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异常双钙钛矿A2BB'O6氧化物的多铁性

吴枚霞 李满荣

异常双钙钛矿A2BB'O6氧化物的多铁性

吴枚霞, 李满荣
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  • 异常钙钛矿结构氧化物是多铁性材料家族中研究得最为广泛的体系之一.本文从ABO3钙钛矿结构出发,引入了异常A2BB'O6双钙钛矿材料,首先简要介绍了传统及异常A2BB'O6双钙钛矿氧化物的结构特点;然后讨论了A2BB'O6多铁性材料的研究进展,包括A位为Mn,Ni等过渡金属离子的极性磁体多铁性材料和A2CoMnO6(A=Lu,Y,Yb,Lu)以及Mn2FeSbO6等第Ⅱ类多铁性材料;最后,在以上基础上展望了异常A2BB'O6双钙钛矿多铁性研究中存在的问题及新型多铁性材料研究的方向.
      通信作者: 李满荣, limanrong@mail.sysu.edu.cn
    • 基金项目: 国家青年千人计划资助的课题.
    [1]

    Tian G, Zhang F, Yao J, Fan H, Li P, Li Z, Song X, Zhang X, Qin M, Zeng M, Zhang Z, Yao J, Gao X, Liu J 2016 ACS Nano 10 1025

    [2]

    Li H B, Lu N, Zhang Q, Wang Y, Feng D, Chen T, Yang S, Duan Z, Li Z, Shi Y, Wang W, Wang W H, Jin K, Liu H, Ma J, Gu L, Nan C, Yu P 2017 Nat. Commun. 8 2156

    [3]

    Zhou L, Dai J, Chai Y, Zhang H, Dong S, Cao H, Calder S, Yin Y, Wang X, Shen X, Liu Z, Saito T, Shimakawa Y, Hojo H, Ikuhara Y, Azuma M, Hu Z, Sun Y, Jin C, Long Y 2017 Adv. Mater. 29 1703435

    [4]

    Yu P, Chu Y, Ramesh R 2012 Phil. Trans. R. Soc. A 370 4856

    [5]

    Zhao L, Lu Z, Zhang F, Tian G, Song X, Li Z, Huang K, Zhang Z, Qin M, Wu S, Lu X, Zeng M, Gao X, Dai J, Liu J 2015 Sci. Rep. 5 9680

    [6]

    Khomskii D 2009 Physics 2 20

    [7]

    Wang Y, Pascut G L, Gao B, Tyson T A, Haule K, Kiryukhin V, Cheong S W 2015 Sci. Rep. 5 12268

    [8]

    Caignaert V, Maignan A, Singh K, Simon C, Pralong V, Raveau B, Mitchell J F, Zheng H, Huq A, Chapon L C 2013 Phys. Rev. B 88 174403

    [9]

    Ghara S, Suard E, Fauth F, Tran T T, Halasyamani P S, Iyo A, Rodrg uez-Carvajal J, Sundaresan A 2017 Phys. Rev. B 95 224416

    [10]

    Chi Z H, Jin C Q 2007 Prog. Phys. 27 225 (in Chinese) [迟振华, 靳常青 2007 物理学进展 27 225]

    [11]

    Wang K F, Liu J M, Wang Y 2009 Prog. Phys. 29 215 (in Chinese) [段纯刚 2009 物理学进展 29 215]

    [12]

    Sun Y 2014 Physics 43 166 (in Chinese) [孙阳 2014 物理 43 166]

    [13]

    Cheong S W, Mostovoy M 2007 Nat. Mater. 6 13

    [14]

    Fiebig M 2005 J. Phys. D: Appl. Phys. 38 R123

    [15]

    Dong S, Xiang H J 2014 Physics 43 173 (in Chinese) [董帅, 向红军 2014 物理 43 173]

    [16]

    Liu J M, Nan C W 2014 Physics 43 88 (in Chinese) [刘俊明, 南策文 2014 物理 43 88]

    [17]

    Smolenskii G A, Chupis I E 1982 Sov. Phys. Usp. 25 475

    [18]

    Bokov V, Mylnikova I, Smolenskii G 1962 Sov. Phys. Jetp-Ussr 15 447

    [19]

    Ivanov S A, Tellgren R, Rundlof H, Thomas N W, Ananta S 2000 J. Phys.: Condens. Matter 12 2393

    [20]

