搜索

x

留言板

尊敬的读者、作者、审稿人, 关于本刊的投稿、审稿、编辑和出版的任何问题, 您可以本页添加留言。我们将尽快给您答复。谢谢您的支持!

姓名
邮箱
手机号码
标题
留言内容
验证码

无铅和少铅的有机-无机杂化钙钛矿太阳电池研究进展

陈亮 张利伟 陈永生

无铅和少铅的有机-无机杂化钙钛矿太阳电池研究进展

陈亮, 张利伟, 陈永生
PDF
导出引用
  • 基于有机-无机杂化卤化铅材料的钙钛矿太阳电池的转换效率在短短几年内已迅速突破22%,为未来能源问题的解决带来了曙光,同时也引起了高度重视.但紧随其后的商品化、产业化发展需求极大地增加了对绿色、无毒的高效无铅钙钛矿太阳电池进行研究和开发的重要性和紧迫性.为进一步加快环境友好型钙钛矿太阳电池的研发进度,对目前无铅和少铅钙钛矿太阳电池的发展现状进行了综述.着重讨论了替代元素种类及其浓度、制备工艺等对薄膜和电池性能的影响,以期对电池的工作机理、替代元素的作用机理有更加深刻的认识,为新型环保、高效的钙钛矿太阳电池的制备提供指导.
      通信作者: 陈永生, chysh2003@zzu.edu.cn
    • 基金项目: 国家自然科学基金(批准号:61574129)和河南省基础与前沿计划(批准号:152300410035)资助的课题.
    [1]

    Kojima A, Teshima K, Shirai Y, Miyasaka T 2009 J. Am. Chem. Soc. 131 6050

    [2]

    Jiang Q, Zhang L Q, Wang H L, Yang X L, Yin Z G, Wu J L, Meng J H, Liu H, Zhang X W, You J B 2016 Nat. Energy 2 16177

    [3]

    Xing G C, Mathews N, Sun S Y, Lim S S, Lam Y M, Gratzel M, Mhaisalkar S, Sum T C 2013 Science 342 344

    [4]

    Shin S S, Yeom E J, Yang W S, Hur S, Kim M G, Im J, Seo J, Noh J H, Seok S I 2017 Science 356 167

    [5]

    Mei A Y, Li X, Liu L F, Ku Z L, Liu T F, Rong Y G, Xu M, Hu M, Chen J Z, Yang Y, Gratzel M, Han H W 2014 Science 345 295

    [6]

    Yang W S, Park B W, Jung E H, Jeon N J, Kim Y C, Lee D U, Shin S S, Seo J, Kim E K, Noh J H, Seok S I 2017 Science 356 1376

    [7]

    Yao X, Ding Y L, Zhang X D, Zhao Y 2015 Acta Phys. Sin. 64 038805 (in Chinese)[姚鑫, 丁艳丽, 张晓丹, 赵颖 2015 物理学报 64 038805]

    [8]

    Yang X D, Chen H, Bi E B, Han L Y 2015 Acta Phys. Sin. 64 038404 (in Chinese)[杨旭东,陈汉,毕恩兵,韩礼元 2015 物理学报 64 038404]

    [9]

    Wang Z, Shi Z, Li T, Chen Y, Huang W 2017 Angew. Chem. Int. Ed. 56 1190

    [10]

    Li B, Li Y, Zheng C, Gao D, Huang W 2016 RSC Adv. 6 38079

    [11]

    Slavney A H, Smaha R W, Smith I C, Jaffe A, Umeyama D, Karunadasa H I 2017 Inorg. Chem. 56 46

    [12]

    Chen J, Cai X, Yang D, Song D, Wang J, Jiang J, Ma A, Lv S, Hu M Z, Ni C 2017 J. Power Sources 355 98

    [13]

    You J, Meng L, Song T B, Guo T F, Yang Y, Chang W H, Hong Z, Chen H, Zhou H, Chen Q, Liu Y, Marco N D, Yang Y 2016 Nat. Nanotechnol. 11 75

    [14]

    Brinkmann K O, Zhao J, Pourdavoud N, Becker T, Hu T, Olthof S, Meerholz K, Hoffmann L, Gahlmann T, Heiderhoff R, Oszajca M F, Luechinger N A, Rogalla D, Chen Y, Cheng B, Riedl T 2017 Nat. Commun. 8 13938

    [15]

    Konstantakou M, Stergiopoulos T 2017 J. Mater. Chem. A 5 11518

    [16]

    Shi Z, Guo J, Chen Y, Li Q, Pan Y, Zhang H, Xia Y, Huang W 2017 Adv. Mater. 29 1605005

    [17]

    Boix P P, Agarwala S, Koh T M, Mathews N, Mhaisalkar S G 2015 J. Phys. Chem. Lett. 6 898

    [18]

    Zhang M, Lyu M, Chen P, Hao M, Yun J H, Wang L 2016 J. Chem. Eng. 11 392

    [19]

    Yang S, Fu W, Zhang Z, Chen H, Li C Z 2017 J. Mater. Chem. A 5 11462

    [20]

    Hoefler S F, Trimmel G, Rath T 2017 Monatsh. Chem. 148 795

    [21]

    Ma Y Z, Wang S F, Zheng L L, Lu Z L, Zhang D F, Bian Z Q, Huang C H, Xiao L X 2014 Chin. J. Chem. 32 957

    [22]

    Travis W, Glover E N K, Bronstein H, Scanlon D O, Palgrave R G 2016 Chem. Sci. 7 4548

    [23]

    Li C, Lu X, Ding W, Feng L, Gao Y, Guo Z 2008 Acta Cryst. 64 702

    [24]

    Eperon G E, Stranks S D, Menelaou C, Johnston M B, Herz L M, Snaith H J 2014 Energy Environ. Sci. 7 982

    [25]

    Brivio F, Walker A B, Walsh A 2013 APL Mater. 1 042111

    [26]

    Cortecchia D, Dewi H A, Yin J, Bruno A, Chen S, Baikie T, Boix P P, Grtzel M, Mhaisalkar S, Soci C, Mathews N 2016 Inorg. Chem. 55 1044

    [27]

    Cui X P, Jiang K J, Huang J H, Zhang Q Q, Su M J, Yang L M, Song Y L, Zhou X Q 2015 Synth. Met. 209 247

    [28]

    Yang D, Lv J, Zhao X, Xu Q, Fu Y, Zhan Y, Zunger A, Zhang L 2017 Chem. Mater. 29 524

    [29]

    Wang Z K, Li M, Yang Y G, Hu Y, Ma H, Gao X Y, Liao L S 2016 Adv. Mater. 28 6695

    [30]

    Wang J T W, Wang Z, Pathak S, Zhang W, deQuilettes D W, Wisnivesky-Rocca-Rivarola F, Huang J, Nayak P K, Patel J B, Yusof H A M, Vaynzof Y, Zhu R, Ramirez I, Zhang J, Ducati C, Grovenor C, Johnston M B, Ginger D S, Nicholas R J, Snaith H J 2016 Energy Environ. Sci. 9 2892

