搜索

x

留言板

尊敬的读者、作者、审稿人, 关于本刊的投稿、审稿、编辑和出版的任何问题, 您可以本页添加留言。我们将尽快给您答复。谢谢您的支持!

姓名
邮箱
手机号码
标题
留言内容
验证码

氧空位对Eu2+, Dy3+掺杂的Ca5MgSi3O12发光及余辉性能的影响

龚宇 陈柏桦 熊亮萍 古梅 熊洁 高小铃 罗阳明 胡胜 王育华

引用本文:
Citation:

氧空位对Eu2+, Dy3+掺杂的Ca5MgSi3O12发光及余辉性能的影响

龚宇, 陈柏桦, 熊亮萍, 古梅, 熊洁, 高小铃, 罗阳明, 胡胜, 王育华

Effect of oxygen vacancies on the fluorescence and phosphorescence properties of Ca5MgSi3O12:Eu2+, Dy3+

Gong Yu, Chen Bai-Hua, Xiong Liang-Ping, Gu Mei, Xiong Jie, Gao Xiao-Ling, Luo Yang-Ming, Hu Sheng, Wang Yu-Hua
PDF
导出引用
  • 利用高温固相法合成了稀土离子Eu2+, Dy3+掺杂的Ca5MgSi3O12长余辉发光材料. 利用光谱学证明了在材料内部存在与氧空位有关的缺陷发光. 通过对比不同条件下合成样品的发光及余辉性能, 发现氧空位对材料的发光及余辉均起到促进作用. 同时发现氧空位发光可以向发光中心传递能量. 利用热释光曲线系统的分析了氧空位对余辉性能的影响. Ca5MgSi3O12:Eu2+,Dy3+是一种潜在的长余辉发光材料.
    Ca5MgSi3O12:Eu2+, Dy3+ was synthesized by solid-state reaction. The luminescence center related to the oxygen vacancies existed in the host matrix. Comparing the fluorescence and phosphorescence properties of samples synthesized under different air condiction, we find that the oxygen vacancies played an important role in the fluorescence and phosphorescence properties. Oxygen vacancies can transfer its energy to the luminescence center. Thermoluminescence spectra were used to characterize the effect of oxygen vacancies on the phosphorescence properties. Ca5MgSi3O12:Eu2+,Dy3+ has a great potential to become a promising candidate to be used as long-lasting phosphors.
    • 基金项目: 中国工程物理研究院科技发展基金(批准号: 2013B0301037)资助的课题.
    • Funds: Project supported by the Science and Technology Funds of China Academy of Engineering Physics (Grant No. 2013B0301037).
    [1]

    Yang Z P, Liu Y F 2006 Acta Phys. Sin. 55 4946 (in Chinese) [杨志平, 刘玉峰 2006 物理学报 55 4946]

    [2]

    Liao Q R, Zhuang W D, Xia T, Liu R H, Hu Y S, Teng X M, Liu Y H 2009 Acta Phys. Sin. 58 2776 (in Chinese) [廖秋荣, 庄卫东, 夏天, 刘荣辉, 胡运生, 滕晓明, 刘元红 2009 物理学报 58 2776]

    [3]

    Yang Z P, Liu Y F, Wang L W, Yu Q M, Xiong Z J, Xu X L 2007 Acta Phys. Sin. 56 546 (in Chinese) [杨志平, 刘玉峰, 王利伟, 余泉茂, 熊志军, 徐小岭 2007 物理学报 56 546]

    [4]

    Wang Z J, Li P L, Wang G, Yang Z P, Guo Q L 2008 Acta Phys. Sin. 57 4575 (in Chinese) [王志军, 李盼来, 王刚, 杨志平, 郭庆林 2008 物理学报 57 4575]

    [5]

    Jia D, Meltzer R S, Yen W M, Jia W, Wang X J 2002 Appl. Phys. Lett. 80 1535

    [6]

    Tavangarian F, Emadi R 2011 Materials Letter 65 2354

    [7]

    Anthony J W, Bideaux R A, Bladh K W, Nichols M C 1990 Handbook of mineralogy (Mineral Data Publishing Tucson, Arizona)

    [8]

