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水热法合成纳米花状二硫化钼及其微观结构表征

傅重源 邢淞 沈涛 邰博 董前民 舒海波 梁培

水热法合成纳米花状二硫化钼及其微观结构表征

傅重源, 邢淞, 沈涛, 邰博, 董前民, 舒海波, 梁培
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  • 本文以钼酸钠、硫代乙酰胺为前驱体, 硅钨酸为添加剂, 成功用水热法合成高纯度纳米花状二硫化钼. 产物特性用X射线衍射(XRD)、能量色散谱(EDS)、扫描电子显微镜(SEM)进行表征. XRD和EDS图显示实验产物为二硫化钼, 且其结晶度和层状堆垛良好. SEM图谱则表明二硫化钼为纳米花状结构, 颗粒直径300 nm左右, 由几十上百片花瓣组成, 每片花瓣厚度十个纳米左右. 通过以硅钨酸为变量的梯度实验, 研究发现, 硅钨酸对于纳米花状MoS2的形成具有重要作用, 不添加硅钨酸, 无法形成纳米花状MoS2, 此外, 硅钨酸的剂量会影响合成MoS2的大小和形貌. 本文还对纳米花状二硫化钼的形成机理做了初步的讨论.
    • 基金项目: 国家自然科学基金(批准号: 61006051, 61177050)、浙江省大学生科技创新活动计划(批准号: 2013R409016)和浙江省科技厅公益技术应用研究(批准号: 2013C31068)资助的课题.
    [1]

    Guo S B, Kang Q P, Cai C B, Qu X H 2012 Rare Metals. 31 368

    [2]

    Guo H H, Yang T, Tao P, Zhang Z D 2014 Chin. Phys. B 23 017201

    [3]

    Zhou W, Yin Z Y, Du Y P, Huang X, Zeng Z Y, Fan Z X, Liu H, Wang J Y, Zhang H 2013 Small 9 140

    [4]

    Rapoport L, N Fleischer, R Tenne 2005 Journal of Materials Chemistry 15 1782

    [5]

    Whittingham M S 2004 Chemical Reviews 104 4271

    [6]

    Cheng F Y, Chen J 2006 Journal of Materials Research. 21 2744

    [7]

    Li Y G, Wang H L, Xie L M, Liang Y Y, Hong G S, Dai H J 2011 Journal of the American Chemical Society 133 7296

    [8]

    Frindt R F, Arrott, A S, Curzon A E, Heinrich B, Morrison S R, Templeton T L, Divigalpitiya R, Gee M A, Joensen P, Schurer P J 1991 Journal of Applied Physics 70 6224

    [9]

    Dong H H 2013 Acta Phys. Sin. 62 206101 (in Chinese) [董海明 2013 物理学报 62 206101]

    [10]

    Liu J, Liang P, Shu H B, Shen T, Xing S, Wu Q 2014 Acta Phys. Sin. 63 117101 (in Chinese) [刘俊, 梁培, 舒海波, 沈涛, 邢凇, 吴琼 2014 物理学报 63 117101]

    [11]

    Zhang Z J, Zhang J, Xue Q J 1994 Journal of Physical Chemistry. 98 12973

    [12]

    Li X M, Long M Q, Cui L L, Xiao J, Xu H 2014 Chin. Phys. B 23 047307

    [13]

    Li H, Yin Z Y, He Q Y, Li H, Huang X, Lu G, Fam Derrick, Wen H, Tok, Alfred I Y, Zhang Q, Zhang H 2012 Small 8 63

    [14]

    Radisavljevic B, Radenovic A, Brivio J, Giacometti V, Kis A 2011 Nature Nanotechnology. 6 147

    [15]

    Lopez-Sanchez O, Lembke D, Kayci M, Radenovic A, Kis A 2013 Nature Nanotechnology. 8 497

    [16]

    Xiang Q J, Yu J G, Jaroniec M 2012 Journal of the American Chemical Society 134 6575

    [17]

    Liu Y, Yu Y X, Zhang W D 2013 Journal of Physical Chemistry C 117 12949

    [18]

    Margulis L, Salitra G, Tenne R, Tallanker M 1993 Nature 365 113

    [19]

    Li W J, Shi E W, Ko J M, Chen Z Z, Ogino H, Fukuda T 2003 Journal of Crystal Growth. 250 418

    [20]

    Li Q, Walter E C, Van der Veer W E, Murray B J, Newberg J T, Bohannan E W, Switzer J A, Hemminger J C, Penner R M 2005 The Journal of Physical Chemistry B 109 3169

    [21]

    Chen J, Li S L, Xu Q, Tanaka K 2002 Chemical Communications. 16 1722

    [22]

    Albiter MA, Huirache-Acuna R, Paraguay-Delgado F, Rico JL, Alonso-Nunez G 2006 Nanotechnology. 17 3473

    [23]

    Dhas N A, Suslick K S 2005 Journal of the American Chemical Society. 127 2368

    [24]

    Li Y, Bando Y, Golberg D 2003 Applied Physics Letters. 82 1962

    [25]

    Novoselov KS, Jiang D, Schedin F, Booth TJ, Khotkevich VV, Morozov SV, Geim AK 2005 Proceedings of the National Academy of Sciences of the United States of America. 102 10451

    [26]

    Coleman J N, Lotya M, O'Neill A, Bergin S D, King P J, Khan U, Young K, Gaucher A, De S, Smith R J 2011 Science. 331 568

    [27]

    Castellanos-Gomez A, Barkelid M, Goossens AM, Calado V E, Van der Zant, H SJ 2012 Nano Letters. 12 3187

    [28]

    Helveg S, Lauritsen J V, Lægsgaard E, Stensgaard I, Nørskov J K, Clausen BS, Topsøe H, Besenbacher F 2000 Physical Review Letters 84 951

    [29]

    Najmaei S, Liu Z, Zhou W, Zou X L, Shi G, Lei S D, Yakobson B I, Idrobo J C, Ajayan P M, Lou J 2013 Nature Materials. 12 754

    [30]

    Chang K, Chen W 2011 ACS Nano. 5 4720

    [31]

    Yuan H J, Chen Y Q, Yu F, Peng Y H, He X W, Zhao D, Tang D S 2011 Chin. Phys. B 20 036103

    [32]

    Cundy C S, Cox P A 2003 Chemical Reviews 103 663

    [33]

    Tang G G, Sun J R, Wei C, Wu K Q, Ji X R, Liu S S, Tang H, Li C S 2012 Materials Letters 86 9

    [34]

    Yang J, Li C X, Quan Z W, Zhang C, Yang P, Li Y, Yu C, Lin J 2008 The Journal of Physical Chemistry C 112 12777

  • [1]

    Guo S B, Kang Q P, Cai C B, Qu X H 2012 Rare Metals. 31 368

    [2]

    Guo H H, Yang T, Tao P, Zhang Z D 2014 Chin. Phys. B 23 017201

    [3]

    Zhou W, Yin Z Y, Du Y P, Huang X, Zeng Z Y, Fan Z X, Liu H, Wang J Y, Zhang H 2013 Small 9 140

    [4]

    Rapoport L, N Fleischer, R Tenne 2005 Journal of Materials Chemistry 15 1782

    [5]

    Whittingham M S 2004 Chemical Reviews 104 4271

    [6]

    Cheng F Y, Chen J 2006 Journal of Materials Research. 21 2744

    [7]

    Li Y G, Wang H L, Xie L M, Liang Y Y, Hong G S, Dai H J 2011 Journal of the American Chemical Society 133 7296

    [8]

    Frindt R F, Arrott, A S, Curzon A E, Heinrich B, Morrison S R, Templeton T L, Divigalpitiya R, Gee M A, Joensen P, Schurer P J 1991 Journal of Applied Physics 70 6224

    [9]

    Dong H H 2013 Acta Phys. Sin. 62 206101 (in Chinese) [董海明 2013 物理学报 62 206101]

    [10]

    Liu J, Liang P, Shu H B, Shen T, Xing S, Wu Q 2014 Acta Phys. Sin. 63 117101 (in Chinese) [刘俊, 梁培, 舒海波, 沈涛, 邢凇, 吴琼 2014 物理学报 63 117101]

    [11]

    Zhang Z J, Zhang J, Xue Q J 1994 Journal of Physical Chemistry. 98 12973

    [12]

    Li X M, Long M Q, Cui L L, Xiao J, Xu H 2014 Chin. Phys. B 23 047307

    [13]

    Li H, Yin Z Y, He Q Y, Li H, Huang X, Lu G, Fam Derrick, Wen H, Tok, Alfred I Y, Zhang Q, Zhang H 2012 Small 8 63

    [14]

    Radisavljevic B, Radenovic A, Brivio J, Giacometti V, Kis A 2011 Nature Nanotechnology. 6 147

    [15]

    Lopez-Sanchez O, Lembke D, Kayci M, Radenovic A, Kis A 2013 Nature Nanotechnology. 8 497

