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有机固体薄膜的交流电导

钱人元 金祥凤 周淑芹

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有机固体薄膜的交流电导

钱人元, 金祥凤, 周淑芹

A.C.CONDUCTANCE OF ORGANIC SOLID THIN FILMS

QIAN REN-YUAN, JIN XIANG-FENG, ZHOU SHU-QIN
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  • 本文讨论了有机固体薄膜交流电导的频率依赖性,指出在较高频率下,电导正比于频率两次方的依赖性,是由于电极接触电阻和薄膜电容所引致的假象。作者建议了一种外加串联电阻法来求取电极接触电阻值,从而使电导和电容的频率依赖性实验数据得到改正。提出了表征有机固体薄膜交流电导特性的三个参数,即在极低频下的直流电导率σd.c.值、在较高频区σ(f)∝fn中的n值和在lgσ-lgf图上高频区直线与σd.c.水平线的交点fx。对聚乙烯咔唑(
    The frequency dependence of A.C. conductance of organic solid thin films have been discussed. It is pointed out that the dependence of conductance on the square of frequency is an artifact due to the electrode contact resistance and the capacity of the film. In this paper a method of an added external resistance is proposed to evaluate the electrode contact resistance and thereby the experimentally measured frequency dependences of conductance and capacity of the film could be corrected for the effect of electrode contact resistance. In order to characterize the A.C. conductance of organic solid thin films three parameters are suggested. That is, the D.C. specific conductance σd.c. at extremely low frequencies, the exponent n in the expression σ(f)∝fn for the region of higher frequencies and the value of fx at which the straight line on the lgσ-lgf plot intersects the horizontal line σ=σd.c. For a solution cast film of poly-vinylcarbazole (PVK)-2,4,7-trinitrofluorenone (TNF) (1:0.75) charge transfer complex and an evaporated film of copper phthalocyanine (PcCu) the following results were obtained:PVK-TNF(1:0.75):σd.c.=1.9·10-16(Ω·cm)-1,n=0.96,fx=6.1·10-3Hz at 14℃, PcCu: σd.c.=1.6·10-9(Ω·cm)-1,n=1.2,fx=1·105Hz at 17℃.
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  • 文章访问数:  6345
  • PDF下载量:  424
  • 被引次数: 0
出版历程
  • 收稿日期:  1979-09-26
  • 刊出日期:  1980-04-05

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