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核壳结构磁性复合纳米材料的可控合成与性能

何学敏 钟伟 都有为

核壳结构磁性复合纳米材料的可控合成与性能

何学敏, 钟伟, 都有为
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  • 具有核/壳结构的磁性复合纳米材料是十分重要的功能材料,其综合物性受材料微结构的影响,而这很大程度上又取决于复合体系的可控合成.本文综述了近二十年来有关核/壳磁性复合纳米材料的制备、表征及性能研究方面的进展,讨论的体系主要有:铁氧体基永磁/软磁(反铁磁)复合纳米材料、非磁性体包覆磁性核而成的复合纳米材料、用磁性颗粒催化合成的碳基复合纳米材料、基于交换偏置效应而设计的复合纳米材料、核-壳同轴结构的一维复合纳米材料和核/壳/壳三元结构的磁性复合纳米材料等.构建复合体系的组分包括M型永磁铁氧体、3d过渡金属(及其合金、氧化物、碳化物)、多铁化合物、非磁性体(比如绝缘体、半导体、有机分子)和碳材料等,着重分析了复合纳米材料的热稳定性、光致发光性能、光电催化能力、电化学特性、微波吸收性能、磁电阻效应、永磁体性能、高频软磁特性、交换偏置效应及其相关现象.最后,对核/壳结构磁性复合纳米材料的未来发展趋势进行了展望,并在基础研究和改性应用方面提出了一些建议.
      通信作者: 钟伟, wzhong@nju.edu.cn
    • 基金项目: 国家自然科学基金(批准号:11604160,11774156,11474151)、江苏省自然科学基金(批准号:BK20160876)、南京大学固体微结构物理国家重点实验室(批准号:M30007)和南京邮电大学基金(批准号:NY215063)资助的课题.
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  • 收稿日期:  2018-05-28
  • 修回日期:  2018-08-27
  • 刊出日期:  2019-11-20

核壳结构磁性复合纳米材料的可控合成与性能

  • 1. 南京邮电大学理学院信息物理研究中心, 南京 210023;
  • 2. 南京大学, 固体微结构物理国家重点实验室, 南京 210093
  • 通信作者: 钟伟, wzhong@nju.edu.cn
    基金项目: 

    国家自然科学基金(批准号:11604160,11774156,11474151)、江苏省自然科学基金(批准号:BK20160876)、南京大学固体微结构物理国家重点实验室(批准号:M30007)和南京邮电大学基金(批准号:NY215063)资助的课题.

摘要: 具有核/壳结构的磁性复合纳米材料是十分重要的功能材料,其综合物性受材料微结构的影响,而这很大程度上又取决于复合体系的可控合成.本文综述了近二十年来有关核/壳磁性复合纳米材料的制备、表征及性能研究方面的进展,讨论的体系主要有:铁氧体基永磁/软磁(反铁磁)复合纳米材料、非磁性体包覆磁性核而成的复合纳米材料、用磁性颗粒催化合成的碳基复合纳米材料、基于交换偏置效应而设计的复合纳米材料、核-壳同轴结构的一维复合纳米材料和核/壳/壳三元结构的磁性复合纳米材料等.构建复合体系的组分包括M型永磁铁氧体、3d过渡金属(及其合金、氧化物、碳化物)、多铁化合物、非磁性体(比如绝缘体、半导体、有机分子)和碳材料等,着重分析了复合纳米材料的热稳定性、光致发光性能、光电催化能力、电化学特性、微波吸收性能、磁电阻效应、永磁体性能、高频软磁特性、交换偏置效应及其相关现象.最后,对核/壳结构磁性复合纳米材料的未来发展趋势进行了展望,并在基础研究和改性应用方面提出了一些建议.

English Abstract

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