-
本文计算了25个含Eu3+离子的晶体中由于晶场效应引起的Eu3+离子的5(DJ),7(FJ)能级的位移和5D,7F谱项能级劈裂的加宽,分析了电子云扩大效应引起的能级位移与实验测量值的关系,并给出这些晶体中电子云扩大效应大小的正确次序。In this paper, the shifts of 5DJ and 7FJ energy levels of Eu3+ ion caused by crystal field effect, are calculated in 25 hosts containing Eu3+ ions. The relation between the calculated shifts and experimental values are analysed. The correct order on nephelauxetic effect shifts in these hosts is given.
计量
- 文章访问数: 6660
- PDF下载量: 643
- 被引次数: 0
下载:
