Search

Article

x

留言板

尊敬的读者、作者、审稿人, 关于本刊的投稿、审稿、编辑和出版的任何问题, 您可以本页添加留言。我们将尽快给您答复。谢谢您的支持!

姓名
邮箱
手机号码
标题
留言内容
验证码

Properties of luminescence and scintillation of Eu-doped high gadolinium glass

Tang Chun-Mei Shen Ying-Long Sheng Qiu-Chun Liu Shuang Li Wen-Tao Wang Long-Fei Chen Dan-Ping

Citation:

Properties of luminescence and scintillation of Eu-doped high gadolinium glass

Tang Chun-Mei, Shen Ying-Long, Sheng Qiu-Chun, Liu Shuang, Li Wen-Tao, Wang Long-Fei, Chen Dan-Ping
PDF
Get Citation

(PLEASE TRANSLATE TO ENGLISH

BY GOOGLE TRANSLATE IF NEEDED.)

  • Eu (1 wt%) doped 15SiO2-25B2O3-30Al2O3-30Gd2O3 oxide glasses are prepared by high-temperature melt-quenching method in air and reduced atmosphere, respectively. The properties of scintillation and photoluminescence of the two samples are compared. When the samples fabricated in reduced atmosphere are excited by the X-ray and 395 nm violet light, a 450–550 nm blue-green light beam from Eu2+ and a 615 nm red light beam from Eu3+ are obtained. The intensity ratios between Eu3+ and Eu2+ are obviously different under different excitation sources. The intensity ratio under the excitation of the 395 nm violet light is 0.02 while it increases to 1.37 under the X-ray excitation. By analyzing the phonon sideband spectra of the samples, it is found that the Eu3+ ions around the former of Si are completely reduced into Eu2+ ions, while only part of Eu3+ ions around the former of B and Al are reduced into Eu2+ ions. Further investigation about the scintillation mechanism indicates that the sensitization of Gd and the energy transfer of Eu2+→Eu3+ near the formers of B and Al increase the scintillation performances of Eu3+ ions in the reduced glass samples.
    • Funds: Project supported by the National Natural Science Foundation of China (Grant No. 51272262).
    [1]

    Chen G R, Baccaro S, Du Y J 2000 Bull. Chin. Ceramic Soc. 5 48 (in Chinese) [陈国荣, Baccaro S, 杜永娟 2000 硅酸盐通报 5 48]

    [2]

    Fu J, Parker J M, Brown R M, Flower P S 2003 J. Non-cryst. Solids 326–327 335

    [3]

    Chewpraditkul W, He X, Chen D, Shen Y, Sheng Q, Yu B, Nikl M, Kucerkova R, Beilerova A, Wanarak C, Phunpueok A 2011 Phys. Status Solidi A 208 2830

    [4]

    Chen D P, Miyoshi M, Akai T, Tetsuo Y 2005 Appl. Phys. Lett. 86 231908

    [5]

    Liu Z J, Yang L Y, Dai N L, Li J Y 2010 Acta Phys. Sin. 60 047806 (in Chinese) [刘自军, 杨旅云, 戴能利, 李进延 2010 物理学报 60 047806]

    [6]

    Wang S X, Zhang Y P, Xu B, Xia H P 2012 Opt. Tech. 38 64 (in Chinese) [王实现, 张约品, 徐波, 夏海平 2012 光学技术 38 64]

    [7]

    Fu J, Kobayashi M, Sugimoto S, Parker J M 2008 Mater. Res. Bull. 43 1502

    [8]

    Chewpraditkul W, Chen D P, Yu B, Zhang Q, Shen Y, Nikl M, Kucerkova R, Beitlerova A, Wanarak C, Phunpueok A 2011 Phys. Status Solidi R 5 40

    [9]

    Tanabe S, Todoroki S, Hirao K, Saoga N 1990 J. Non-cryst. Solids 122 59

    [10]

    Li H, Peng Z G, Qi J 2010 J. Wuhan Univ. Technol. 32 36 (in Chinese) [李宏, 彭志钢, 戚杰 2010 武汉理工大学学报 32 36]

    [11]

    Kishimoto Y, Zhang X T, Hayakawa T, Nogami M 2009 J. Lumin. 129 1055

    [12]

    Liu Z J, Chen Q Q, Dai N L, Yu Y, Yang L Y, Li J Y 2012 J. Non-cryst. Solids 358 3289

    [13]

