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Glansdorff-Prigogine判据与最小熵产生定理

陈式刚

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Glansdorff-Prigogine判据与最小熵产生定理

陈式刚

GLANSDORFF-PRIGOGINE CRITERION AND THEOREM OF MINIMUM ENTROPY PRODUCTION

CHEN SHI-GANG
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  • 起因于Graham和Landauer的批评,我们在本文中讨论了Glansdorff-Prigogine判据和最小熵产生定理的应用范围及实用价值问题。文中指出Glansdorff-Prigogine判据作为热力学理论是严格的,但在多变量的实际问题中没有实用价值。同时指出最小熵产生定理的应用范围比线性非平衡热力学中其他定理的适用范围要小得多,因此把它作为一个原理是不恰当的。但是Landauer对最小熵产生定理的批评是错误的。
    Initiated from Graham's and Landauer's criticism, we discuss the problem of applicable range and practical value of the Glansdorff-Prigogine criterion and of the theorem of minimum entropy production in this paper. We point out that the Glansd-orff-Prigogine criterion as a thermodynamic theory is rigorous, but in the practical problem of many variables, it has no applicable value. And, the applicable range of the theorem of minimum entropy production is much smaller than that of other theorem's in the linear non-equilibrium thermodynamics, therefore, to use it as a principle is not adequate. But landauer's criticism about the theorem of minimum entropy production is wrong.
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出版历程
  • 收稿日期:  1980-01-11
  • 刊出日期:  1980-05-05

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