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本文计算了顺磁物质CeF, 因Ce离子从基态能级4 f 至s d 的电偶极跃迁产生的F a r a d a y 旋转. 讨论晶场对Ce 离子4 f 和s d 能级的影响, 通过唯象地引入一个与磁化强度M成正比的“附加磁场”H=M,由此获得4 t 离子在外加磁场和“ 附加磁场” 的共同作用下的一级Ze e m a n 分裂. 经劈裂后的两个子能级上各自产生左、右圆偏振光激发的电偶极跃迁, 导致磁光F a r a d a y 效应.对于波长为0.6 3 2 8 微米 的人射光, 在60 一如OK 温度范围内计算得到的ver det 常数和磁化率能够较好地与实验相符.The Faraday rotation caused by electronic transitions between the 4f and 5d states of Ce ions in paramagnetic CeF_3_ crystals is calculated. The crystal field is an important perturbation on the energy levels. An external magnetic field, together with an additive magnetic field introduced phenomenologically in our paper, would spilt every 4f state into two sublevels. The dipole transitions between these sublevels, and 5d states induce the Faradap effect. The Verdet constant at 0.6328 um in the temperature range of 60-300K is obtained. It is shown that our calculation is in good agreement with experiment.
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