    Wang J, Neaton J, Zheng H, Nagarajan V, Ogale S, Liu B, Viehland D, Vaithyanathan V, Schlom D, Waghmare U 2003 Science 299 1719

    [21]

    Dho J, Qi X, Kim H, MacManus-Driscoll J L, Blamire M G 2006 Adv. Mater. 18 1445

    [22]

    Azuma M, Takata K, Saito T, Ishiwata S, Shimakawa Y, Takano M 2005 J. Am. Chem. Soc. 127 8889

    [23]

    Nechache R, Cojocaru C V, Harnagea C, Nauenheim C, Nicklaus M, Ruediger A, Rosei F, Pignolet A 2011 Adv. Mater. 23 1724

    [24]

    Shi L, Bai F M 2011 J. Chin. Cera. Soc. 39 550 (in Chinese) [石雷, 白飞明 2011 硅酸盐学报 39 550]

    [25]

    Kwei G H, Lawson A C, Billinge S J L, Cheong S W 1993 J. Phys. Chem. 97 2368

    [26]

    Cai G H, Greenblatt M, Li M R 2017 Chem. Mater. 29 5447

    [27]

    Živkovi I, Pra K, Zaharko O, Berger H 2010 J. Phys.: Condens. Matter 22 056002

    [28]

    Oh Y S, Artyukhin S, Yang J J, Zapf V, Kim J W, Vanderbilt D, Cheong S W 2014 Nat. Commun. 5 3201

    [29]

    Ivanov S A, Mathieu R, Nordblad P, Tellgren R, Ritter C, Politova E, Kaleva G, Mosunov A, Stefanovich S, Weil M 2013 Chem. Mater. 25 935

    [30]

    Solana-Madruga E, Dos santos-Garcia A J, Arvalo-Lpez A M, vila-Brande D, Ritter C, Attfield J P, Sez-Puche R 2015 Dalton Trans. 44 20441

    [31]

    Li M R, McCabe E E, Stephens P W, Croft M, Collins L, Kalinin S V, Deng Z, Retuerto M, Gupta A S, Padmanabhan H, Gopalan V, Grams C P, Hemberger J, Orlandi F, Manuel P, Li W M, Jin C Q, Walker D, Greenblatt M 2017 Nat. Commun. 8 2037

    [32]

    Li M R, Croft M, Stephens P W, Ye M, Vanderbilt D, Retuerto M, Deng Z, Grams C P, Hemberger J, Hadermann J, Li W M, Jin C Q, Saouma F O, Jang J I, Akamatsu H, Gopalan V, Walker D, Greenblatt M 2015 Adv. Mater. 27 2177

    [33]

    Li M R, Walker D, Retuerto M, Sarkar T, Hadermann J, Stephens P W, Croft M, Ignatov A, Grams C P, Hemberger J, Nowik I, Halasyamani P S, Tran T T, Mukherjee S, Dasgupta T S, Greenblatt M 2013 Angew. Chem. Int. Ed. 52 8406

    [34]

    Li M R, Retuerto M, Walker D, Sarkar T, Stephens P W, Mukherjee S, Dasgupta T S, Hodges J P, Croft M, Grams C P, Hemberger J, Snchez-Bentez J, Huq A, Saouma F O, Jang J I, Greenblatt M 2014 Angew. Chem. Int. Ed. 53 10774

    [35]

    Li M R, Retuerto M, Stephens P W, Croft M, Sheptyakov D, Pomjakushin V, Deng Z, Akamatsu H, Gopalan V, Snchez-Bentez J, Saouma F O, Jang J I, Walker D, Greenblatt M 2016 Angew. Chem. Int. Ed. 128 10016

    [36]

    Li M R, Stephens P W, Retuerto M, Sarkar T, Grams C P, Hemberger J, Croft M C, Walker D, Greenblatt M 2014 J. Am. Chem. Soc. 136 8508

    [37]

    Wang P S, Ren W, Bellaiche L, Xiang H J 2015 Phys. Rev. Lett. 114 147204

    [38]

    Song G, Zhang W 2016 Sci. Rep. 6 20133

    [39]

    Zhao L, Du C H, Komarek A C 2017 Phys. Status Solidi: Rap. Res. Lett. 11 1700073

    [40]

    Ivanov S, Nordblad P, Mathieu R, Tellgren R, Politova E, Andr G 2011 Eur. J. Inorg. Chem. 2011 4691