    Mardare C, Mardare A, Fernandes J, Joanni E, Pina S, Fernandes M, Correia R 2003 Journal of the European Ceramic Society 23 1027

    [9]

    Vitale-Brovarone C, Nunzio S D, Bretcanu O, Vern E 2004 Journal of Materials Science: Materials in Medicine 15 209

    [10]

    Kobayashi T, Okada K, Kuroda T, Sato K 1997 Journal of Biomedical Materials Research 37 100

    [11]

    Ryu H S, Hong K S, Lee J K, Kim D J, Lee J H, Chang B S, Lee D, Lee C K, Chung S S 2004 Biomaterials 25 393

    [12]

    Hannan M T, Felson D T, Dawsonughes B, Tucker K L, Cupples L A, Wilson P W F, Kiel D P 2000 Journal of Bone and Mineral Research 15 710

    [13]

    Sojka J, Weaver C 1995 Nutr Rev. 53 71

    [14]

    Stendig-Lindberg G, Tepper R, Leichter I 1993 Magnesium research: official organ of the International Society for the Development of Research on Magnesium 6 155

    [15]

    Sripanyakorn S, Jugdaohsingh R, Elliott H, Walker C, Mehta P, Shoukru S, Thompson R P H, Powell J J 2004 British Journal of Nutrition 91 403

    [16]

    Zhang E, Yang L, Xu J, Chen H 2003 Acta Biomaterialia 6 1756

    [17]

    Jiang L, Chang C, Mao D, Feng C 2004 Optical Materials 27 51

    [18]

    Wang B, Sun L, Ju H, Zhao S, Deng D, Wang H, Xu S 2009 Materials Letter 63 1329

    [19]

    Allen P B, Perebeinos V 1999 Phys. Rev. Lett. 83 4828

    [20]

    Liu Y, Kuang J, Lei B, Shi C 2005 J. Mater. Chem. 15 4025

    [21]

    Wang W, Jiang C, Shen M, Fang L, Zheng F, Wu X 2009 J. Appl. Phys. Lett. 94 081904

    [22]

    Dexter D, Schulman J H 1954 The Journal of Chemical Physics 22 1063

    [23]

    Lin Y, Tang Z, Zhang Z, Nan C W 2002 Appl. Phys. Lett. 81 996

    [24]

    Kinoshita T, Yamazaki M, Kawazoe H, Hosono H 1999 Journal of Applied Physics 86 3729

    [25]

    Aitasalo T, Deren P, Hls J, Jungner H, Krupa J C, Lastusaari M, Legendziewicz J, Niittykoski J, Strek W 2003 Journal of Solid State Chemistry 171 114

  • [1]

    Yang Z P, Liu Y F 2006 Acta Phys. Sin. 55 4946 (in Chinese) [杨志平, 刘玉峰 2006 物理学报 55 4946]

    [2]

    Liao Q R, Zhuang W D, Xia T, Liu R H, Hu Y S, Teng X M, Liu Y H 2009 Acta Phys. Sin. 58 2776 (in Chinese) [廖秋荣, 庄卫东, 夏天, 刘荣辉, 胡运生, 滕晓明, 刘元红 2009 物理学报 58 2776]

    [3]

    Yang Z P, Liu Y F, Wang L W, Yu Q M, Xiong Z J, Xu X L 2007 Acta Phys. Sin. 56 546 (in Chinese) [杨志平, 刘玉峰, 王利伟, 余泉茂, 熊志军, 徐小岭 2007 物理学报 56 546]

    [4]

    Wang Z J, Li P L, Wang G, Yang Z P, Guo Q L 2008 Acta Phys. Sin. 57 4575 (in Chinese) [王志军, 李盼来, 王刚, 杨志平, 郭庆林 2008 物理学报 57 4575]

    [5]

    Jia D, Meltzer R S, Yen W M, Jia W, Wang X J 2002 Appl. Phys. Lett. 80 1535

    [6]

    Tavangarian F, Emadi R 2011 Materials Letter 65 2354

    [7]

    Anthony J W, Bideaux R A, Bladh K W, Nichols M C 1990 Handbook of mineralogy (Mineral Data Publishing Tucson, Arizona)

    [8]