    [31]

    Abdelhady A L, Saidaminov M I, Murali B, Adinolfi V, Voznyy O, Katsiev K, Alarousu E, Comin R, Dursun I, Sinatra L, Sargent E H, Mohammed O F, Bakr O M 2016 J. Phys. Chem. Lett. 7 295

    [32]

    Abdi-Jalebi M, Dar M I, Sadhanala A, Senanayak S P, Franckevicčius M, Arora N, Hu Y, Nazeeruddin M K, Zakeeruddin S M, Gratzel M, Friend R H 2016 Adv. Energy Mater. 6 1502472

    [33]

    Chang J, Lin Z, Zhu H, Isikgor F H, Xu Q H, Zhang C, Hao Y, Ouyang J 2016 J. Mater. Chem. A 4 16546

    [34]

    Even J, Pedesseau L, Jancu J M, Katan C 2014 Phys. Status Solidi RRL 8 31

    [35]

    Stoumpos C C, Malliakas C D, Kanatzidis M G 2013 Inorg. Chem. 52 9019

    [36]

    Ma L, Hao F, Stoumpos C C, Phelan B T, Wasielewski M R, Kanatzidis M G 2016 J. Am. Chem. Soc. 138 14750

    [37]

    Hao F, Stoumpos C C, Cao D H, Chang R P H, Kanatzidis M G 2014 Nat. Photonics 8 489

    [38]

    Yang W S, Noh J H, Jeon N J, Kim Y C, Ryu S, Seo J, Seok S I 2015 Science 348 1234

    [39]

    Hao F, Stoumpos C C, Guo P, Zhou N, Marks T J, Chang R P H, Kanatzidis M G 2015 J. Am. Chem. Soc. 137 11445

    [40]

    Sutherland B R, Hoogland S, Adachi M M, Kanjanaboos P, Wong C T O, McDowell J J, Xu J, Voznyy O, Ning Z, Houtepen A J, Sargent E H 2015 Adv. Mater. 27 53

    [41]

    Noel N K, Stranks S D, Abate A, Wehrenfennig C, Guarnera S, Haghighirad A A, Sadhanala A, Eperon G E, Pathak S K, Johnston M B, Petrozza A, Herz L M, Snaith H J 2014 Energy Environ Sci. 7 3061

    [42]

    Yu Y, Zhao D, Grice C R, Meng W, Wang C, Liao W, Cimaroli A J, Zhang H, Zhu K, Yan Y 2016 RSC Adv. 6 90248

    [43]

    Zhao B, Abdi-Jalebi M, Tabachnyk M, Glass H, Kamboj V S, Nie W A, Pearson J, Puttisong Y, Gdel K C, Beere H E, Ritchie D A, Mohite A D, Dutton S E, Friend R H, Sadhanala A 2017 Adv. Mater. 29 1604744

    [44]

    Song T B, Yokoyama T, Stoumpos C C, Logsdon J, Cao D H, Wasielewski M R, Aramaki S, Kanatzidis M G 2017 J. Am. Chem. Soc. 139 836

    [45]

    Kim H D, Miyamoto Y, Kubota H, Yamanari T, Ohkita H 2017 Chem. Lett. 46 253

    [46]

    Fujihara T, Terakawa S, Matsushima T, Qin C, Yahiroa M, Adachi C 2017 J. Mater. Chem. C 5 1121

    [47]

    Yokoyama T, Cao D H, Stoumpos C C, Song T B, Sato Y, Aramaki S, Kanatzidis M G 2016 J. Phys. Chem. Lett. 7 776

    [48]

    Chiarella F, Ferro P, Licci F, Barra M, Biasiucci M, Cassinese A, Vaglio R 2007 Appl. Phys. A 86 89

    [49]

    Jung M C, Raga S R, Qi Y 2016 RSC Adv. 6 2819

    [50]

    Yokoyama T, Song T B, Cao D H, Stoumpos C C, Aramaki S, Kanatzidis M G 2017 ACS Energy Lett. 2 22

    [51]

    Ergen O, Gilbert S M, Pham T, Turner S J, Tan M T Z, Worsley M A, Zettl A 2017 Nat. Mater. 16 522

    [52]

    Koh T M, Krishnamoorthy T, Yantara N, Shi C, Leong W L, Boix P P, Grimsdale A C, Mhaisalkar S G, Mathews N 2015 J. Mater. Chem. A 3 14996

    [53]

    Lee S J, Shin S S, Kim Y C, Kim D, Ahn T K, Noh J H, Seo J, Seok S I 2016 J. Am. Chem. Soc. 138 3974

    [54]

    Ke W, Stoumpos C C, Logsdon J L, Wasielewski M R, Yan Y, Fang G, Kanatzidis M G 2016 J. Am. Chem. Soc. 138 14998

    [55]

    Zhao Z, Gu F, Li Y, Sun W, Ye S, Rao H, Liu Z, Bian Z, Huang C 2017 Adv. Sci. 4 1700204

    [56]

    Liao W, Zhao D, Yu Y, Grice C R, Wang C, Cimaroli A J, Schulz P, Meng W, Zhu K, Xiong R G, Yan Y 2016 Adv. Mater. 28 9333

    [57]

    Zhang M, Lyu M, Yun J H, Noori M, Zhou X, Cooling N A, Wang Q, Yu H, Dastoor P C, Wang L 2016 Nano Res. 9 1570

    [58]

    Liao Y, Liu H, Zhou W, Yang D, Shang Y, Shi Z, Li B, Jiang X, Zhang L, Quan L N, Quintero-Bermudez R, Sutherland B R, Mi Q, Sargent E H, Ning Z 2017 J. Am. Chem. Soc. 139 6693

    [59]

    Ke W, Stoumpos C C, Zhu M, Mao L, Spanopoulos I, Liu J, Kontsevoi O Y, Chen M, Sarma D, Zhang Y, Wasielewski M R, Kanatzidis M G 2017 Sci. Adv. 3 e1701293

    [60]

    Chung I, Lee B, He J, Chang R P H, Kanatzidis M G 2012 Nature 485 486

    [61]

    Wu B, Zhou Y, Xing G, Xu Q, Garces H F, Solanki A, Goh T W, Padture N P, Sum T C 2017 Adv. Funct. Mater. 27 1604818

    [62]

    Marshall K P, Walton R I, Hatton R A 2015 J. Mater. Chem. A 3 11631

    [63]

    Zhou Y, Garces H F, Senturk B S, Ortiz A L, Padture N P 2013 Mater. Lett. 110 127

    [64]

    Chen Z, Wang J J, Ren Y, Yu C, Shum K 2012 Appl. Phys. Lett. 101 093901

    [65]

    Xu P, Chen S, Xiang H J, Gong X G, Wei S H 2014 Chem. Mater. 26 6068

    [66]

