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Eu3+掺杂Gd2W2O9和Gd2(WO4)3纳米荧光粉发光性质研究

冯晓辉 孟庆裕 孙江亭 吕树臣 孙立男

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Eu3+掺杂Gd2W2O9和Gd2(WO4)3纳米荧光粉发光性质研究

冯晓辉, 孟庆裕, 孙江亭, 吕树臣, 孙立男

Luminescent properties of Eu3+ doped Gd2W2O9 and Gd2(WO4)3 nanophosphors

Feng Xiao-Hui, Meng Qing-Yu, Sun Jiang-Ting, Lü Shu-Chen, Sun Li-nan
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  • 采用共沉淀法制备了不同Eu3+掺杂浓度的Gd2W2O9和Gd2(WO4)3纳米发光材料.通过对纳米材料样品的X射线衍射谱(XRD)和场发射扫描电镜(FE-SEM)照片的观察和分析,对样品的结构和形貌进行了表征.测量了各样品的发射光谱、激发光谱,计算了各样品的部分J-O参数和Eu3+ 5D
    Eu3+ doped Gd2W2O9 and Gd2(WO4)3 nanophosphors with different concentrations were prepared via a co-precipitation method. The structure and morphology of the nanocrystal samples were characterized by using X-ray diffraction (XRD) and field emission scanning electron microscopy (FE-SEM). The emission spectra and excitation spectra of the samples were measured, the J-O parameters and the quantum efficiencies of the 5D0 level of Eu3+ of the samples were calculated, and the concentration quenching curves of Eu3+ luminescence in different hosts were given. The study results indicate that similar to the Gd2(WO4)3:Eu, the red emission of Eu3+ 5D0 → 7F2 transition in Gd2W2O9:Eu can also be effectively excited by 395 nm near-UV light and 465 nm blue light. So the Gd2W2O9:Eu red phosphors may have a potential application for white light emitting diodes.
    • 基金项目: 国家自然科学基金(批准号:51002041),黑龙江省自然科学基金(批准号:A200812),黑龙江省科技厅2009年度高新技术攻关项目(批准号:09A405),黑龙江省教育厅科学技术研究计划(批准号:11551148),哈尔滨师范大学青年学术骨干资助计划(批准号:KGB200811) 资助的课题.
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    Jia M L, Zhang J H, Lu S Z, Sun J T, Luo Y S, Ren X G, Song H W and Wang X J 2004 Chem. Phys. Lett. 384 193

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    Song H W, Chen B J, Peng H S, Zhang J S 2002 Appl. Phys. Lett. 81 1776

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    Zhao C H,Zhang B P, Shang P P 2009 Chin. Phys. B 18 5539

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    Kodaira C A, Brito H F, Malta O L, Serra O A 2003 J. Lumin. 101 11

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    Kodaira C A, Brito H F, Felinto M C F C 2003 J. Solid State Chem. 171 401

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    Jia P Y, Liu X M, Yu M, Luo Y, Fang J, Lin J 2006 Chem. Phys. Lett. 424 358

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    Pullar R C, Farrah S, Alford N McN 2007 Journal of the European Ceramic Society 27 1059

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    Kodaira C A, Brito H F, Teotonio E E S, Felinto M C F C, Malta O L, Brito G E S 2004 J. Braz. Chem. Soc. 15 890

    [18]

    Wang Y G, Ma J F, Tao J T, Zhu X Y, Zhou J, Zhao Z Q, Xie L J, Tian H 2007 Ceramics International 33 1125

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    Fu H B,.Pan C S, Zhang L W, Zhu Y F 2007 Mater. Res. Bull. 42 696

    [20]

    Di W H, Wang X J, Chen B J, Lu S Z, Zhao X X 2005 J. Phys. Chem. B 109 13154

    [21]

    He C, Guan Y F, Yao L Z, Cai W L, Lia X G, Yao Z 2003 Mater. Res. Bull. 38 973

    [22]

    Huang Y H, Jiang D L, Zhang J X, Lin Q L 2010 Acta Phys. Sin. 59 300(in Chinese) [黄毅华、江东亮、张景贤、林庆玲 2010 物理学报 59 300]

    [23]

    Jiang B X, Huang T D, Wu Y S, Liu W B, Pan Y B, Feng T, Yang Q H 2008 Chin. Phys. B 17 3407

    [24]

    Judd B R 1962 Phys. Rev. 127 750

    [25]

    Ofelt G S 1962 J. Chem. Phys. 37 511

    [26]

    Ray S, Pramanik P, Singha A, Roy A 2005 J. Appl. Phys. 97 094312

    [27]

    Nishimura G, Kushida T 1988 Phys. Rev. B 37 9075

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    Reisfeld R, Greenberg E, Brown R N, Drexhage M G, Jφrgensen C K 1983 Chem. Phys. Lett. 95 91

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    Tian Y, Qi X H, Wu X W, Hua R N, Chen B J 2009 J. Phys. Chem. C 113 10767

