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原子实极化效应对ScⅡ离子3d2三重态超精细相互作用的影响

习金华 吴礼金

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原子实极化效应对ScⅡ离子3d2三重态超精细相互作用的影响

习金华, 吴礼金

EFFECTS OF THE CORE POLARIZATIONS ON THE HYPER FINE INTERACTION OF THE TRIPLET (3d2)3P STATES OF ScII

XI JIN-HUA, WU LI-JIN
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  • 本文采用Rayleigh-Schr?dinger微扰方法计算钪离子ScII 3d2的三重态3P2和3P1的超精细相互作用常数,并与实验作比较,计算结果表明,原子实的极化(特别是自旋极化)效应对磁偶极常数有着决定性的影响。
    The hyperfine interaction constants of the triplet (3d2)3P states of Sell are calculated using Rayieigh-Schr?dinger perturbation method. The core polarizations are included to all orders using a recurrence formula and the correlations to low orders. The results are compared with experimental data and MCDF calculations of Young et al. It is found that the core polarization (especially the spin polarization) has drastic effects on the magnetic dipole interaction constant. Our results for constant A (MHz) are-116.667 and -12.442 for 3P1 and 3P2 states respectively, that of the experiments are-107.3(6) and -27.7(8), whereas the MCDF calculations of Young et al. obtained-1.8 and 85.9.
    • 基金项目: 本所波谱与原子分子物理开放研究实验室资助
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  • 文章访问数:  6820
  • PDF下载量:  638
  • 被引次数: 0
出版历程
  • 收稿日期:  1991-03-13
  • 刊出日期:  2005-07-03

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