    [41]

    Ye M, Vanderbilt D 2016 Phys. Rev. B 93 134303

    [42]

    Choi Y J, Yi H T, Lee S, Huang Q, Kiryukhin V, Cheong S W 2008 Phys. Rev. Lett. 100 047601

    [43]

    Tokura Y, Seki S, Nagaosa N 2014 Rep. Prog. Phys. 77 076501

    [44]

    Yez-Vilar S, Mun E D, Zapf V S, Ueland B G, Gardner J S, Thompson J D, Singleton J, Snchez-Andjar M, Mira J, Biskup N, Sears-Rodr guez M A, Batista C D 2011 Phys. Rev. B 84 134427

    [45]

    Sharma G, Saha J, Kaushik S, Siruguri V, Patnaik S 2013 Appl. Phys. Lett. 103 012903

    [46]

    Blasco J, Garca-Muoz J, Garca J, Stankiewicz J, Subas G, Ritter C, Rodrguez-Velamazn J 2015 Appl. Phys. Lett. 107 012902

    [47]

    Choi H Y, Moon J Y, Kim J H, Choi Y J, Lee N 2017 Crystals 7 67

    [48]

    Yi W, Princep A J, Guo Y, Johnson R D, Khalyavin D, Manuel P, Senyshyn A, Presniakov I A, Sobolev A V, Matsushita Y 2015 Inorg. Chem. 54 8012

    [49]

    Dos santos-Garca A J, Solana-Madruga E, Ritter C, Andrada-Chacn A, Snchez-Bentez J, Mompean F J, Garcia-Hernandez M, Sez-Puche R, Schmidt R 2017 Angew. Chem. Int. Ed. 129 4438

    [50]

    Mathieu R, Ivanov S A, Solovyev I V, Bazuev G V, Anil Kumar P, Lazor P, Nordblad P 2013 Phys. Rev. B 87 014408

    [51]

    Zhao H J, Ren W, Yang Y, iguez J, Chen X M, Bellaiche L 2014 Nat. Commun. 5 4021

  • [1]

    Tian G, Zhang F, Yao J, Fan H, Li P, Li Z, Song X, Zhang X, Qin M, Zeng M, Zhang Z, Yao J, Gao X, Liu J 2016 ACS Nano 10 1025

    [2]

    Li H B, Lu N, Zhang Q, Wang Y, Feng D, Chen T, Yang S, Duan Z, Li Z, Shi Y, Wang W, Wang W H, Jin K, Liu H, Ma J, Gu L, Nan C, Yu P 2017 Nat. Commun. 8 2156

    [3]

    Zhou L, Dai J, Chai Y, Zhang H, Dong S, Cao H, Calder S, Yin Y, Wang X, Shen X, Liu Z, Saito T, Shimakawa Y, Hojo H, Ikuhara Y, Azuma M, Hu Z, Sun Y, Jin C, Long Y 2017 Adv. Mater. 29 1703435

    [4]

    Yu P, Chu Y, Ramesh R 2012 Phil. Trans. R. Soc. A 370 4856

    [5]

    Zhao L, Lu Z, Zhang F, Tian G, Song X, Li Z, Huang K, Zhang Z, Qin M, Wu S, Lu X, Zeng M, Gao X, Dai J, Liu J 2015 Sci. Rep. 5 9680

    [6]

    Khomskii D 2009 Physics 2 20

    [7]

    Wang Y, Pascut G L, Gao B, Tyson T A, Haule K, Kiryukhin V, Cheong S W 2015 Sci. Rep. 5 12268

    [8]

    Caignaert V, Maignan A, Singh K, Simon C, Pralong V, Raveau B, Mitchell J F, Zheng H, Huq A, Chapon L C 2013 Phys. Rev. B 88 174403

    [9]

    Ghara S, Suard E, Fauth F, Tran T T, Halasyamani P S, Iyo A, Rodrg uez-Carvajal J, Sundaresan A 2017 Phys. Rev. B 95 224416

    [10]

    Chi Z H, Jin C Q 2007 Prog. Phys. 27 225 (in Chinese) [迟振华, 靳常青 2007 物理学进展 27 225]

    [11]

    Wang K F, Liu J M, Wang Y 2009 Prog. Phys. 29 215 (in Chinese) [段纯刚 2009 物理学进展 29 215]

