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Emission spectra of OH radical (A2Σ+→X2Πr) and its application on high temperature gas

Yang Qian-Suo Jiang Zong-Lin Peng Zhi-Min Ding Yan-Jun

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Emission spectra of OH radical (A2Σ+→X2Πr) and its application on high temperature gas

Yang Qian-Suo, Jiang Zong-Lin, Peng Zhi-Min, Ding Yan-Jun
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  • Based on the inherent molecular structure characteristics of the OH radicals, the energy level distribution, the transition frequency and Einstein spontaneous emission transition probability are systematically analyzed and numerically studied. Meanwhile, combined with the spectra experiments, the natural broadening, collision broadening, Doppler broadening and instrumental broadening effects on spectral line shape are analyzed. The dependence of the spectral profile on the rotational temperature, the vibrational temperature, and the spectral function are numerically explored in certain ranges. The corresponding numerical results are also discussed for the emission spectra thermometry, which provides a theoretical basis for the emission thermometry. In experimental, the emission spectra of OH (A2Σ+→X2Πr) system of the hydrogen flames are recorded by the optical multi-channel analyzer and studied. By the fitting of the experimental spectra to the numerically calculated spectra, the corresponding rotational and vibrational temperatures of the hydrogen flames are determined, respectively.
    [1]

    Levin D A 1999 AIAA paper 3567 1

    [2]

    Anokhin E M, Ivanova T Y, Koudriavtsev N N, Starikovskii A Y 2007 AIAA paper 814 1

    [3]

    Hyun S Y, Chul P, Chang K S 2008 AIAA paper 1276 1

    [4]

    Sharma S P, Gillespie W 1991 J. Thermophys Heat Transfer 5 257

    [5]

    Djameel R, Michel D, Raymond B 1999 J. Thermophys Heat Transfer 13 219

    [6]

    Jeong E, Jeung I S, Byrne S O, Houwing A F 2008 J. Propul Power 24 1258

    [7]

    Griffiths A D, Houwing A F P 2005 Appl. Opt. 44 6653

    [8]

    Liu D B, Yang D, Jiang R G, Li Y, Wang J D 2002 Spectrosc Spect Anal. 23 670 (in Chinese) [刘大斌、 杨 栋、 蒋荣光、 李 燕、 王俊德 2002 光谱学与光谱分析 23 670]

    [9]

    Dong L F, Ran J X, Yin Z Q, Mao Z G 2002 Spectrosc Spect Anal. 25 1184 (in Chinese) [董丽芳、 冉俊霞、 尹增谦、 毛志国 2005 光谱学与光谱分析 25 1184]

    [10]

    Laux C O, Kruger C H, Zare R N 2003 Plasma Sources Sci. T. 12 125

    [11]

    Laux C O, Gessman R J, Kruger C H, Roux F, Michaud F, Davis S P 2001 J. Quant Spectrosc RA 68 473

    [12]

    Chun F S, Tracy M, Fang Y Y 2003 AIAA paper 3750 1

    [13]

    James S, Serguei Z U. S. Patent 6914246b2

    [14]

    Chul P 1985 NASA TM 86707

    [15]

    Laux C O 1993 Ph. D. Thesis (US: Stanford University)

    [16]

    Fujita K, Takashi A B E 1997 The Institute of Space and Astronautical Science Report 669 1

    [17]

    Liu L Y, Zhang J L, Ma T C, Deng X L 2002 Spectrosc Spect Anal. 22 1013 (in Chinese) [刘莉莹、 张家良、 马腾才、 邓新 绿 2002 光谱学与光谱分析 22 1013] [18] Zhang J L 2002 Ph. D. Thesis (Dalian: Dalian University of Technology) (in Chinese) [张家良 2002 博士学位论文(大连理工大学)]

    [18]

    Tu X, Lu S Y, Yan J H, Ma Z Y, Pan X C, Cen K F 2002 Spectrosc Spect Anal. 22 1013 (in Chinese) [屠 昕、 陆胜勇、 严建华、 马增益、 潘新潮、 岑可法 2006 光谱学与光谱分析 26 1785]

    [19]

    Tu X 2007 Ph. D. Thesis (Hangzhou: ZheJiang University) (in Chinese) [屠 昕 2007 博士学位论文(浙江大学)]

    [20]

    Dong L F, Li Y H, Chen W J, Li X C 2007 Spectrosc Spect Anal. 27 2406 (in Chinese) [董丽芳、 李永辉、 陈文军、 李雪 辰 2007 光谱学与光谱分析 27 2406] [22] Jorge L, David R C 1996 SRI Report No. MP 96-001

    [21]

    Jorge L, David R C 1998 J. Chem. Phys. 109 439

    [22]

    Kristen L S, Jorge L, Jay B. J, David R C 1997 J. Chem. Phys. 106 6262

    [23]

    Charles D I 2000 J. Phys. D: Appl. Phys. 33 1697

    [24]

    Dieke G H, Crosswhite H M 1962, J. Quant Spectrosc RA 2 97

    [25]

    Lawrence S B, Yu H C, James A G, Broadfoot A L, Rainer A D, Edmond M 2004 AIAA paper 1257 1