    Kumar M H, Dharani S, Leong W L, Boix P P, Prabhakar R R, Baikie T, Shi C, Ding H, Ramesh R, Asta M, Graetzel M, Mhaisalkar S G, Mathews N 2014 Adv. Mater. 26 7122

    [67]

    Wang N, Zhou Y, Ju M G, Garces H F, Ding T, Pang S, Zeng X C, Padture N P, Sun X W 2016 Adv. Energy Mater. 6 1601130

    [68]

    Marshall K P, Walker M, Walton R I, Hatton R A 2016 Nat. Energy 1 16178

    [69]

    Sabba D, Mulmudi H K, Prabhakar R R, Krishnamoorthy T, Baikie T, Boix P P, Mhaisalkar S, Mathews N 2015 J. Phys. Chem. C 119 1763

    [70]

    Moghe D, Wang L, Traverse C J, Redoute A, Sponseller M, Brown P R, Bulović V, Lunt R R 2016 Nano Energy 28 469

    [71]

    Li W, Li J, Li J, Fan J, Mai Y, Wang L 2016 J. Mater. Chem. A 4 17104

    [72]

    Gupta S, Bendikov T, Hodes G, Cahen D 2016 ACS Energy Lett. 1 1028

    [73]

    Shannon R D 1976 Acta Crystallogr. A 32 751

    [74]

    Lee B, Stoumpos C C, Zhou N, Hao F, Malliakas C, Yeh C Y, Marks T J, Kanatzidis M G, Chang R P H 2014 J. Am. Chem. Soc. 136 15379

    [75]

    Qiu X, Jiang Y, Zhang H, Qiu Z, Yuan S, Wang P, Cao B 2016 Phys. Status Solidi RRL 10 587

    [76]

    Qiu X, Cao B, Yuan S, Chen X, Qiu Z, Jiang Y, Ye Q, Wang H, Zeng H, Liu J, Kanatzidis M G 2017 Sol. Energy Mater. Sol. Cells 159 227

    [77]

    Sun P P, Li Q S, Yang L N, Li Z S 2016 Nanoscale 8 1503

    [78]

    Krishnamoorthy T, Ding H, Yan C, Leong W L, Baikie T, Zhang Z, Sherburne M, Li S, Asta M, Mathews N, Mhaisalkar S G 2015 J. Mater. Chem. A 3 23829

    [79]

    Uribe J I, Ramirez D, Osorio-Guilleńn J M, Osorio J, Jaramillo F 2016 J. Phys. Chem. C 120 16393

    [80]

    Pazoki M, Jacobsson T J, Hagfeldt A, Boschloo G, Edvinsson T 2016 Phys. Rev. B 93 144105

    [81]

    Filip M R, Giustino F 2016 J. Phys. Chem. C 120 166

    [82]

    Hamdeh U H, Nelson R D, Ryan B J, Bhattacharjee U, Petrich J W, Panthani M G 2016 Chem. Mater. 28 6567

    [83]

    Peresh E Y, Sidei V I, Zubaka O V, Stercho I P 2011 Inorg. Mater. 47 208

    [84]

    Maughan A E, Ganose A M, Bordelon M M, Miller E M, Scanlon D O, Neilson J R 2016 J. Am. Chem. Soc. 138 8453

    [85]

    Sakai N, Haghighirad A A, Filip M R, Nayak P K, Nayak S, Ramadan A, Wang Z, Giustino F, Snaith H J 2017 J. Am. Chem. Soc. 139 6030

    [86]

    Retuerto M, Emge T, Hadermann J, Stephens P W, Li M R, Yin Z P, Croft M, Ignatov A, Zhang S J, Yuan Z, Jin C, Simonson J W, Aronson M C, Pan A, Basov D N, Kotliar G, Greenblatt M 2013 Chem. Mater. 25 4071

    [87]

    Riggs S C, Shapiro M C, Corredor F, Geballe T H, Fisher I R, McCandless G T, Chan J Y 2012 J. Cryst. Growth 355 13

    [88]

    Slavney A H, Hu T, Lindenberg A M, Karunadasa H I 2016 J. Am. Chem. Soc. 138 2138

    [89]

    Volonakis G, Filip M R, Haghighirad A A, Sakai N, Wenger B, Snaith H J, Giustino F 2016 J. Phys. Chem. Lett. 7 1254

    [90]

    Volonakis G, Haghighirad A A, Milot R L, Sio W H, Filip M R, Wenger B, Johnston M B, Herz L M, Snaith H J, Giustino F 2017 J. Phys. Chem. Lett. 8 772

    [91]

    Zhao X G, Yang D, Sun Y, Li T, Zhang L, Yu L, Zunger A 2017 J. Am. Chem. Soc. 139 6718

    [92]

    Zhao X G, Yang J, Fu Y, Yang D, Xu Q, Yu L, Wei S H, Zhang L 2017 J. Am. Chem. Soc. 139 2630

    [93]

    McClure E T, Ball M R, Windl W, Woodward P M 2016 Chem. Mater. 28 1348

    [94]

    Greul E, Petrus M L, Binek A, Docampo P, Bein T 2017 J. Mater. Chem. A 5 19972

    [95]

    Feng H J, Deng W, Yang K, Huang J, Zeng X C 2017 J. Phys. Chem. C 121 4471

    [96]

    Kulkarni S A, Baikie T, Boix P P, Yantara N, Mathews N, Mhaisalkar S 2014 J. Mater. Chem. A 2 9221

    [97]

    Hao F, Stoumpos C C, Chang R P H, Kanatzidis M G 2014 J. Am. Chem. Soc. 136 8094

    [98]

    Liu C, Fan J, Li H, Zhang C, Mai Y 2016 Sci. Rep. 6 35705

    [99]

    Eperon G E, Leijtens T, Bush K A, Prasanna R, Green T, Wang J T W, McMeekin D P, Volonakis G, Milot R L, May R, Palmstrom A, Slotcavage D J, Belisle R A, Patel J B, Parrott E S, Sutton R J, Ma W, Moghadam F, Conings B, Babayigit A, Boyen H G, Bent S, Giustino F, Herz L M, Johnston M B, McGehee M D, Snaith H J 2016 Science 354 861

    [100]

    Ogomi Y, Morita A, Tsukamoto S, Saitho T, Fujikawa N, Shen Q, Toyoda T, Yoshino K, Pandey S S, Ma T, Hayase S 2014 J. Phys. Chem. Lett. 5 1004

    [101]

    Zuo F, Williams S T, Liang P W, Chueh C C, Liao C Y, Jen A K Y 2014 Adv. Mater. 26 6454

    [102]

    Zhu L, Yuh B, Schoen S, Li X, Aldighaithir M, Richardson B J, Alamer A, Yu Q 2016 Nanoscale 8 7621

    [103]

    Yang Z, Rajagopal A, Chueh C C, Jo S B, Liu B, Zhao T, Jen A K Y 2016 Adv. Mater. 28 8990

    [104]