    [12]

    Sun Y 2014 Physics 43 166 (in Chinese) [孙阳 2014 物理 43 166]

    [13]

    Cheong S W, Mostovoy M 2007 Nat. Mater. 6 13

    [14]

    Fiebig M 2005 J. Phys. D: Appl. Phys. 38 R123

    [15]

    Dong S, Xiang H J 2014 Physics 43 173 (in Chinese) [董帅, 向红军 2014 物理 43 173]

    [16]

    Liu J M, Nan C W 2014 Physics 43 88 (in Chinese) [刘俊明, 南策文 2014 物理 43 88]

    [17]

    Smolenskii G A, Chupis I E 1982 Sov. Phys. Usp. 25 475

    [18]

    Bokov V, Mylnikova I, Smolenskii G 1962 Sov. Phys. Jetp-Ussr 15 447

    [19]

    Ivanov S A, Tellgren R, Rundlof H, Thomas N W, Ananta S 2000 J. Phys.: Condens. Matter 12 2393

    [20]

    Wang J, Neaton J, Zheng H, Nagarajan V, Ogale S, Liu B, Viehland D, Vaithyanathan V, Schlom D, Waghmare U 2003 Science 299 1719

    [21]

    Dho J, Qi X, Kim H, MacManus-Driscoll J L, Blamire M G 2006 Adv. Mater. 18 1445

    [22]

    Azuma M, Takata K, Saito T, Ishiwata S, Shimakawa Y, Takano M 2005 J. Am. Chem. Soc. 127 8889

    [23]

    Nechache R, Cojocaru C V, Harnagea C, Nauenheim C, Nicklaus M, Ruediger A, Rosei F, Pignolet A 2011 Adv. Mater. 23 1724

    [24]

    Shi L, Bai F M 2011 J. Chin. Cera. Soc. 39 550 (in Chinese) [石雷, 白飞明 2011 硅酸盐学报 39 550]

    [25]

    Kwei G H, Lawson A C, Billinge S J L, Cheong S W 1993 J. Phys. Chem. 97 2368

    [26]

    Cai G H, Greenblatt M, Li M R 2017 Chem. Mater. 29 5447

    [27]

    Živkovi I, Pra K, Zaharko O, Berger H 2010 J. Phys.: Condens. Matter 22 056002

    [28]

    Oh Y S, Artyukhin S, Yang J J, Zapf V, Kim J W, Vanderbilt D, Cheong S W 2014 Nat. Commun. 5 3201

    [29]

    Ivanov S A, Mathieu R, Nordblad P, Tellgren R, Ritter C, Politova E, Kaleva G, Mosunov A, Stefanovich S, Weil M 2013 Chem. Mater. 25 935

    [30]

    Solana-Madruga E, Dos santos-Garcia A J, Arvalo-Lpez A M, vila-Brande D, Ritter C, Attfield J P, Sez-Puche R 2015 Dalton Trans. 44 20441

    [31]

    Li M R, McCabe E E, Stephens P W, Croft M, Collins L, Kalinin S V, Deng Z, Retuerto M, Gupta A S, Padmanabhan H, Gopalan V, Grams C P, Hemberger J, Orlandi F, Manuel P, Li W M, Jin C Q, Walker D, Greenblatt M 2017 Nat. Commun. 8 2037

    [32]

    Li M R, Croft M, Stephens P W, Ye M, Vanderbilt D, Retuerto M, Deng Z, Grams C P, Hemberger J, Hadermann J, Li W M, Jin C Q, Saouma F O, Jang J I, Akamatsu H, Gopalan V, Walker D, Greenblatt M 2015 Adv. Mater. 27 2177

    [33]

    Li M R, Walker D, Retuerto M, Sarkar T, Hadermann J, Stephens P W, Croft M, Ignatov A, Grams C P, Hemberger J, Nowik I, Halasyamani P S, Tran T T, Mukherjee S, Dasgupta T S, Greenblatt M 2013 Angew. Chem. Int. Ed. 52 8406

    [34]

    Li M R, Retuerto M, Walker D, Sarkar T, Stephens P W, Mukherjee S, Dasgupta T S, Hodges J P, Croft M, Grams C P, Hemberger J, Snchez-Bentez J, Huq A, Saouma F O, Jang J I, Greenblatt M 2014 Angew. Chem. Int. Ed. 53 10774

    [35]

