Ionic conductivity and activation volume of bulk sample and comprssed powder disc of amorphous lithium ionic conductor B2O3-0.7Li2O-0.7LiCl-xAl2O3 (x= 0.05, 0.15) in the hydros-tatie pressure range of 0.0001-1.23 GPa were investigated. We found that the peak of conductivity of compressed powder disc consisted of contact conductivity and bulk conductivity. For hydrostatic pressure dependence of ionic conductivity of the bulk sample, a preliminary microscopic explanation was obtained by considering the physical picture of ionic transport passages. In addition, we observed that decrease of the content of alumina lowers the pressure of conductivity maximum. Variation of ionic conductivity with pressure was measured after heating samples at different temperature or at 300℃ for 4-20 hours. The behaviors were due to the amorphous phase separation and successive crystallization process of the two amorphous phases.