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有序金纳米颗粒阵列的制备及光吸收特性研究

李娆 朱亚彬 狄月 刘冬雪 李冰 钟韦

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有序金纳米颗粒阵列的制备及光吸收特性研究

李娆, 朱亚彬, 狄月, 刘冬雪, 李冰, 钟韦

Fabrication of ordered Au nanoparticles array and its optical absorption properties

Li Rao, Zhu Ya-Bin, Di Yue, Liu Dong-Xue, Li Bing, Zhong Wei
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  • 采用纳米球刻蚀技术中漂移法在玻璃基片上制备较大 面积不同直径的聚苯乙烯小球掩模板, 采用磁控溅射技术在掩模板上沉积不同厚度的金薄膜, 去除聚苯乙烯小球后, 通过扫描电子显微镜观察到周期排列的三角状金纳米颗粒点阵. 通过紫外-可见分光光度计测试所制备样品的光吸收特性, 发现表面等离子体共振峰随粒径增大发生红移, 随金纳米颗粒高度增加发生蓝移. 基于Mie理论, 利用Matlab软件编程对不同粒径的金阵列光吸收特性进行理论模拟, 并与实验结果进行对比.
    Three kinds of polystyrene spheres with different sizes were fabricated on glasses by drifting method of nanosphere lithography. Au thin films with various thicknesses were prepared by magnetron sputtering under controlled deposition time. Triangle-shaped Au nanoparticles array in three different heights after removing the PS template were observed using scanning electron microscopy. The absorption characteristics of all samples were measured by ultraviolet-visible spectrophotometer. Surface plasmon resonance peak was seen to shift to the longer wavelength with increasing diameter of Au nanoparticles. And the surface plasmon resonance peak was shifted to the shorter wavelength with increasing height of Au nanoparticles. Based on Mie theory, we simulated the extinction properties, which vary with the diameter of Au nanoparticles, using Matlab software. The conclusion is in accordance with our experimental results.
    • 基金项目: 中央高校基本科研业务费专项基金(批准号:2009JBM098)和北京市自然科学基金(批准号:2113050)资助的课题.
    • Funds: Project supported by the Fundamental Research Funds for the Central Universities of Ministry of Education of China (Grant No. 2009JBM098), and the Natural Science Foundation of Beijing, China (Grant No. 2113050).
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    Stern E A, Ferrell R A 1960 Phys. Rev. 120 130

    [2]

    Zhang S X, Gao S Y, Yang S X, Zhang H 2008 Chemical Bulletin 8 601 (in Chinese) [张树霞, 高书燕, 杨恕霞, 张洪 2008 化学通报 8 601]

    [3]

    Haynes C L, Van Duyne R P 2001 J. Phys. Chem. B 105 5599

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    Zhong Z Y, Liu S, Zhao W D, Li M J, Zhang H W 2005 J. Funct. Mater. 36 1312 (in Chinese) [钟智勇, 刘爽, 赵文多, 李敏姬, 张怀武 2005 功能材料 36 1312]

    [5]

    Mie G 1908 Ann. Phys. 25 377

    [6]

    Gans R 1915 Physik 47 270

    [7]

    Purcell E M, Pennypacker G R 1973 Astrophys. J 186 705

    [8]

    Novotny L, Pohl D W, Hecht B 1995 Opt. Lett. 20 970

    [9]

    Kottmann J P, Martin O J F, Smith E R 2001 Phys. Rev. B 64 1

    [10]

    Wang K, Yang G, Long H, Li Y H, Dai N L, Lu P X 2008 Acta.P hys. Sin. 57 3862 (in Chinese) [王凯, 杨光, 龙华, 李玉华, 戴能利, 陆培祥 2008 物理学报 57 3862]

    [11]

    Gao T R, Chen Z Y, Peng Y, Li F S 2002 Chin. Phys. 11 1307

    [12]

    Zhao J, Anatoliy, Pinchuk. O 2008 American Chemical Society 41 12

    [13]

    Johnson P B, Christy R W 1972 Phys. Rev. B 12 4370

    [14]

    Galina N, Raman K 2006 Opt. Lett. 14 2118

    [15]

    Christian Mätzler 2002 Ph.D. Dissertation (Bern: University of Bern.)

  • [1]

    Stern E A, Ferrell R A 1960 Phys. Rev. 120 130

    [2]

    Zhang S X, Gao S Y, Yang S X, Zhang H 2008 Chemical Bulletin 8 601 (in Chinese) [张树霞, 高书燕, 杨恕霞, 张洪 2008 化学通报 8 601]

    [3]

    Haynes C L, Van Duyne R P 2001 J. Phys. Chem. B 105 5599

    [4]

    Zhong Z Y, Liu S, Zhao W D, Li M J, Zhang H W 2005 J. Funct. Mater. 36 1312 (in Chinese) [钟智勇, 刘爽, 赵文多, 李敏姬, 张怀武 2005 功能材料 36 1312]

    [5]

    Mie G 1908 Ann. Phys. 25 377

    [6]

    Gans R 1915 Physik 47 270

    [7]

    Purcell E M, Pennypacker G R 1973 Astrophys. J 186 705

    [8]

    Novotny L, Pohl D W, Hecht B 1995 Opt. Lett. 20 970

    [9]

    Kottmann J P, Martin O J F, Smith E R 2001 Phys. Rev. B 64 1

    [10]

    Wang K, Yang G, Long H, Li Y H, Dai N L, Lu P X 2008 Acta.P hys. Sin. 57 3862 (in Chinese) [王凯, 杨光, 龙华, 李玉华, 戴能利, 陆培祥 2008 物理学报 57 3862]

    [11]

    Gao T R, Chen Z Y, Peng Y, Li F S 2002 Chin. Phys. 11 1307

    [12]

    Zhao J, Anatoliy, Pinchuk. O 2008 American Chemical Society 41 12

    [13]

    Johnson P B, Christy R W 1972 Phys. Rev. B 12 4370

    [14]

    Galina N, Raman K 2006 Opt. Lett. 14 2118

    [15]

    Christian Mätzler 2002 Ph.D. Dissertation (Bern: University of Bern.)

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出版历程
  • 收稿日期:  2013-04-19
  • 修回日期:  2013-06-29
  • 刊出日期:  2013-10-05

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