    Liu X, Yang Z, Chueh C C, Rajagopal A, Williams S T, Sun Y, Jen A K Y 2016 J. Mater. Chem. A 4 17939

    [105]

    Yang Z, Rajagopal A, Jo S B, Chueh C C, Williams S, Huang C C, Katahara J K, Hillhouse H W, Jen A K Y 2016 Nano Lett. 16 7739

    [106]

    Zhu H L, Xiao J, Mao J, Zhang H, Zhao Y, Choy W C H 2017 Adv. Funct. Mater. 27 1605489

    [107]

    Li L, Zhang F, Hao Y, Sun Q, Li Z, Hua W, Cui Y, Zhu F 2017 J. Mater. Chem. C 5 2360

    [108]

    Mosconi E, Umaribc P, de Angelis F 2015 J. Mater. Chem. A 3 9208

    [109]

    Lin G, Lin Y, Huang H, Cui R, Guo X, Liu B, Dong J, Guo X, Sun B 2016 Nano Energy 27 638

    [110]

    Lyu M, Zhang M, Cooling N A, Jiao Y, Wang Q, Yun J H, Vaughan B, Triani G, Evans P, Zhou X, Feron K, Du A, Dastoor P, Wang L 2016 Sci. Bull. 61 1558

    [111]

    Li Y, Sun W, Yan W, Ye S, Rao H, Peng H, Zhao Z, Bian Z, Liu Z, Zhou H, Huang C 2016 Adv. Energy Mater. 6 1601353

    [112]

    Liu J, Wang G, Song Z, He X, Luo K, Ye Q, Liao C, Mei J 2017 J. Mater. Chem. A 5 9097

    [113]

    Xu X, Chueh C C, Yang Z, Rajagopal A, Xu J, Jo S B, Jen A K Y 2017 Nano Energy 34 392

    [114]

    Liao W, Zhao D, Yu Y, Shrestha N, Ghimire K, Grice C R, Wang C, Xiao Y, Cimaroli A J, Ellingson R J, Podraza N J, Zhu K, Xiong R G, Yan Y 2016 J. Am. Chem. Soc. 138 12360

    [115]

    Zhao D, Yu Y, Wang C, Liao W, Shrestha N, Grice C R, Cimaroli A J, Guan L, Ellingson R J, Zhu K, Zhao X, Xiong R G, Yan Y 2017 Nat. Energy 2 17018

    [116]

    Prez-del-Rey D, Forgcs D, Hutter E M, Savenije T J, Nordlund D, Schulz P, Berry J J, Sessolo M, Bolink H J 2016 Adv. Mater. 28 9839

    [117]

    Navas J, Snchez-Coronilla A, Gallardo J J, Hernndez N C, Piero J C, Alcntara R, Fernndez-Lorenzo C, de los Santos D M, Aguilar T, Martn-Calleja J 2015 Nanoscale 7 6216

    [118]

    Shai X, Zuo L, Sun P, Liao P, Huang W, Yao E P, Lia H, Liu S, Shen Y, Yang Y, Wang M 2017 Nano Energy 36 213

    [119]

    Zhang H, Wang H, Williams S T, Xiong D, Zhang W, Chueh C C, Chen W, Jen A K Y 2017 Adv. Mater. 29 1606608

    [120]

    Wang R, Zhang X, He J, Ma C, Xu L, Sheng P, Huang F 2017 J. Alloy. Compd. 695 555

    [121]

    Klug M T, Osherov A, Haghighirad A A, Stranks S D, Brown P R, Bai S, Wang J T W, Dang X, Bulovic V, Snaith H J, Belcher A M 2017 Energy Environ. Sci. 10 236

    [122]

    Williams S T, Rajagopal A, Jo S B, Chueh C C, Tang T F L, Kraegera A, Jen A K Y 2017 J. Mater. Chem. A 5 10640

    [123]

    Jahandar M, Heo J H, Song C E, Kong K J, Shin W S, Lee J C, Im S H, Moon S J 2016 Nano Energy 27 330

    [124]

    Shahbazi S, Tsai C M, Narra S, Wang C Y, Shiu H S, Afshar S, Taghavinia N, Diau E W G 2017 J. Phys. Chem. C 121 3673

    [125]

    Chen Q, Chen L, Ye F, Zhao T, Tang F, Rajagopal A, Jiang Z, Jiang S, Jen A K Y, Xie Y, Cai J, Chen L 2017 Nano Lett. 17 3231

  • [1]

    Kojima A, Teshima K, Shirai Y, Miyasaka T 2009 J. Am. Chem. Soc. 131 6050

    [2]

    Jiang Q, Zhang L Q, Wang H L, Yang X L, Yin Z G, Wu J L, Meng J H, Liu H, Zhang X W, You J B 2016 Nat. Energy 2 16177

    [3]

    Xing G C, Mathews N, Sun S Y, Lim S S, Lam Y M, Gratzel M, Mhaisalkar S, Sum T C 2013 Science 342 344

    [4]

    Shin S S, Yeom E J, Yang W S, Hur S, Kim M G, Im J, Seo J, Noh J H, Seok S I 2017 Science 356 167

    [5]

    Mei A Y, Li X, Liu L F, Ku Z L, Liu T F, Rong Y G, Xu M, Hu M, Chen J Z, Yang Y, Gratzel M, Han H W 2014 Science 345 295

    [6]

    Yang W S, Park B W, Jung E H, Jeon N J, Kim Y C, Lee D U, Shin S S, Seo J, Kim E K, Noh J H, Seok S I 2017 Science 356 1376

    [7]

    Yao X, Ding Y L, Zhang X D, Zhao Y 2015 Acta Phys. Sin. 64 038805 (in Chinese)[姚鑫, 丁艳丽, 张晓丹, 赵颖 2015 物理学报 64 038805]

    [8]

    Yang X D, Chen H, Bi E B, Han L Y 2015 Acta Phys. Sin. 64 038404 (in Chinese)[杨旭东,陈汉,毕恩兵,韩礼元 2015 物理学报 64 038404]

    [9]

    Wang Z, Shi Z, Li T, Chen Y, Huang W 2017 Angew. Chem. Int. Ed. 56 1190

    [10]

    Li B, Li Y, Zheng C, Gao D, Huang W 2016 RSC Adv. 6 38079

    [11]

    Slavney A H, Smaha R W, Smith I C, Jaffe A, Umeyama D, Karunadasa H I 2017 Inorg. Chem. 56 46

    [12]

    Chen J, Cai X, Yang D, Song D, Wang J, Jiang J, Ma A, Lv S, Hu M Z, Ni C 2017 J. Power Sources 355 98

    [13]

    You J, Meng L, Song T B, Guo T F, Yang Y, Chang W H, Hong Z, Chen H, Zhou H, Chen Q, Liu Y, Marco N D, Yang Y 2016 Nat. Nanotechnol. 11 75

    [14]