    Shen Y L, Tang C M, Sheng Q C, Liu S, Li W T, Wang L F, Chen D P 2013 Acta Phys. Sin. 62 117803 (in Chinese) [沈应龙, 唐春梅, 盛秋春, 刘双, 李文涛, 王龙 飞, 陈丹平 2013 物理学报 62 117803]

    [14]

    Shen Y L, Zhang Q, Cheng J M, Sheng Q C, Liu S, Li W T, Chewpraditkuld W, Chen D P 2013 Mater. Lett. 97 151

    [15]

    Arunkumar S, Marimuthu K 2013 J. Lumin. 139 6

    [16]

    Masayuki N, Tsukasa Y, Yoshihiro A 1998 J. Lumin. 78 63

    [17]

    Sun J Y, Du H Y, Hu W X 2003 Solid Luminescent Materials (Beijing: Chemical Industry Press) p472 (in Chinese) [孙家跃, 杜海燕, 胡文祥 2003 固体发光材料 (北京: 化学工业出版社)第472页]

    [18]

    Cheng J J, Zhang G L, Bi C H 1979 J. Chin. Ceramic Soc. 7 244 (in Chinese) [程继健, 张关林, 毕昌华 1979 硅酸盐学报 7 244]

    [19]

    Sun T, Xiao H N, Guo W M, Hong X C 2010 Ceram. Int. 36 821

    [20]

    Zeng H D, Yang Y F, Lin Z Y, Liang X L, Yuan S L, Chen G R, Sun L Y 2011 J. Non-cryst. Solids 357 2328

    [21]

    Chen D, Miyoshi H, Akai T, Yazawa T 2006 Waste Manage. 26 1017

    [22]

    Shen Y L 2013 Ph. D. Dissertation (Shanghai: Shanghai Institute of Optics and Fine Mechanics Chinese Academy of Science) (in Chinese) [沈应龙 2013 博士学位论文(上海: 中国科学院上海光学精密机械研究所)]

  • [1]

    Chen G R, Baccaro S, Du Y J 2000 Bull. Chin. Ceramic Soc. 5 48 (in Chinese) [陈国荣, Baccaro S, 杜永娟 2000 硅酸盐通报 5 48]

    [2]

    Fu J, Parker J M, Brown R M, Flower P S 2003 J. Non-cryst. Solids 326–327 335

    [3]

    Chewpraditkul W, He X, Chen D, Shen Y, Sheng Q, Yu B, Nikl M, Kucerkova R, Beilerova A, Wanarak C, Phunpueok A 2011 Phys. Status Solidi A 208 2830

    [4]

    Chen D P, Miyoshi M, Akai T, Tetsuo Y 2005 Appl. Phys. Lett. 86 231908

    [5]

    Liu Z J, Yang L Y, Dai N L, Li J Y 2010 Acta Phys. Sin. 60 047806 (in Chinese) [刘自军, 杨旅云, 戴能利, 李进延 2010 物理学报 60 047806]

    [6]

    Wang S X, Zhang Y P, Xu B, Xia H P 2012 Opt. Tech. 38 64 (in Chinese) [王实现, 张约品, 徐波, 夏海平 2012 光学技术 38 64]

    [7]

    Fu J, Kobayashi M, Sugimoto S, Parker J M 2008 Mater. Res. Bull. 43 1502

    [8]

    Chewpraditkul W, Chen D P, Yu B, Zhang Q, Shen Y, Nikl M, Kucerkova R, Beitlerova A, Wanarak C, Phunpueok A 2011 Phys. Status Solidi R 5 40

    [9]

    Tanabe S, Todoroki S, Hirao K, Saoga N 1990 J. Non-cryst. Solids 122 59

    [10]

    Li H, Peng Z G, Qi J 2010 J. Wuhan Univ. Technol. 32 36 (in Chinese) [李宏, 彭志钢, 戚杰 2010 武汉理工大学学报 32 36]

    [11]

    Kishimoto Y, Zhang X T, Hayakawa T, Nogami M 2009 J. Lumin. 129 1055

    [12]

    Liu Z J, Chen Q Q, Dai N L, Yu Y, Yang L Y, Li J Y 2012 J. Non-cryst. Solids 358 3289

    [13]

    Shen Y L, Tang C M, Sheng Q C, Liu S, Li W T, Wang L F, Chen D P 2013 Acta Phys. Sin. 62 117803 (in Chinese) [沈应龙, 唐春梅, 盛秋春, 刘双, 李文涛, 王龙 飞, 陈丹平 2013 物理学报 62 117803]

    [14]

    Shen Y L, Zhang Q, Cheng J M, Sheng Q C, Liu S, Li W T, Chewpraditkuld W, Chen D P 2013 Mater. Lett. 97 151

    [15]

    Arunkumar S, Marimuthu K 2013 J. Lumin. 139 6

    [16]

    Masayuki N, Tsukasa Y, Yoshihiro A 1998 J. Lumin. 78 63

    [17]

    Sun J Y, Du H Y, Hu W X 2003 Solid Luminescent Materials (Beijing: Chemical Industry Press) p472 (in Chinese) [孙家跃, 杜海燕, 胡文祥 2003 固体发光材料 (北京: 化学工业出版社)第472页]

    [18]

    Cheng J J, Zhang G L, Bi C H 1979 J. Chin. Ceramic Soc. 7 244 (in Chinese) [程继健, 张关林, 毕昌华 1979 硅酸盐学报 7 244]

    [19]

    Sun T, Xiao H N, Guo W M, Hong X C 2010 Ceram. Int. 36 821

    [20]

    Zeng H D, Yang Y F, Lin Z Y, Liang X L, Yuan S L, Chen G R, Sun L Y 2011 J. Non-cryst. Solids 357 2328

    [21]

    Chen D, Miyoshi H, Akai T, Yazawa T 2006 Waste Manage. 26 1017

    [22]

    Shen Y L 2013 Ph. D. Dissertation (Shanghai: Shanghai Institute of Optics and Fine Mechanics Chinese Academy of Science) (in Chinese) [沈应龙 2013 博士学位论文(上海: 中国科学院上海光学精密机械研究所)]