    [16]

    Xiang Q J, Yu J G, Jaroniec M 2012 Journal of the American Chemical Society 134 6575

    [17]

    Liu Y, Yu Y X, Zhang W D 2013 Journal of Physical Chemistry C 117 12949

    [18]

    Margulis L, Salitra G, Tenne R, Tallanker M 1993 Nature 365 113

    [19]

    Li W J, Shi E W, Ko J M, Chen Z Z, Ogino H, Fukuda T 2003 Journal of Crystal Growth. 250 418

    [20]

    Li Q, Walter E C, Van der Veer W E, Murray B J, Newberg J T, Bohannan E W, Switzer J A, Hemminger J C, Penner R M 2005 The Journal of Physical Chemistry B 109 3169

    [21]

    Chen J, Li S L, Xu Q, Tanaka K 2002 Chemical Communications. 16 1722

    [22]

    Albiter MA, Huirache-Acuna R, Paraguay-Delgado F, Rico JL, Alonso-Nunez G 2006 Nanotechnology. 17 3473

    [23]

    Dhas N A, Suslick K S 2005 Journal of the American Chemical Society. 127 2368

    [24]

    Li Y, Bando Y, Golberg D 2003 Applied Physics Letters. 82 1962

    [25]

    Novoselov KS, Jiang D, Schedin F, Booth TJ, Khotkevich VV, Morozov SV, Geim AK 2005 Proceedings of the National Academy of Sciences of the United States of America. 102 10451

    [26]

    Coleman J N, Lotya M, O'Neill A, Bergin S D, King P J, Khan U, Young K, Gaucher A, De S, Smith R J 2011 Science. 331 568

    [27]

    Castellanos-Gomez A, Barkelid M, Goossens AM, Calado V E, Van der Zant, H SJ 2012 Nano Letters. 12 3187

    [28]

    Helveg S, Lauritsen J V, Lægsgaard E, Stensgaard I, Nørskov J K, Clausen BS, Topsøe H, Besenbacher F 2000 Physical Review Letters 84 951

    [29]

    Najmaei S, Liu Z, Zhou W, Zou X L, Shi G, Lei S D, Yakobson B I, Idrobo J C, Ajayan P M, Lou J 2013 Nature Materials. 12 754

    [30]

    Chang K, Chen W 2011 ACS Nano. 5 4720

    [31]

    Yuan H J, Chen Y Q, Yu F, Peng Y H, He X W, Zhao D, Tang D S 2011 Chin. Phys. B 20 036103

    [32]

    Cundy C S, Cox P A 2003 Chemical Reviews 103 663

    [33]

    Tang G G, Sun J R, Wei C, Wu K Q, Ji X R, Liu S S, Tang H, Li C S 2012 Materials Letters 86 9

    [34]

    Yang J, Li C X, Quan Z W, Zhang C, Yang P, Li Y, Yu C, Lin J 2008 The Journal of Physical Chemistry C 112 12777

  • 引用本文:
    Citation:
计量
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出版历程
  • 收稿日期:  2014-06-12
  • 修回日期:  2014-08-20
  • 刊出日期:  2015-01-05

水热法合成纳米花状二硫化钼及其微观结构表征

  • 1. 中国计量学院, 光学与电子科技学院, 杭州 310018
    基金项目: 

    国家自然科学基金(批准号: 61006051, 61177050)、浙江省大学生科技创新活动计划(批准号: 2013R409016)和浙江省科技厅公益技术应用研究(批准号: 2013C31068)资助的课题.

摘要: 本文以钼酸钠、硫代乙酰胺为前驱体, 硅钨酸为添加剂, 成功用水热法合成高纯度纳米花状二硫化钼. 产物特性用X射线衍射(XRD)、能量色散谱(EDS)、扫描电子显微镜(SEM)进行表征. XRD和EDS图显示实验产物为二硫化钼, 且其结晶度和层状堆垛良好. SEM图谱则表明二硫化钼为纳米花状结构, 颗粒直径300 nm左右, 由几十上百片花瓣组成, 每片花瓣厚度十个纳米左右. 通过以硅钨酸为变量的梯度实验, 研究发现, 硅钨酸对于纳米花状MoS2的形成具有重要作用, 不添加硅钨酸, 无法形成纳米花状MoS2, 此外, 硅钨酸的剂量会影响合成MoS2的大小和形貌. 本文还对纳米花状二硫化钼的形成机理做了初步的讨论.

English Abstract

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