    Brinkmann K O, Zhao J, Pourdavoud N, Becker T, Hu T, Olthof S, Meerholz K, Hoffmann L, Gahlmann T, Heiderhoff R, Oszajca M F, Luechinger N A, Rogalla D, Chen Y, Cheng B, Riedl T 2017 Nat. Commun. 8 13938

    [15]

    Konstantakou M, Stergiopoulos T 2017 J. Mater. Chem. A 5 11518

    [16]

    Shi Z, Guo J, Chen Y, Li Q, Pan Y, Zhang H, Xia Y, Huang W 2017 Adv. Mater. 29 1605005

    [17]

    Boix P P, Agarwala S, Koh T M, Mathews N, Mhaisalkar S G 2015 J. Phys. Chem. Lett. 6 898

    [18]

    Zhang M, Lyu M, Chen P, Hao M, Yun J H, Wang L 2016 J. Chem. Eng. 11 392

    [19]

    Yang S, Fu W, Zhang Z, Chen H, Li C Z 2017 J. Mater. Chem. A 5 11462

    [20]

    Hoefler S F, Trimmel G, Rath T 2017 Monatsh. Chem. 148 795

    [21]

    Ma Y Z, Wang S F, Zheng L L, Lu Z L, Zhang D F, Bian Z Q, Huang C H, Xiao L X 2014 Chin. J. Chem. 32 957

    [22]

    Travis W, Glover E N K, Bronstein H, Scanlon D O, Palgrave R G 2016 Chem. Sci. 7 4548

    [23]

    Li C, Lu X, Ding W, Feng L, Gao Y, Guo Z 2008 Acta Cryst. 64 702

    [24]

    Eperon G E, Stranks S D, Menelaou C, Johnston M B, Herz L M, Snaith H J 2014 Energy Environ. Sci. 7 982

    [25]

    Brivio F, Walker A B, Walsh A 2013 APL Mater. 1 042111

    [26]

    Cortecchia D, Dewi H A, Yin J, Bruno A, Chen S, Baikie T, Boix P P, Grtzel M, Mhaisalkar S, Soci C, Mathews N 2016 Inorg. Chem. 55 1044

    [27]

    Cui X P, Jiang K J, Huang J H, Zhang Q Q, Su M J, Yang L M, Song Y L, Zhou X Q 2015 Synth. Met. 209 247

    [28]

    Yang D, Lv J, Zhao X, Xu Q, Fu Y, Zhan Y, Zunger A, Zhang L 2017 Chem. Mater. 29 524

    [29]

    Wang Z K, Li M, Yang Y G, Hu Y, Ma H, Gao X Y, Liao L S 2016 Adv. Mater. 28 6695

    [30]

    Wang J T W, Wang Z, Pathak S, Zhang W, deQuilettes D W, Wisnivesky-Rocca-Rivarola F, Huang J, Nayak P K, Patel J B, Yusof H A M, Vaynzof Y, Zhu R, Ramirez I, Zhang J, Ducati C, Grovenor C, Johnston M B, Ginger D S, Nicholas R J, Snaith H J 2016 Energy Environ. Sci. 9 2892

    [31]

    Abdelhady A L, Saidaminov M I, Murali B, Adinolfi V, Voznyy O, Katsiev K, Alarousu E, Comin R, Dursun I, Sinatra L, Sargent E H, Mohammed O F, Bakr O M 2016 J. Phys. Chem. Lett. 7 295

    [32]

    Abdi-Jalebi M, Dar M I, Sadhanala A, Senanayak S P, Franckevicčius M, Arora N, Hu Y, Nazeeruddin M K, Zakeeruddin S M, Gratzel M, Friend R H 2016 Adv. Energy Mater. 6 1502472

    [33]

    Chang J, Lin Z, Zhu H, Isikgor F H, Xu Q H, Zhang C, Hao Y, Ouyang J 2016 J. Mater. Chem. A 4 16546

    [34]

    Even J, Pedesseau L, Jancu J M, Katan C 2014 Phys. Status Solidi RRL 8 31

    [35]

    Stoumpos C C, Malliakas C D, Kanatzidis M G 2013 Inorg. Chem. 52 9019

    [36]

    Ma L, Hao F, Stoumpos C C, Phelan B T, Wasielewski M R, Kanatzidis M G 2016 J. Am. Chem. Soc. 138 14750

    [37]

    Hao F, Stoumpos C C, Cao D H, Chang R P H, Kanatzidis M G 2014 Nat. Photonics 8 489

    [38]

    Yang W S, Noh J H, Jeon N J, Kim Y C, Ryu S, Seo J, Seok S I 2015 Science 348 1234

    [39]

    Hao F, Stoumpos C C, Guo P, Zhou N, Marks T J, Chang R P H, Kanatzidis M G 2015 J. Am. Chem. Soc. 137 11445

    [40]

    Sutherland B R, Hoogland S, Adachi M M, Kanjanaboos P, Wong C T O, McDowell J J, Xu J, Voznyy O, Ning Z, Houtepen A J, Sargent E H 2015 Adv. Mater. 27 53

    [41]

    Noel N K, Stranks S D, Abate A, Wehrenfennig C, Guarnera S, Haghighirad A A, Sadhanala A, Eperon G E, Pathak S K, Johnston M B, Petrozza A, Herz L M, Snaith H J 2014 Energy Environ Sci. 7 3061

    [42]

    Yu Y, Zhao D, Grice C R, Meng W, Wang C, Liao W, Cimaroli A J, Zhang H, Zhu K, Yan Y 2016 RSC Adv. 6 90248

    [43]

    Zhao B, Abdi-Jalebi M, Tabachnyk M, Glass H, Kamboj V S, Nie W A, Pearson J, Puttisong Y, Gdel K C, Beere H E, Ritchie D A, Mohite A D, Dutton S E, Friend R H, Sadhanala A 2017 Adv. Mater. 29 1604744

    [44]

    Song T B, Yokoyama T, Stoumpos C C, Logsdon J, Cao D H, Wasielewski M R, Aramaki S, Kanatzidis M G 2017 J. Am. Chem. Soc. 139 836

    [45]

    Kim H D, Miyamoto Y, Kubota H, Yamanari T, Ohkita H 2017 Chem. Lett. 46 253

    [46]

    Fujihara T, Terakawa S, Matsushima T, Qin C, Yahiroa M, Adachi C 2017 J. Mater. Chem. C 5 1121

    [47]

    Yokoyama T, Cao D H, Stoumpos C C, Song T B, Sato Y, Aramaki S, Kanatzidis M G 2016 J. Phys. Chem. Lett. 7 776

    [48]

    Chiarella F, Ferro P, Licci F, Barra M, Biasiucci M, Cassinese A, Vaglio R 2007 Appl. Phys. A 86 89

    [49]

    Jung M C, Raga S R, Qi Y 2016 RSC Adv. 6 2819

    [50]

    Yokoyama T, Song T B, Cao D H, Stoumpos C C, Aramaki S, Kanatzidis M G 2017 ACS Energy Lett. 2 22

    [51]