    Mardare C, Mardare A, Fernandes J, Joanni E, Pina S, Fernandes M, Correia R 2003 Journal of the European Ceramic Society 23 1027

    [9]

    Vitale-Brovarone C, Nunzio S D, Bretcanu O, Vern E 2004 Journal of Materials Science: Materials in Medicine 15 209

    [10]

    Kobayashi T, Okada K, Kuroda T, Sato K 1997 Journal of Biomedical Materials Research 37 100

    [11]

    Ryu H S, Hong K S, Lee J K, Kim D J, Lee J H, Chang B S, Lee D, Lee C K, Chung S S 2004 Biomaterials 25 393

    [12]

    Hannan M T, Felson D T, Dawsonughes B, Tucker K L, Cupples L A, Wilson P W F, Kiel D P 2000 Journal of Bone and Mineral Research 15 710

    [13]

    Sojka J, Weaver C 1995 Nutr Rev. 53 71

    [14]

    Stendig-Lindberg G, Tepper R, Leichter I 1993 Magnesium research: official organ of the International Society for the Development of Research on Magnesium 6 155

    [15]

    Sripanyakorn S, Jugdaohsingh R, Elliott H, Walker C, Mehta P, Shoukru S, Thompson R P H, Powell J J 2004 British Journal of Nutrition 91 403

    [16]

    Zhang E, Yang L, Xu J, Chen H 2003 Acta Biomaterialia 6 1756

    [17]

    Jiang L, Chang C, Mao D, Feng C 2004 Optical Materials 27 51

    [18]

    Wang B, Sun L, Ju H, Zhao S, Deng D, Wang H, Xu S 2009 Materials Letter 63 1329

    [19]

    Allen P B, Perebeinos V 1999 Phys. Rev. Lett. 83 4828

    [20]

    Liu Y, Kuang J, Lei B, Shi C 2005 J. Mater. Chem. 15 4025

    [21]

    Wang W, Jiang C, Shen M, Fang L, Zheng F, Wu X 2009 J. Appl. Phys. Lett. 94 081904

    [22]

    Dexter D, Schulman J H 1954 The Journal of Chemical Physics 22 1063

    [23]

    Lin Y, Tang Z, Zhang Z, Nan C W 2002 Appl. Phys. Lett. 81 996

    [24]

    Kinoshita T, Yamazaki M, Kawazoe H, Hosono H 1999 Journal of Applied Physics 86 3729

    [25]

    Aitasalo T, Deren P, Hls J, Jungner H, Krupa J C, Lastusaari M, Legendziewicz J, Niittykoski J, Strek W 2003 Journal of Solid State Chemistry 171 114

