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Abstract: Polarons and bipolarons in mixed halide MX compounds were studied in the frame work of the two-band extended Peierls-Hubbard model.Different from the isolated MX chains,it was found that the segments tend to select impurities in mixed halide compounds.Then the charge confinement and the effect of electron-electron interactions were investigated.Finally the properties of impurities in mixed halide compounds with spontaneous charge transfer were also discussed.