结构自还原效应对铋掺碱土金属硅磷铝硼玻璃超宽带近红外发光的影响

李永进; 宋志国; 李臣; 万荣华; 邱建备; 杨正文; 尹兆益; 王雪; 王齐; 周大成; 杨勇

doi:10.7498/aps.62.117801

摘要

本文报道了结构自还原对铋掺杂碱土金属硅磷铝硼玻璃超宽带近红外发光性质的影响. 以Eu作为对比, 在空气气氛中采用高温熔融法分别制备了Eu2O3和Bi2O3掺杂的35SiO2-25AlPO4-12.5Al2O3-12.5B2O3-15RO(R=Ca,Sr,Ba) 玻璃. 结果证实该玻璃中可发生Eu3+→Eu2+的高温自还原现象, 且随着碱土金属离子半径增大Eu2+ 的自还原性减弱; 同样条件下Bi位于1300 nm波段的近红外发光却随之增强, 而位于1100 nm波段近红外发光和源于Bi2+的红光则减弱. 根据结构自还原机理及碱土离子半径变化对玻璃近红外超宽带发光性质的影响, 讨论了Bi离子的近红外发光中心的归属. 上述研究表明玻璃结构自还原特性可以为Bi近红外发光机理研究以及高效Bi掺杂超宽带近红外发光玻璃的设计提供一种有效的思路和方法.

关键词:

Abstract

We report the effects of self-reduction of glass matrix on the broadband near infrared (NIR) emissions from Bi-doped alkali earth aluminoborosilicate glasses. Bi2O3 -doped as well as Eu2O3, -doped as a comparison, 35SiO2-25AlPO4-12.5Al2O3-12.5B2O3-15RO (R=Ca,Sr,Ba) glasses were prepared in air. Results show that the self-reduction process of Eu3+→Eu2+ occurs in this glass matrix. Meanwhile the intensity of NIR emission peaked at about 1300nm increases with the increase in the radius of alkali earth ions, while the intensity of both NIR emission peaked at about 1100nm and the red emission from Bi2+decreases. Then the origins of infrared-emitting bismuth centers were discussed according to the correlation of the conversion of Bi ions with the size of alkali earth ions. The results of this work is helpful for understanding the nature of Bi-NIR-emission and may be a guide for the selection of composition of high performance Bi-doped glass.

Keywords:

作者及机构信息

1.
昆明理工大学材料科学与工程学院, 昆明 650093;

2.
昆明理工大学, 教育部稀贵及有色金属先进材料教育部重点实验室, 昆明 650093

基金项目: 国家重点基础研究发展计划973项目(批准号: 2011CB211708)、国家自然科学基金(批准号: 61265007)和云南省自然科学基金资助项目(批准号: 2012FD010)资助的课题.

Authors and contacts

1.
School of Materials Science and Engineering, Kunming University of Science and Technology, Kunming 650093, China;

2.
Key Lab of Advanced Materials in Rare & Precious and nonferrous Metals, Ministry of Education, Kunming University of Science and Technology, Kunming 650093, China

Funds: Project supported by the National Basic Research Program of China (Grant No. 2011CB211708), the National Natural Science Foundation of China (Grant No. 61265007), and the Natural Science Foundation of Yunnan Province, China (Grant No. 2012FD010).

