掺杂两类. 受限于样品, 对电子型掺杂铜氧化物的研究工作远少于空穴型掺杂体系. 本文简要回顾有关电子型掺杂铜氧化物超导体近期研究成果, 通过对比电子型掺杂和空穴型掺杂铜氧化物的相图来阐明电子型掺杂铜氧化物的研究对探索高温超导机理的必要性, 并特别针对电子型掺杂样品制备中的关键因素“退火过程”展开讨论. 结合课题组最新实验结果和相关实验报道我们发现电子型掺杂铜氧化物超导体在制备过程中除受到温度和氧分压的影响外, 退火效果还受到界面应力的强烈调制. 在综合考虑样品生长过程中温度、气氛及应力等多种因素的基础上, 探讨了“保护退火”方法导致电子型体系化学掺杂相图变化的起因.
      通信作者: 金魁, kuijin@iphy.ac.cn
    • 基金项目: 国家重点基础研究发展计划(批准号: 2015CB921000)和国家自然科学基金(批准号: 11474338)资助的课题.
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  • 收稿日期:  2015-03-11
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浅析电子型掺杂铜氧化物超导体的退火过程

  • 1. 中国科学院物理研究所, 北京凝聚态国家实验室, 北京 100190
  • 通信作者: 金魁, kuijin@iphy.ac.cn
    基金项目: 

    国家重点基础研究发展计划(批准号: 2015CB921000)和国家自然科学基金(批准号: 11474338)资助的课题.

摘要: 铜氧化物高温超导体的发现, 打破了基于电声子相互作用BCS理论所预言的超导转变温度极限, 掀开了高温超导材料探索和高温超导机理研究的序幕. 根据掺杂类型的不同, 铜氧化物超导材料可以分为空穴型掺杂和电子型掺杂两类. 受限于样品, 对电子型掺杂铜氧化物的研究工作远少于空穴型掺杂体系. 本文简要回顾有关电子型掺杂铜氧化物超导体近期研究成果, 通过对比电子型掺杂和空穴型掺杂铜氧化物的相图来阐明电子型掺杂铜氧化物的研究对探索高温超导机理的必要性, 并特别针对电子型掺杂样品制备中的关键因素“退火过程”展开讨论. 结合课题组最新实验结果和相关实验报道我们发现电子型掺杂铜氧化物超导体在制备过程中除受到温度和氧分压的影响外, 退火效果还受到界面应力的强烈调制. 在综合考虑样品生长过程中温度、气氛及应力等多种因素的基础上, 探讨了“保护退火”方法导致电子型体系化学掺杂相图变化的起因.

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