We have studied the properties of the spontaneous emission from a two-level atom embedded in two-band photonic crystals. Due to the anisotropic two-band dispersion relation, the localized and propagating fields cannot coexist, this leads to the non-quasi-oscillation behaviour of the upper level population. Thus the upper level population will tend to a constant as time goes to infinity, or decay with time in a power law, or decay with time exponentially, different from that in the isotropic one-band dispersion relation case. These properties are directly related to the relative position of the upper level from the band edge and the width of the gap.