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施引文献

[1]	Dong G P, Xiao X D, Ren J J, Ruan J, Liu X F, Qiu J R, Lin C G, Tao H Z, Zhao X J 2008 Chinese Physics Letters 25 1891
[2]	Peng M, Chen D, Qiu J, Jiang X, Zhu C 2007 Opt. Mater. 29 556
[3]	Arai Y, Suzuki T, Ohishi Y, Morimoto S, Khonthon S 2007 Appl. Phys. Lett. 90 261110
[4]	Zhou S, Feng G, Bao J, Yang H, Qiu J 2007 J. Mater. Res. 22 1435
[5]	Hughes M, Suzuki T, Ohishi Y 2008 JOSA B 25 1380
[6]	Hughes M A, Suzuki T, Ohishi Y 2010 Opt. Mater. 32 1028
[7]	Hughes M A, Akada T, Suzuki T, Ohishi Y, Hewak D W 2009 Opt. Express 17 19345
[8]	Peng M, Dong G, Wondraczek L, Zhang L, Zhang N, Qiu J 2011J. Non-Cryst. Solids 357 2241
[9]	Zhou S, Jiang N, Zhu B, Yang H, Ye S, Lakshminarayana G, Hao J, Qiu J 2008 Adv. Funct. Mater. 18 1407
[10]	Liu J F, Su L B, Tang H L, Xu J 2012 Acta Phys. Sin. 61127806 (in Chinese) [刘军芳, 苏良碧, 唐慧丽, 徐军 2012 物理学报 61 127806]
[11]	Zhou D C, Liu Z L, Song Z G, Yang Z W, He X J, Wang R F, Jiao Q, Qiu J B 2012 Acta Phys. Sin. 61 127802 (in Chinese) [周大成, 刘志亮, 宋志国, 杨正文, 何禧佳, 王荣飞, 焦清, 邱建备 2012 物理学报 61 127802]
[12]	Fujimoto Y 2009 J. Am. Ceram. Soc. 93 581
[13]	Peng M, Zollfrank C, Wondraczek L 2009 Journal of Physics: Condensed Matter 21 285106
[14]	Peng M, Sprenger B, Schmidt M A, Schwefel H L, Wondraczek L 2010 Opt. Express 18 12852
[15]	Khonthon S, Morimoto S, Arai Y, Ohishi Y 2007 Journal of the Ceramic Society of Japan 115 259
[16]	Sharonov M Y, Bykov A B, Petricevic V, Alfano R R 2008 Opt. Lett. 33 2131
[17]	Duffy J A 1996 J. Non-Cryst. Solids 196 45
[18]	Peng M, Wu B, Da N, Wang C, Chen D, Zhu C, Qiu J 2008 J. Non-Cryst. Solids 354 1221
[19]	Liu S, Zhao G, Ruan W, Yao Z, Xie T, Jin J, Ying H, Wang J, Han G 2008 J. Am. Ceram. Soc. 91 2740
[20]	Zhang C, Yang J, Lin C, Li C, Lin J 2009 Eur. J. Solid State Inorg. Chem. 182 1673
[21]	Su Q, Zeng Q H, Pei Z W 2000 Chinese Journal of Inorganic Chemistry 16 293 (in Chinese) [苏锵, 曾庆华, 裴治武 2000 无机化学学报 16 293]
[22]	Wang C, Peng M, Jiang N, Jiang X, Zhao C, Qiu J 2007 J. Mater. Sci. Lett. 61 3608
[23]	Peng M, Hong G 2007 J. Lumin. 127 735
[24]	Peng M, Pei Z, Hong G, Su Q 2003 J. Mater. Chem. 13 1202
[25]	Xu J, Zhao H, Su L, Yu J, Zhou P, Tang H, Zheng L, Li H 2010 Opt. Express 18 3385
[26]	Su L, Yu J, Zhou P, Li H, Zheng L, Yang Y, Wu F, Xia H, Xu J 2009 Opt. Lett. 34 2504
[27]	Okhrimchuk A G, Butvina L N, Dianov E M, Lichkova N V, Zagorodnev V N, Boldyrev K N 2008 Opt. Lett. 33 2182
[28]	Su L, Zhao H, Li H, Zheng L, Ren G, Xu J, Ryba-Romanowski W, Lisiecki R, Solarz P 2011 Opt. Lett. 36 4551
[29]	Zhou P, Su L B, Li H J, Yu J, Zheng L H, Yang Q H, Xu J 2010 Acta Phys. Sin. 59 2827 (in Chinese) [周朋, 苏良碧, 李红军, 喻军, 郑丽和, 杨秋红, 徐军 2010 物理学报 59 2827]
[30]	Lian Z, Wang J, Lv Y, Wang S, Su Q 2007 J. Alloys Compd. 430 257
[31]	Zhang Q, Liu X, Qiao Y, Qian B, Dong G, Ruan J, Zhou Q, Qiu J, Chen D 2010 Opt. Mater. 32 427
[32]	Yang Z W, Liu Z L, Song Z W, Zhou D C, Yin Z Y, Zhu K, Qiu J B 2011 J. Alloys Compd. 509 6816
[33]	Ren J, Qiu J, Wu B, Chen D 2007 Journal of materials research 22 1574
[34]	Song Z G, Li C, Li Y J, Yang Z W, Zhou D C, Yin Z Y, Wang Q, Yang Y, Zhao Z Y, Yu X 2012 Mater. Res. Bull. 48 260
[35]	Kustov E F, Bulatov L, Dvoyrin V V, Mashinsky V M 2009 Opt. Lett. 34 1549
[36]	Zheng J, Peng M, Kang F, Cao R, Ma Z, Dong G, Qiu J, Xu S 2012 Opt. Express 20 22569

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