  • [1] 续卓, 郭竞渊, 熊正烨, 唐强, 高沐. 掺Tm3+和Tb3+的LiMgPO4磷光体的发光光谱与能量转移. 物理学报, 2021, 70(16): 167801. doi: 10.7498/aps.70.20210357
    [2] 王泽普, 付念, 于涵, 徐晶威, 何祺, 郑树凯, 丁帮福, 闫小兵. 铟掺杂钨位增强钨酸铋氧空位光催化效率. 物理学报, 2019, 68(21): 217102. doi: 10.7498/aps.68.20191010
    [3] 刘盛意, 张金苏, 孙佳石, 陈宝玖, 李香萍, 徐赛, 程丽红. 实验优化设计Sr2MgSi2O7:Eu2+, Dy3+的合成及长余辉特性. 物理学报, 2019, 68(5): 053301. doi: 10.7498/aps.68.20182015
    [4] 栗苹, 许玉堂. 氧空位迁移造成的氧化物介质层时变击穿的蒙特卡罗模拟. 物理学报, 2017, 66(21): 217701. doi: 10.7498/aps.66.217701
    [5] 吴丽, 王倩, 李国栋, 窦巧娅, 吉旭. 不同退火温度的Al2O3:C薄膜热释光和光释光性能. 物理学报, 2016, 65(3): 037802. doi: 10.7498/aps.65.037802
    [6] 蒋然, 杜翔浩, 韩祖银, 孙维登. Ti/HfO2/Pt阻变存储单元中的氧空位聚簇分布. 物理学报, 2015, 64(20): 207302. doi: 10.7498/aps.64.207302
    [7] 罗达玲, 唐强, 郭竞渊, 张纯祥. MSO4:Eu2+(M =Mg, Ca, Sr, Ba)的等电子陷阱与热释光特性. 物理学报, 2015, 64(8): 087805. doi: 10.7498/aps.64.087805
    [8] 程帅, 徐旭辉, 王鹏久, 邱建备. 新型电子俘获型材料β-Sr2SiO4:Eu2+, La3+长余辉和光激励发光性能的研究. 物理学报, 2015, 64(1): 017802. doi: 10.7498/aps.64.017802
    [9] 王鹏久, 徐旭辉, 邱建备, 周大成, 刘雪娥, 程帅. 高亮度蓝绿色长余辉材料Ba4 (Si3O8)2:Eu2+, Pr3+的发光性能及其余辉机理研究. 物理学报, 2014, 63(7): 077804. doi: 10.7498/aps.63.077804
    [10] 谢伟, 王银海, 全军, 邹长伟, 梁枫, 邵乐喜. H3BO3对Y1.98O3:Eu0.01, Dy0.01红色长余辉发光材料结构和余辉性能的影响. 物理学报, 2014, 63(1): 016101. doi: 10.7498/aps.63.016101
    [11] 沈庆鹤, 高志伟, 丁怀义, 张光辉, 潘楠, 王晓平. Ga掺杂对ZnO纳米结构可见光发射的抑制效应. 物理学报, 2012, 61(16): 167105. doi: 10.7498/aps.61.167105
    [12] 胡克艳, 李红军, 徐军, 杨秋红, 苏良碧, 唐强. 不同粒径-Al2O3:C晶态粉体热释光和光释光特性. 物理学报, 2012, 61(15): 157802. doi: 10.7498/aps.61.157802
    [13] 李海玲, 王银海, 张万鑫, 王显盛, 赵慧. Eu3+掺杂CaO的合成与红色长余辉发光性能研究. 物理学报, 2012, 61(22): 227802. doi: 10.7498/aps.61.227802
    [14] 谢伟, 王银海, 胡义华, 张军, 邹长伟, 李达, 邵乐喜. Sr0.6Ba0.2Ca0.2Al2O4 ∶Eu,Dy的制备与长余辉发光性能研究. 物理学报, 2011, 60(6): 067801. doi: 10.7498/aps.60.067801
    [15] 牟中飞, 王银海, 胡义华, 吴浩怡, 邓柳咏, 谢伟, 符楚君, 廖臣兴. Y3Al5O12∶Ce3+的余辉和热释光特性. 物理学报, 2011, 60(1): 013201. doi: 10.7498/aps.60.013201
    [16] 张斌, 张浩佳, 杨秋红, 陆神洲. α-Al2O3透明陶瓷的发光及热释光特性. 物理学报, 2010, 59(2): 1333-1337. doi: 10.7498/aps.59.1333
    [17] 谢伟, 王银海, 胡义华, 罗莉, 吴浩怡, 邓柳咏. Y2O3: Eu,Dy的制备与红色长余辉发光性能研究. 物理学报, 2010, 59(5): 3344-3349. doi: 10.7498/aps.59.3344
    [18] 杨新波, 李红军, 徐 军, 程 艳, 苏良碧, 唐 强. α-Al2O3:C晶体的热释光和光释光特性. 物理学报, 2008, 57(12): 7900-7905. doi: 10.7498/aps.57.7900
    [19] 张纯祥, 唐强, 罗达玲. CaSO4∶Eu磷光体的热释光特性研究. 物理学报, 2002, 51(12): 2881-2886. doi: 10.7498/aps.51.2881
    [20] 刘波, 施朝淑, 周东方, 戚泽明, 胡关钦, 汤洪高. 掺Gd3+,Y3+对PbWO_4低温热释光的影响. 物理学报, 2001, 50(8): 1627-1631. doi: 10.7498/aps.50.1627
计量
  • 文章访问数:  5559
  • PDF下载量:  840
  • 被引次数: 0
出版历程
  • 收稿日期:  2013-01-08
  • 修回日期:  2013-04-24
  • 刊出日期:  2013-08-05

/

返回文章
返回