  • [1] Liu Wen-Quan, Chao Ke-Fu, Wu Wen-Jie, Bao Fu-Quan, Zhou Bing-Qing. CaAlSiN3:Eu2+ red phosphors synthesized by atmospheric nitrogen and their luminescence properties. Acta Physica Sinica, 2016, 65(20): 207801. doi: 10.7498/aps.65.207801
    [2] Cheng Shuai, Xu Xu-Hui, Wang Peng-Jiu, Qiu Jian-Bei. Long persistent and photo-stimulated luminescence properties of β-Sr2SiO4:Eu2+, La3+ phosphors. Acta Physica Sinica, 2015, 64(1): 017802. doi: 10.7498/aps.64.017802
    [3] Liu Li-Wan, Zhou Qin-Ling, Shao Chong-Yun, Zhang Yu, Hu Li-Li, Yang Qiu-Hong, Chen Dan-Ping. Scintillation properties of Ce3+ doped SiO2-Al2O3-Gd2O3 glass. Acta Physica Sinica, 2015, 64(16): 167802. doi: 10.7498/aps.64.167802
    [4] Zhou Ren-Di, Huang Xue-Fei, Qi Zhi-Jian, Huang Wei-Gang. Preparation and luminescent properties of Ca2Si(O4-xNx):Eu2+ green-emitting phosphors. Acta Physica Sinica, 2014, 63(19): 197801. doi: 10.7498/aps.63.197801
    [5] Wang Zhi-Jun, Liu Hai-Yan, Yang Yong, Jiang Hai-Feng, Duan Ping-Guang, Li Pan-Lai, Yang Zhi-Ping, Guo Qing-Lin. Synthesization and luminescent properties of blue emitting phosphor Ba2Ca(PO4)2:Eu2+. Acta Physica Sinica, 2014, 63(7): 077802. doi: 10.7498/aps.63.077802
    [6] Liu Dan, Liang Pei, Wang Le, Xu Guo-Tang, Liu Yang, Li Xiao-Yan, Dong Qian-Min, Huang Jie. Low-temperature combustion synthesis and luminescent properties of SrMgAl10O17:Eu2+, Er3+ high brightness blue phosphors. Acta Physica Sinica, 2013, 62(19): 197802. doi: 10.7498/aps.62.197802
    [7] Gong Yu, Chen Bai-Hua, Xiong Liang-Ping, Gu Mei, Xiong Jie, Gao Xiao-Ling, Luo Yang-Ming, Hu Sheng, Wang Yu-Hua. Effect of oxygen vacancies on the fluorescence and phosphorescence properties of Ca5MgSi3O12:Eu2+, Dy3+. Acta Physica Sinica, 2013, 62(15): 153201. doi: 10.7498/aps.62.153201
    [8] Luo Lin-Ling, Tang Ke, Zhu Da-Chuan, Han Tao, Zhao Cong. Effect of Li+ and Er3+ co-doping on the luminescence properties of Ba2SiO4:Eu. Acta Physica Sinica, 2013, 62(15): 157802. doi: 10.7498/aps.62.157802
    [9] Zhong Rui-Xia, Zhang Jia-Hua, Li Ming-Ya, Wang Xiao-Qiang. Luminescent properties and energy transfer in MAl12O19: Eu2+, Cr3+ (M = Ca, Sr, Ba). Acta Physica Sinica, 2012, 61(11): 117801. doi: 10.7498/aps.61.117801
    [10] Cao Shi-Xiu, Han Tao, Tu Ming-Jing. The effect of Eu2+ doping concentration on luminescence properties of Ca2-xMgSi2O7∶x Eu2+ green phosphor. Acta Physica Sinica, 2011, 60(12): 127802. doi: 10.7498/aps.60.127802
    [11] Xie Wei, Wang Yin-Hai, Hu Yi-Hua, Wu Hao-Yi, Deng Liu-Yong, Liao Feng. Structure and luminescence properties of Sr4Al14O25:Eu2+, Dy3+ by Ca2+ doping. Acta Physica Sinica, 2010, 59(2): 1148-1154. doi: 10.7498/aps.59.1148
    [12] Ding Xu, Xu Yan, Guo Chong-Feng. Luminescence characteristics of Sr2B5O9Cl: Eu2+ phosphors for white LED. Acta Physica Sinica, 2010, 59(9): 6632-6636. doi: 10.7498/aps.59.6632
    [13] Cui Cai-E, Wang Sen, Huang Ping. Effect of Dy on properties of red long-afterglow phosphor Sr3Al2O6:Eu2+,Dy3+. Acta Physica Sinica, 2009, 58(5): 3565-3571. doi: 10.7498/aps.58.3565
    [14] Ma Ming-Xing, Zhu Da-Chuan, Tu Ming-Jing. Effect of H3BO3 on composition and luminescence properties of BaAl2Si2O8:Eu2+ blue phosphor. Acta Physica Sinica, 2009, 58(9): 6512-6517. doi: 10.7498/aps.58.6512
    [15] Wang Zhi-Jun, Li Pan-Lai, Wang Ying, Yang Zhi-Ping, Guo Qing-Lin. Luminescence characteristics of LiBaBO3:Eu2+ phosphor for white LED. Acta Physica Sinica, 2009, 58(2): 1257-1260. doi: 10.7498/aps.58.1257
    [16] Ma Ming-Xing, Zhu Da-Chuan, Tu Ming-Jing. The effect of Eu2+ doping concentration on luminescence properties of BaAl2Si2O8:Eu2+ blue phosphor. Acta Physica Sinica, 2009, 58(8): 5826-5830. doi: 10.7498/aps.58.5826
    [17] Yang Zhi-Ping, Yang Guang-Wei, Wang Shao-Li, Tian Jing, Li Pan-Lai, Li Xu. Luminescence and energy transfer of Eu2+, Mn2+ in BaZnP2O7. Acta Physica Sinica, 2008, 57(1): 581-585. doi: 10.7498/aps.57.581
    [18] Peng Zhi-Wei, Wang Ling-Ling, Liu Huang-Qing, Huang Wei-Qing, Zou Bing-Suo. Combustion synthesis and photoluminescence of nanocrystalline Gd2O3:Eu3+. Acta Physica Sinica, 2007, 56(2): 1162-1166. doi: 10.7498/aps.56.1162
    [19] Yang Zhi-Ping, Liu Yu-Feng, Wang Li-Wei, Yu Quan-Mao, Xiong Zhi-Jun, Xu Xiao-Ling. Luminesce properties of the single white emitting phosphor Eu2+, Mn2+ co-doped Ca2SiO3Cl2. Acta Physica Sinica, 2007, 56(1): 546-550. doi: 10.7498/aps.56.546
    [20] Yang Zhi-Ping, Liu Yu-Feng. Preparation and luminescence characteristics of Eu2+ activated Ca3SiO5 green-emitting phosphor. Acta Physica Sinica, 2006, 55(9): 4946-4950. doi: 10.7498/aps.55.4946
Metrics
  • Abstract views:  4842
  • PDF Downloads:  655
  • Cited By: 0
Publishing process
  • Received Date:  16 August 2013
  • Accepted Date:  29 September 2013
  • Published Online:  05 December 2013

/

返回文章
返回