  • [1]

    Wan Y, Han W J, Liu J H, Xia L H, Mateos X, Petrov V, Zhang H J, Wang J Y 2009 Acta Phys. Sin. 58 278(in Chinese) [万 勇、韩文娟、刘均海、夏临华、Xavier Mateos、Valentin Petrov、张怀金、王继扬 2009 物理学报 58 278]

    [2]

    Zang J C, Zheng K, Zou Y L, Wu J P, Song Y R, Liu G Q, Feng B H, Zhang D X, Liu Y L, Zhu K 2010 Acta Phys. Sin. 59 609(in Chinese) [臧竞存、郑 锴、邹玉林、吴敬朋、宋晏蓉、刘国庆、冯宝华、张东香、刘玉龙、朱 恪 2010 物理学报 59 609]

    [3]

    Chen G X, Zhang Q Y, Zhao C, Shi D M, Jiang Z H 2010 Acta Phys. Sin. 59 1321(in Chinese) [陈敢新、张勤远、赵 纯、石冬梅、姜中宏 2010 物理学报 59 1321]

    [4]

    Vodchits A I, Orlovich V A, Apanasevich P A, Basiev T T, Zverev P G 2007 Opt. Mater. 29 1616

    [5]

    Huang J P, H. S. Luo, Zhou P L, Yu X B, Li Y K 2007 J. Lumin. 126 881

    [6]

    Ryu J H, Bang S Y, Kim W S, Park G S, Kim K M, Yoon J W, Shim K B, Koshizaki N 2007 J. Alloys Compd. 441 146

    [7]

    Longo V M, Orhan E, Cavalcante L S, Porto S L, Espinosa J W M, Varela J A, Longo E 2007 Chem. Phys. 334 180

    [8]

    Bhargava R N, Gallagher D, Hong X, Nurmikko A 1994 Phys. Rev. Lett. 72 416

    [9]

    Bhargava R N 1996 J. Lumin. 70 85

    [10]

    Jia M L, Zhang J H, Lu S Z, Sun J T, Luo Y S, Ren X G, Song H W and Wang X J 2004 Chem. Phys. Lett. 384 193

    [11]

    Song H W, Chen B J, Peng H S, Zhang J S 2002 Appl. Phys. Lett. 81 1776

    [12]

    Zhao C H,Zhang B P, Shang P P 2009 Chin. Phys. B 18 5539

    [13]

    Kodaira C A, Brito H F, Malta O L, Serra O A 2003 J. Lumin. 101 11

    [14]

    Kodaira C A, Brito H F, Felinto M C F C 2003 J. Solid State Chem. 171 401

    [15]

    Jia P Y, Liu X M, Yu M, Luo Y, Fang J, Lin J 2006 Chem. Phys. Lett. 424 358

    [16]

    Pullar R C, Farrah S, Alford N McN 2007 Journal of the European Ceramic Society 27 1059

    [17]

    Kodaira C A, Brito H F, Teotonio E E S, Felinto M C F C, Malta O L, Brito G E S 2004 J. Braz. Chem. Soc. 15 890

    [18]

    Wang Y G, Ma J F, Tao J T, Zhu X Y, Zhou J, Zhao Z Q, Xie L J, Tian H 2007 Ceramics International 33 1125

    [19]

    Fu H B,.Pan C S, Zhang L W, Zhu Y F 2007 Mater. Res. Bull. 42 696

    [20]

    Di W H, Wang X J, Chen B J, Lu S Z, Zhao X X 2005 J. Phys. Chem. B 109 13154

    [21]

    He C, Guan Y F, Yao L Z, Cai W L, Lia X G, Yao Z 2003 Mater. Res. Bull. 38 973

    [22]

    Huang Y H, Jiang D L, Zhang J X, Lin Q L 2010 Acta Phys. Sin. 59 300(in Chinese) [黄毅华、江东亮、张景贤、林庆玲 2010 物理学报 59 300]

    [23]

    Jiang B X, Huang T D, Wu Y S, Liu W B, Pan Y B, Feng T, Yang Q H 2008 Chin. Phys. B 17 3407

    [24]

    Judd B R 1962 Phys. Rev. 127 750

    [25]

    Ofelt G S 1962 J. Chem. Phys. 37 511

    [26]

    Ray S, Pramanik P, Singha A, Roy A 2005 J. Appl. Phys. 97 094312

    [27]

    Nishimura G, Kushida T 1988 Phys. Rev. B 37 9075

    [28]

    Reisfeld R, Greenberg E, Brown R N, Drexhage M G, Jφrgensen C K 1983 Chem. Phys. Lett. 95 91

    [29]

    Tian Y, Qi X H, Wu X W, Hua R N, Chen B J 2009 J. Phys. Chem. C 113 10767

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出版历程
  • 收稿日期:  2010-06-16
  • 修回日期:  2010-09-19
  • 刊出日期:  2011-03-15

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