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Isotope interchange reaction dynamics of the T+OD system

Zhu Zhi-Yan Zhu Zheng-He Zhang Li Li Pei-Gang Tang Wei-Hua Zheng Ying-Ying

Isotope interchange reaction dynamics of the T+OD system

Zhu Zhi-Yan, Zhu Zheng-He, Zhang Li, Li Pei-Gang, Tang Wei-Hua, Zheng Ying-Ying
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  • Received Date:  22 November 2010
  • Accepted Date:  06 July 2011
  • Published Online:  05 June 2011

Isotope interchange reaction dynamics of the T+OD system

  • 1. Center for Optoelectronics Materials and Devices, Zhejiang Sci-Tech University, Hangzhou 310018, China;
  • 2. Institute of Atomic and Molecular Physics, Sichuan University, Chengdu 610065, China

Abstract: The atomic and molecular reaction dynamics for T+OD have been studied basad on the potential energy function of DTO(1 A1) by Monte Carlo quasi-classical trajectory approach. It is shown that the reaction T+ODDTO with a long-lived complex has a threshold energy at low collision energy, which accords with the potential curve. The interchange reaction increases with collision energy increasing, until the DTO molecules decompose into D, T, and O completely, and these reactions have threshold energyies too. The trajectories and the collision cross-sections of T+OD(0, 0) and D+OT(0, 0) are different due to the isotopic effect of D atom and T atom.

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