    Ergen O, Gilbert S M, Pham T, Turner S J, Tan M T Z, Worsley M A, Zettl A 2017 Nat. Mater. 16 522

    [52]

    Koh T M, Krishnamoorthy T, Yantara N, Shi C, Leong W L, Boix P P, Grimsdale A C, Mhaisalkar S G, Mathews N 2015 J. Mater. Chem. A 3 14996

    [53]

    Lee S J, Shin S S, Kim Y C, Kim D, Ahn T K, Noh J H, Seo J, Seok S I 2016 J. Am. Chem. Soc. 138 3974

    [54]

    Ke W, Stoumpos C C, Logsdon J L, Wasielewski M R, Yan Y, Fang G, Kanatzidis M G 2016 J. Am. Chem. Soc. 138 14998

    [55]

    Zhao Z, Gu F, Li Y, Sun W, Ye S, Rao H, Liu Z, Bian Z, Huang C 2017 Adv. Sci. 4 1700204

    [56]

    Liao W, Zhao D, Yu Y, Grice C R, Wang C, Cimaroli A J, Schulz P, Meng W, Zhu K, Xiong R G, Yan Y 2016 Adv. Mater. 28 9333

    [57]

    Zhang M, Lyu M, Yun J H, Noori M, Zhou X, Cooling N A, Wang Q, Yu H, Dastoor P C, Wang L 2016 Nano Res. 9 1570

    [58]

    Liao Y, Liu H, Zhou W, Yang D, Shang Y, Shi Z, Li B, Jiang X, Zhang L, Quan L N, Quintero-Bermudez R, Sutherland B R, Mi Q, Sargent E H, Ning Z 2017 J. Am. Chem. Soc. 139 6693

    [59]

    Ke W, Stoumpos C C, Zhu M, Mao L, Spanopoulos I, Liu J, Kontsevoi O Y, Chen M, Sarma D, Zhang Y, Wasielewski M R, Kanatzidis M G 2017 Sci. Adv. 3 e1701293

    [60]

    Chung I, Lee B, He J, Chang R P H, Kanatzidis M G 2012 Nature 485 486

    [61]

    Wu B, Zhou Y, Xing G, Xu Q, Garces H F, Solanki A, Goh T W, Padture N P, Sum T C 2017 Adv. Funct. Mater. 27 1604818

    [62]

    Marshall K P, Walton R I, Hatton R A 2015 J. Mater. Chem. A 3 11631

    [63]

    Zhou Y, Garces H F, Senturk B S, Ortiz A L, Padture N P 2013 Mater. Lett. 110 127

    [64]

    Chen Z, Wang J J, Ren Y, Yu C, Shum K 2012 Appl. Phys. Lett. 101 093901

    [65]

    Xu P, Chen S, Xiang H J, Gong X G, Wei S H 2014 Chem. Mater. 26 6068

    [66]

    Kumar M H, Dharani S, Leong W L, Boix P P, Prabhakar R R, Baikie T, Shi C, Ding H, Ramesh R, Asta M, Graetzel M, Mhaisalkar S G, Mathews N 2014 Adv. Mater. 26 7122

    [67]

    Wang N, Zhou Y, Ju M G, Garces H F, Ding T, Pang S, Zeng X C, Padture N P, Sun X W 2016 Adv. Energy Mater. 6 1601130

    [68]

    Marshall K P, Walker M, Walton R I, Hatton R A 2016 Nat. Energy 1 16178

    [69]

    Sabba D, Mulmudi H K, Prabhakar R R, Krishnamoorthy T, Baikie T, Boix P P, Mhaisalkar S, Mathews N 2015 J. Phys. Chem. C 119 1763

    [70]

    Moghe D, Wang L, Traverse C J, Redoute A, Sponseller M, Brown P R, Bulović V, Lunt R R 2016 Nano Energy 28 469

    [71]

    Li W, Li J, Li J, Fan J, Mai Y, Wang L 2016 J. Mater. Chem. A 4 17104

    [72]

    Gupta S, Bendikov T, Hodes G, Cahen D 2016 ACS Energy Lett. 1 1028

    [73]

    Shannon R D 1976 Acta Crystallogr. A 32 751

    [74]

    Lee B, Stoumpos C C, Zhou N, Hao F, Malliakas C, Yeh C Y, Marks T J, Kanatzidis M G, Chang R P H 2014 J. Am. Chem. Soc. 136 15379

    [75]

    Qiu X, Jiang Y, Zhang H, Qiu Z, Yuan S, Wang P, Cao B 2016 Phys. Status Solidi RRL 10 587

    [76]

    Qiu X, Cao B, Yuan S, Chen X, Qiu Z, Jiang Y, Ye Q, Wang H, Zeng H, Liu J, Kanatzidis M G 2017 Sol. Energy Mater. Sol. Cells 159 227

    [77]

    Sun P P, Li Q S, Yang L N, Li Z S 2016 Nanoscale 8 1503

    [78]

    Krishnamoorthy T, Ding H, Yan C, Leong W L, Baikie T, Zhang Z, Sherburne M, Li S, Asta M, Mathews N, Mhaisalkar S G 2015 J. Mater. Chem. A 3 23829

    [79]

    Uribe J I, Ramirez D, Osorio-Guilleńn J M, Osorio J, Jaramillo F 2016 J. Phys. Chem. C 120 16393

    [80]

    Pazoki M, Jacobsson T J, Hagfeldt A, Boschloo G, Edvinsson T 2016 Phys. Rev. B 93 144105

    [81]

    Filip M R, Giustino F 2016 J. Phys. Chem. C 120 166

    [82]

    Hamdeh U H, Nelson R D, Ryan B J, Bhattacharjee U, Petrich J W, Panthani M G 2016 Chem. Mater. 28 6567

    [83]

    Peresh E Y, Sidei V I, Zubaka O V, Stercho I P 2011 Inorg. Mater. 47 208

    [84]

    Maughan A E, Ganose A M, Bordelon M M, Miller E M, Scanlon D O, Neilson J R 2016 J. Am. Chem. Soc. 138 8453

    [85]

    Sakai N, Haghighirad A A, Filip M R, Nayak P K, Nayak S, Ramadan A, Wang Z, Giustino F, Snaith H J 2017 J. Am. Chem. Soc. 139 6030

    [86]

    Retuerto M, Emge T, Hadermann J, Stephens P W, Li M R, Yin Z P, Croft M, Ignatov A, Zhang S J, Yuan Z, Jin C, Simonson J W, Aronson M C, Pan A, Basov D N, Kotliar G, Greenblatt M 2013 Chem. Mater. 25 4071

    [87]

    Riggs S C, Shapiro M C, Corredor F, Geballe T H, Fisher I R, McCandless G T, Chan J Y 2012 J. Cryst. Growth 355 13

    [88]

    Slavney A H, Hu T, Lindenberg A M, Karunadasa H I 2016 J. Am. Chem. Soc. 138 2138

    [89]

