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Stereodynamics study of the reactions of He+H+2 and its isotopic variants

Kong Hao Liu Xin-Guo Xu Wen-Wu Liang Jing-Juan Zhang Qing-Gang

Stereodynamics study of the reactions of He+H+2 and its isotopic variants

Kong Hao, Liu Xin-Guo, Xu Wen-Wu, Liang Jing-Juan, Zhang Qing-Gang
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Publishing process
  • Received Date:  04 November 2008
  • Accepted Date:  21 January 2009
  • Published Online:  05 May 2009

Stereodynamics study of the reactions of He+H+2 and its isotopic variants

  • 1. 山东师范大学物理与电子科学学院,济南 250014

Abstract: The stereodynamics in the chemical reaction He+H+2 and its isotopic variants at the collision energy of 145 kJ/mol have been studied by using the quasi-classical trajectory (QCT) method on AQUILANTI surface. The correlated k-j′, k-k′-j′ angular distributions, and the product rotational alignment are discussed in detail. The calculations indicate that the stereodynamics of the reactions of He+HH+→HeH++H, He+HD+→HeH++D and He+HT+→HeH++T are sensitive to the mass factor and the repulsive energy of diatomic molecule.

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