    Li M R, Retuerto M, Stephens P W, Croft M, Sheptyakov D, Pomjakushin V, Deng Z, Akamatsu H, Gopalan V, Snchez-Bentez J, Saouma F O, Jang J I, Walker D, Greenblatt M 2016 Angew. Chem. Int. Ed. 128 10016

    [36]

    Li M R, Stephens P W, Retuerto M, Sarkar T, Grams C P, Hemberger J, Croft M C, Walker D, Greenblatt M 2014 J. Am. Chem. Soc. 136 8508

    [37]

    Wang P S, Ren W, Bellaiche L, Xiang H J 2015 Phys. Rev. Lett. 114 147204

    [38]

    Song G, Zhang W 2016 Sci. Rep. 6 20133

    [39]

    Zhao L, Du C H, Komarek A C 2017 Phys. Status Solidi: Rap. Res. Lett. 11 1700073

    [40]

    Ivanov S, Nordblad P, Mathieu R, Tellgren R, Politova E, Andr G 2011 Eur. J. Inorg. Chem. 2011 4691

    [41]

    Ye M, Vanderbilt D 2016 Phys. Rev. B 93 134303

    [42]

    Choi Y J, Yi H T, Lee S, Huang Q, Kiryukhin V, Cheong S W 2008 Phys. Rev. Lett. 100 047601

    [43]

    Tokura Y, Seki S, Nagaosa N 2014 Rep. Prog. Phys. 77 076501

    [44]

    Yez-Vilar S, Mun E D, Zapf V S, Ueland B G, Gardner J S, Thompson J D, Singleton J, Snchez-Andjar M, Mira J, Biskup N, Sears-Rodr guez M A, Batista C D 2011 Phys. Rev. B 84 134427

    [45]

    Sharma G, Saha J, Kaushik S, Siruguri V, Patnaik S 2013 Appl. Phys. Lett. 103 012903

    [46]

    Blasco J, Garca-Muoz J, Garca J, Stankiewicz J, Subas G, Ritter C, Rodrguez-Velamazn J 2015 Appl. Phys. Lett. 107 012902

    [47]

    Choi H Y, Moon J Y, Kim J H, Choi Y J, Lee N 2017 Crystals 7 67

    [48]

    Yi W, Princep A J, Guo Y, Johnson R D, Khalyavin D, Manuel P, Senyshyn A, Presniakov I A, Sobolev A V, Matsushita Y 2015 Inorg. Chem. 54 8012

    [49]

    Dos santos-Garca A J, Solana-Madruga E, Ritter C, Andrada-Chacn A, Snchez-Bentez J, Mompean F J, Garcia-Hernandez M, Sez-Puche R, Schmidt R 2017 Angew. Chem. Int. Ed. 129 4438

    [50]

    Mathieu R, Ivanov S A, Solovyev I V, Bazuev G V, Anil Kumar P, Lazor P, Nordblad P 2013 Phys. Rev. B 87 014408

    [51]

    Zhao H J, Ren W, Yang Y, iguez J, Chen X M, Bellaiche L 2014 Nat. Commun. 5 4021

  • 引用本文:
    Citation:
计量
  • 文章访问数:  2365
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出版历程
  • 收稿日期:  2018-04-26
  • 修回日期:  2018-05-19
  • 刊出日期:  2018-08-05

异常双钙钛矿A2BB'O6氧化物的多铁性

  • 1. 中山大学化学学院, 生物无机和合成化学教育部重点实验室, 广州 510275
  • 通信作者: 李满荣, limanrong@mail.sysu.edu.cn
    基金项目: 

    国家青年千人计划资助的课题.

摘要: 异常钙钛矿结构氧化物是多铁性材料家族中研究得最为广泛的体系之一.本文从ABO3钙钛矿结构出发,引入了异常A2BB'O6双钙钛矿材料,首先简要介绍了传统及异常A2BB'O6双钙钛矿氧化物的结构特点;然后讨论了A2BB'O6多铁性材料的研究进展,包括A位为Mn,Ni等过渡金属离子的极性磁体多铁性材料和A2CoMnO6(A=Lu,Y,Yb,Lu)以及Mn2FeSbO6等第Ⅱ类多铁性材料;最后,在以上基础上展望了异常A2BB'O6双钙钛矿多铁性研究中存在的问题及新型多铁性材料研究的方向.

English Abstract

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