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高压PECVD技术沉积硅基薄膜过程中硅烷状态的研究

侯国付 薛俊明 孙 建 郭群超 张德坤 任慧志 赵 颖 耿新华 李乙钢

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高压PECVD技术沉积硅基薄膜过程中硅烷状态的研究

侯国付, 薛俊明, 孙 建, 郭群超, 张德坤, 任慧志, 赵 颖, 耿新华, 李乙钢

Research on silane depletion status during the deposition of silicon thin films by high-pressure PECVD

Hou Guo-Fu, Xue Jun-Ming, Sun Jian, Guo Qun-Chao, Zhang De-Kun, Ren Hui-Zhi, Zhao Ying, Geng Xin-Hua, Li Yi-Gang
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  • 采用高压射频等离子体增强化学气相沉积(RF-PECVD)方法在不同功率下制备了一系列硅薄膜材料,研究了材料晶化率和生长速度随功率变化的规律, 进而研究PECVD方法沉积硅薄膜过程中的硅烷反应状态,并提出可以根据硅烷耗尽程度的不同将硅烷反应状态分为未耗尽、耗尽和过耗尽三种.然后,对不同硅烷反应状态下的材料结构、光电性能以及相应的电池进行了研究,并指出适合于太阳电池本征层的高质量微晶硅材料应该沉积在硅烷耗尽状态.
    In this paper a series of hydrogenated silicon thin films were prepared by high-pressure radio frequency plasma enhanced chemical vapor deposition (RF-PECVD) using various plasma powers. The influence of plasma power on Raman crystallinity and deposition rate was investigated to study the silane depletion level during the deposition of silicon thin films. Based on these results the status of silane depletion were classified as un-depleted, depleted and over-depleted status. Additionally, the structural and opto-electrical properties were also investigated for those materials deposited under different silane depletion status. The results demonstrated that the μc-Si:H films, which are deposited at depleted status, have good opto-electrical properties and are suitable for application as intrinsic layers in solar cells.
    • 基金项目: 国家重点基础研究发展计划(973)项目(批准号:2006CB202602,2006CB202603)、南开大学博士启动基金(批准号:J02033)和国家教育部光电信息技术科学重点实验室(批准号:2005-18)资助的课题.
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  • 文章访问数:  8360
  • PDF下载量:  1456
  • 被引次数: 0
出版历程
  • 收稿日期:  2006-01-23
  • 修回日期:  2006-07-05
  • 刊出日期:  2007-01-05

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