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It has been shown that the paramagnetic ions doped in KMgF3 are in axial symme-try environment. In the present work, that the shift of the nearest neighbour F- ions of the K+ vacancy, 3.76°and -0.64°deviating from the c3 axis respectively, are predic-ted by analysing the anisotropic g factors and the zero-field splitting of EPR.
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