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LASER-INDUCED FLUORESCENCE EXCIATION SPECTRUM OF OXALYL CHLORIDE

LU QING-ZHENG CHEN YANG TANG SONG-BAI MA XING-XIAO

LASER-INDUCED FLUORESCENCE EXCIATION SPECTRUM OF OXALYL CHLORIDE

LU QING-ZHENG, CHEN YANG, TANG SONG-BAI, MA XING-XIAO
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  • Received Date:  20 August 1990
  • Published Online:  05 March 1991

LASER-INDUCED FLUORESCENCE EXCIATION SPECTRUM OF OXALYL CHLORIDE

  • 1. 中国科学技术大学近代化学系,合肥,230026

Abstract: Laser-induced fluorescence excitation spectrum of oxalyl cholride (C2O2Cl2) in the rang of 358-372.5nm has been observed. More than 60 vibrational transitions have been assigned, in which 24 bands were not found in absorption spectrum. From the vibrational structure, we obtained some of the vibrational frequencies in ground state and excited state in which v"7=84cm-1 and v'7= 164cm-1 are new data. The rotational analysis of high resolved 401 band leads to the rotational constants A = 0.190cm-1, B = 0.114cm-1, and C = 0.048cm-1.

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