    Volonakis G, Filip M R, Haghighirad A A, Sakai N, Wenger B, Snaith H J, Giustino F 2016 J. Phys. Chem. Lett. 7 1254

    [90]

    Volonakis G, Haghighirad A A, Milot R L, Sio W H, Filip M R, Wenger B, Johnston M B, Herz L M, Snaith H J, Giustino F 2017 J. Phys. Chem. Lett. 8 772

    [91]

    Zhao X G, Yang D, Sun Y, Li T, Zhang L, Yu L, Zunger A 2017 J. Am. Chem. Soc. 139 6718

    [92]

    Zhao X G, Yang J, Fu Y, Yang D, Xu Q, Yu L, Wei S H, Zhang L 2017 J. Am. Chem. Soc. 139 2630

    [93]

    McClure E T, Ball M R, Windl W, Woodward P M 2016 Chem. Mater. 28 1348

    [94]

    Greul E, Petrus M L, Binek A, Docampo P, Bein T 2017 J. Mater. Chem. A 5 19972

    [95]

    Feng H J, Deng W, Yang K, Huang J, Zeng X C 2017 J. Phys. Chem. C 121 4471

    [96]

    Kulkarni S A, Baikie T, Boix P P, Yantara N, Mathews N, Mhaisalkar S 2014 J. Mater. Chem. A 2 9221

    [97]

    Hao F, Stoumpos C C, Chang R P H, Kanatzidis M G 2014 J. Am. Chem. Soc. 136 8094

    [98]

    Liu C, Fan J, Li H, Zhang C, Mai Y 2016 Sci. Rep. 6 35705

    [99]

    Eperon G E, Leijtens T, Bush K A, Prasanna R, Green T, Wang J T W, McMeekin D P, Volonakis G, Milot R L, May R, Palmstrom A, Slotcavage D J, Belisle R A, Patel J B, Parrott E S, Sutton R J, Ma W, Moghadam F, Conings B, Babayigit A, Boyen H G, Bent S, Giustino F, Herz L M, Johnston M B, McGehee M D, Snaith H J 2016 Science 354 861

    [100]

    Ogomi Y, Morita A, Tsukamoto S, Saitho T, Fujikawa N, Shen Q, Toyoda T, Yoshino K, Pandey S S, Ma T, Hayase S 2014 J. Phys. Chem. Lett. 5 1004

    [101]

    Zuo F, Williams S T, Liang P W, Chueh C C, Liao C Y, Jen A K Y 2014 Adv. Mater. 26 6454

    [102]

    Zhu L, Yuh B, Schoen S, Li X, Aldighaithir M, Richardson B J, Alamer A, Yu Q 2016 Nanoscale 8 7621

    [103]

    Yang Z, Rajagopal A, Chueh C C, Jo S B, Liu B, Zhao T, Jen A K Y 2016 Adv. Mater. 28 8990

    [104]

    Liu X, Yang Z, Chueh C C, Rajagopal A, Williams S T, Sun Y, Jen A K Y 2016 J. Mater. Chem. A 4 17939

    [105]

    Yang Z, Rajagopal A, Jo S B, Chueh C C, Williams S, Huang C C, Katahara J K, Hillhouse H W, Jen A K Y 2016 Nano Lett. 16 7739

    [106]

    Zhu H L, Xiao J, Mao J, Zhang H, Zhao Y, Choy W C H 2017 Adv. Funct. Mater. 27 1605489

    [107]

    Li L, Zhang F, Hao Y, Sun Q, Li Z, Hua W, Cui Y, Zhu F 2017 J. Mater. Chem. C 5 2360

    [108]

    Mosconi E, Umaribc P, de Angelis F 2015 J. Mater. Chem. A 3 9208

    [109]

    Lin G, Lin Y, Huang H, Cui R, Guo X, Liu B, Dong J, Guo X, Sun B 2016 Nano Energy 27 638

    [110]

    Lyu M, Zhang M, Cooling N A, Jiao Y, Wang Q, Yun J H, Vaughan B, Triani G, Evans P, Zhou X, Feron K, Du A, Dastoor P, Wang L 2016 Sci. Bull. 61 1558

    [111]

    Li Y, Sun W, Yan W, Ye S, Rao H, Peng H, Zhao Z, Bian Z, Liu Z, Zhou H, Huang C 2016 Adv. Energy Mater. 6 1601353

    [112]

    Liu J, Wang G, Song Z, He X, Luo K, Ye Q, Liao C, Mei J 2017 J. Mater. Chem. A 5 9097

    [113]

    Xu X, Chueh C C, Yang Z, Rajagopal A, Xu J, Jo S B, Jen A K Y 2017 Nano Energy 34 392

    [114]

    Liao W, Zhao D, Yu Y, Shrestha N, Ghimire K, Grice C R, Wang C, Xiao Y, Cimaroli A J, Ellingson R J, Podraza N J, Zhu K, Xiong R G, Yan Y 2016 J. Am. Chem. Soc. 138 12360

    [115]

    Zhao D, Yu Y, Wang C, Liao W, Shrestha N, Grice C R, Cimaroli A J, Guan L, Ellingson R J, Zhu K, Zhao X, Xiong R G, Yan Y 2017 Nat. Energy 2 17018

    [116]

    Prez-del-Rey D, Forgcs D, Hutter E M, Savenije T J, Nordlund D, Schulz P, Berry J J, Sessolo M, Bolink H J 2016 Adv. Mater. 28 9839

    [117]

    Navas J, Snchez-Coronilla A, Gallardo J J, Hernndez N C, Piero J C, Alcntara R, Fernndez-Lorenzo C, de los Santos D M, Aguilar T, Martn-Calleja J 2015 Nanoscale 7 6216

    [118]

    Shai X, Zuo L, Sun P, Liao P, Huang W, Yao E P, Lia H, Liu S, Shen Y, Yang Y, Wang M 2017 Nano Energy 36 213

    [119]

    Zhang H, Wang H, Williams S T, Xiong D, Zhang W, Chueh C C, Chen W, Jen A K Y 2017 Adv. Mater. 29 1606608

    [120]

    Wang R, Zhang X, He J, Ma C, Xu L, Sheng P, Huang F 2017 J. Alloy. Compd. 695 555

    [121]

    Klug M T, Osherov A, Haghighirad A A, Stranks S D, Brown P R, Bai S, Wang J T W, Dang X, Bulovic V, Snaith H J, Belcher A M 2017 Energy Environ. Sci. 10 236

    [122]

    Williams S T, Rajagopal A, Jo S B, Chueh C C, Tang T F L, Kraegera A, Jen A K Y 2017 J. Mater. Chem. A 5 10640

    [123]

    Jahandar M, Heo J H, Song C E, Kong K J, Shin W S, Lee J C, Im S H, Moon S J 2016 Nano Energy 27 330

    [124]

    Shahbazi S, Tsai C M, Narra S, Wang C Y, Shiu H S, Afshar S, Taghavinia N, Diau E W G 2017 J. Phys. Chem. C 121 3673

