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TaN/TiN和NbN/TiN纳米结构多层膜超硬效应及超硬机理研究

喻利花 董师润 许俊华 李戈扬

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TaN/TiN和NbN/TiN纳米结构多层膜超硬效应及超硬机理研究

喻利花, 董师润, 许俊华, 李戈扬

Superhardness effect of TaN/TiN and NbN/TiN nanostructure multilayers and its mechanism

Yu Li-Hua, Dong Shi-Run, Xu Jun-Hua, Li Ge-Yang
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  • 采用射频磁控溅射方法制备单层TaN,NbN和TiN薄膜和不同调制周期的TaN/TiN和NbN/TiN纳米多层膜.薄膜采用X射线衍射仪、高分辨率透射电子显微镜和显微硬度仪进行表征.结果表明TaN/TiN和NbN/TiN纳米多层膜在一定的调制周期范围内均呈共格界面,相应地均出现了超硬效应,且最大硬度值接近.分析了TaN/TiN与NbN/TiN纳米多层膜的超硬机理,TaN/TiN的晶格错配度与NbN/TiN的接近,但TaN/TiN的弹性模量差与NbN/TiN的有一定的差别,表明由于晶格错配使共格外延生长在界面处
    Monolithic TaN,NbN, TiN films and TaN/TiN, NbN/TiN multilayers with different modulation periods were prepared by reactive magnetic sputtering. The films were characterized by X-ray diffraction, high-resolution transmission electron microscopy and nanoindentation. Results showed that there are coherent interfaces between the layers of TaN and TiN in TaN/TiN multilayers and the layers of NbN and TiN in NbN/TiN multilayers within a modulation period. The superhardness effect happened and the maximum hardness values of the two multilayers are nearly equal. The superhardness mechanism was discussed. The lattices mismatch between NbN/TiN and TaN/TiN multilayers is similar, but the difference in modulus of NbN/TiN multilayers is larger than that of TaN/TiN multilayers. It shows that stress field induced by coherent epitaxial growth is the main reason of superhardness effect.
    • 基金项目: 国家自然科学基金(批准号:50574044)资助的课题.
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  • 文章访问数:  8051
  • PDF下载量:  1168
  • 被引次数: 0
出版历程
  • 收稿日期:  2008-01-16
  • 修回日期:  2008-04-28
  • 刊出日期:  2008-11-20

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