    [26]

    Hinkley R K, Hall J A, Walker T E H, Richards W G 1972 J. Phys. B: Atom. Molec. Phys. 5 204

    [27]

    David G D, Michael F A 1982 The Astrophysical Journal 258 864

    [28]

    Bennett R F M 1970 Mon. Not. R. astr. Soc. 47 35

    [29]

    Peng Z M 2010 Ph. D. Thesis (Beijing: Institute of Mechanics, Chinese Academy of Sciences) (in Chinese) [彭志敏 2010 博士学位论文(中国科学院力学研究所)]

  • [1]

    Levin D A 1999 AIAA paper 3567 1

    [2]

    Anokhin E M, Ivanova T Y, Koudriavtsev N N, Starikovskii A Y 2007 AIAA paper 814 1

    [3]

    Hyun S Y, Chul P, Chang K S 2008 AIAA paper 1276 1

    [4]

    Sharma S P, Gillespie W 1991 J. Thermophys Heat Transfer 5 257

    [5]

    Djameel R, Michel D, Raymond B 1999 J. Thermophys Heat Transfer 13 219

    [6]

    Jeong E, Jeung I S, Byrne S O, Houwing A F 2008 J. Propul Power 24 1258

    [7]

    Griffiths A D, Houwing A F P 2005 Appl. Opt. 44 6653

    [8]

    Liu D B, Yang D, Jiang R G, Li Y, Wang J D 2002 Spectrosc Spect Anal. 23 670 (in Chinese) [刘大斌、 杨 栋、 蒋荣光、 李 燕、 王俊德 2002 光谱学与光谱分析 23 670]

    [9]

    Dong L F, Ran J X, Yin Z Q, Mao Z G 2002 Spectrosc Spect Anal. 25 1184 (in Chinese) [董丽芳、 冉俊霞、 尹增谦、 毛志国 2005 光谱学与光谱分析 25 1184]

    [10]

    Laux C O, Kruger C H, Zare R N 2003 Plasma Sources Sci. T. 12 125

    [11]

    Laux C O, Gessman R J, Kruger C H, Roux F, Michaud F, Davis S P 2001 J. Quant Spectrosc RA 68 473

    [12]

    Chun F S, Tracy M, Fang Y Y 2003 AIAA paper 3750 1

    [13]

    James S, Serguei Z U. S. Patent 6914246b2

    [14]

    Chul P 1985 NASA TM 86707

    [15]

    Laux C O 1993 Ph. D. Thesis (US: Stanford University)

    [16]

    Fujita K, Takashi A B E 1997 The Institute of Space and Astronautical Science Report 669 1

    [17]

    Liu L Y, Zhang J L, Ma T C, Deng X L 2002 Spectrosc Spect Anal. 22 1013 (in Chinese) [刘莉莹、 张家良、 马腾才、 邓新 绿 2002 光谱学与光谱分析 22 1013] [18] Zhang J L 2002 Ph. D. Thesis (Dalian: Dalian University of Technology) (in Chinese) [张家良 2002 博士学位论文(大连理工大学)]

    [18]

    Tu X, Lu S Y, Yan J H, Ma Z Y, Pan X C, Cen K F 2002 Spectrosc Spect Anal. 22 1013 (in Chinese) [屠 昕、 陆胜勇、 严建华、 马增益、 潘新潮、 岑可法 2006 光谱学与光谱分析 26 1785]

    [19]

    Tu X 2007 Ph. D. Thesis (Hangzhou: ZheJiang University) (in Chinese) [屠 昕 2007 博士学位论文(浙江大学)]

    [20]

    Dong L F, Li Y H, Chen W J, Li X C 2007 Spectrosc Spect Anal. 27 2406 (in Chinese) [董丽芳、 李永辉、 陈文军、 李雪 辰 2007 光谱学与光谱分析 27 2406] [22] Jorge L, David R C 1996 SRI Report No. MP 96-001

    [21]

    Jorge L, David R C 1998 J. Chem. Phys. 109 439

    [22]

    Kristen L S, Jorge L, Jay B. J, David R C 1997 J. Chem. Phys. 106 6262

    [23]

    Charles D I 2000 J. Phys. D: Appl. Phys. 33 1697

    [24]

    Dieke G H, Crosswhite H M 1962, J. Quant Spectrosc RA 2 97

    [25]

    Lawrence S B, Yu H C, James A G, Broadfoot A L, Rainer A D, Edmond M 2004 AIAA paper 1257 1

    [26]

    Hinkley R K, Hall J A, Walker T E H, Richards W G 1972 J. Phys. B: Atom. Molec. Phys. 5 204

    [27]

    David G D, Michael F A 1982 The Astrophysical Journal 258 864

    [28]

    Bennett R F M 1970 Mon. Not. R. astr. Soc. 47 35

    [29]

    Peng Z M 2010 Ph. D. Thesis (Beijing: Institute of Mechanics, Chinese Academy of Sciences) (in Chinese) [彭志敏 2010 博士学位论文(中国科学院力学研究所)]

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Publishing process
  • Received Date:  19 June 2010
  • Accepted Date:  29 July 2010
  • Published Online:  15 May 2011

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