    [125]

    Chen Q, Chen L, Ye F, Zhao T, Tang F, Rajagopal A, Jiang Z, Jiang S, Jen A K Y, Xie Y, Cai J, Chen L 2017 Nano Lett. 17 3231

  • [1] 姚鑫, 丁艳丽, 张晓丹, 赵颖. 钙钛矿太阳电池综述. 物理学报, 2015, 64(3): 038805. doi: 10.7498/aps.64.038805
    [2] 杨旭东, 陈汉, 毕恩兵, 韩礼元. 高效率钙钛矿太阳电池发展中的关键问题. 物理学报, 2015, 64(3): 038404. doi: 10.7498/aps.64.038404
    [3] 刘长文, 周讯, 岳文瑾, 王命泰, 邱泽亮, 孟维利, 陈俊伟, 齐娟娟, 董超. 金属氧化物基杂化型聚合物太阳电池研究. 物理学报, 2015, 64(3): 038804. doi: 10.7498/aps.64.038804
    [4] 许中华, 陈卫兵, 叶玮琼, 杨伟丰. 聚合物和小分子叠层结构有机太阳电池研究. 物理学报, 2014, 63(21): 218801. doi: 10.7498/aps.63.218801
    [5] 杜相, 陈思, 林东旭, 谢方艳, 陈建, 谢伟广, 刘彭义. 十二烷二酸修饰TiO2电子传输层改善钙钛矿太阳电池的电流特性. 物理学报, 2018, 67(9): 098801. doi: 10.7498/aps.67.20172779
    [6] 张钰, 周欢萍. 有机-无机杂化钙钛矿材料的本征稳定性. 物理学报, 2019, 68(15): 158804. doi: 10.7498/aps.68.20190343
    [7] 曾湘安, 艾斌, 邓幼俊, 沈辉. 硅片及其太阳电池的光衰规律研究. 物理学报, 2014, 63(2): 028803. doi: 10.7498/aps.63.028803
    [8] 曾隆月, 戴松元, 王孔嘉, 史成武, 孔凡太, 胡林华, 潘 旭. 染料敏化纳米ZnO薄膜太阳电池机理初探. 物理学报, 2005, 54(1): 53-57. doi: 10.7498/aps.54.53
    [9] 徐炜炜, 戴松元, 方霞琴, 胡林华, 孔凡太, 潘 旭, 王孔嘉. 电沉积处理与染料敏化纳米薄膜太阳电池的优化. 物理学报, 2005, 54(12): 5943-5948. doi: 10.7498/aps.54.5943
    [10] 戴松元, 孔凡太, 胡林华, 史成武, 方霞琴, 潘 旭, 王孔嘉. 染料敏化纳米薄膜太阳电池实验研究. 物理学报, 2005, 54(4): 1919-1926. doi: 10.7498/aps.54.1919
    [11] 翁 坚, 肖尚锋, 陈双宏, 戴松元. 大面积染料敏化太阳电池的实验研究. 物理学报, 2007, 56(6): 3602-3606. doi: 10.7498/aps.56.3602
    [12] 蔡宏琨, 陶科, 王林申, 赵敬芳, 隋妍萍, 张德贤. 柔性衬底非晶硅薄膜太阳电池界面处理的研究. 物理学报, 2009, 58(11): 7921-7925. doi: 10.7498/aps.58.7921
    [13] 黄阳, 戴松元, 陈双宏, 胡林华, 孔凡太, 寇东星, 姜年权. 大面积染料敏化太阳电池的串联阻抗特性研究. 物理学报, 2010, 59(1): 643-648. doi: 10.7498/aps.59.643
    [14] 寇东星, 刘伟庆, 胡林华, 黄阳, 戴松元, 姜年权. 电极表面改性对染料敏化太阳电池性能影响的机理研究. 物理学报, 2010, 59(8): 5857-5862. doi: 10.7498/aps.59.5857
    [15] 陈双宏, 翁坚, 王利军, 张昌能, 黄阳, 姜年权, 戴松元. 负偏压作用下染料敏化太阳电池界面及光电性能研究. 物理学报, 2011, 60(12): 128404. doi: 10.7498/aps.60.128404
    [16] 於黄忠, 周晓明, 邓俊裕. 热处理对不同溶剂制备的共混体系太阳电池性能影响. 物理学报, 2011, 60(7): 077206. doi: 10.7498/aps.60.077206
    [17] 方昕, 沈文忠. 多晶硅中的氧碳行为及其对太阳电池转换效率的影响. 物理学报, 2011, 60(8): 088801. doi: 10.7498/aps.60.088801
    [18] 曹宇, 张建军, 李天微, 黄振华, 马峻, 倪牮, 耿新华, 赵颖. 微晶硅锗太阳电池本征层纵向结构的优化. 物理学报, 2013, 62(3): 036102. doi: 10.7498/aps.62.036102
    [19] 韩安军, 孙云, 李志国, 李博研, 何静靖, 张毅, 刘玮. 低温超薄高效Cu(In, Ga)Se2太阳电池的实现. 物理学报, 2013, 62(4): 048401. doi: 10.7498/aps.62.048401
    [20] 郑雪, 余学功, 杨德仁. -Si:H/SiNx叠层薄膜对晶体硅太阳电池的钝化. 物理学报, 2013, 62(19): 198801. doi: 10.7498/aps.62.198801
  • 引用本文:
    Citation:
计量
  • 文章访问数:  1766
  • PDF下载量:  419
  • 被引次数: 0
出版历程
  • 收稿日期:  2017-09-04
  • 修回日期:  2017-09-30
  • 刊出日期:  2019-01-20

无铅和少铅的有机-无机杂化钙钛矿太阳电池研究进展

  • 1. 河南理工大学物理与电子信息学院, 焦作 454000;
  • 2. 郑州大学物理工程学院, 材料物理重点实验室, 郑州 450052
  • 通信作者: 陈永生, chysh2003@zzu.edu.cn
    基金项目: 

    国家自然科学基金(批准号:61574129)和河南省基础与前沿计划(批准号:152300410035)资助的课题.

摘要: 基于有机-无机杂化卤化铅材料的钙钛矿太阳电池的转换效率在短短几年内已迅速突破22%,为未来能源问题的解决带来了曙光,同时也引起了高度重视.但紧随其后的商品化、产业化发展需求极大地增加了对绿色、无毒的高效无铅钙钛矿太阳电池进行研究和开发的重要性和紧迫性.为进一步加快环境友好型钙钛矿太阳电池的研发进度,对目前无铅和少铅钙钛矿太阳电池的发展现状进行了综述.着重讨论了替代元素种类及其浓度、制备工艺等对薄膜和电池性能的影响,以期对电池的工作机理、替代元素的作用机理有更加深刻的认识,为新型环保、高效的钙钛矿太阳电池的制备提供指导.

English Abstract

参考文献 (125)

目录

    /

    返回文章
    返回