Photocatalytic application of Z-type system

Li Ping; Li Hai-Jin; Tu Wen-Guang; Zhou Yong; Zou Zhi-Gang

doi:10.7498/aps.64.094209

Abstract

Z-type photocatlytic system, reflembling natural photosynthesis, consists of two different photocatalysts and a shuttle redox mediator, involving two-photon excitation process for photocatlysis. One photocatalyst as a photoreduction system offers the reduction sites by conduction band (CB) electrons, and the other photocatalyst as a photooxidation system provides the oxidation sites by valence band (VB) holes. A shuttle redox mediator as an electron conductor transfers the electrons from the CB of the photooxidation system to the VB of the photoreduction system. On the one hand, the separation of photocatalytic reactive sites is advantageous for spatial separation of the electrons and holes, which is beneficial for enhancing the photocatlytic activities. On the other hand, photoreduction system and photooxidation system of different materials effectively inhibit the reflerse reaction involvement of photoreductive and photooxidative products. The Z-type photocatlytic system simultaneously possesses a wide light absorption range and strong redox ability.

Keywords:

Authors and contacts

1.
National Laboratory of Solid State Microstructures, Nanjing University, Nanjing 210093, China;
2.
Department of Physics, Nanjing University, Nanjing 210093, China;
3.
Eco-materials and Renewable Energy Research Center (ERERC), Nanjing University, Nanjing 210093, China;
4.
School of Mathematics and Physics, Anhui University of Technology, Ma’anshan 243002, China
Funds: Project supported by the National Basic Research Program of China (Grant Nos. 2014CB239302, 2011CB933303, 2013CB632404), the National Natural Science Foundation of China (Grant Nos. 21473091, 51272101, 51202005), the National Science Foundation of Jiangsu Province (Grant Nos. BK2012015, BK20130053), the College Postgraduate Research and Innovation Project of Jiangsu Province (Grant Nos. KYLX_0025) and the Provincial Science Key Foundation of Higher Education Institutions of Anhui (Grant Nos. KJ2011A053).

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[52]	Tu W, Zhou Y, Liu Q, Yan S, Bao S, Wang X, Xiao M, Zou Z 2013 Adv. Funct. Mater. 23 1743
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[54]	Arai T, Sato S, Kajino T, Morikawa T 2013 Energy Environ. Sci. 6 1274
[55]	Qin S, Xin F, Liu Y, Yin X, Ma W 2011 Journal of colloid and interface science 356 257
[56]	Li P, Zhou Y, Li H, Xu Q, Meng X, Wang X, Xiao M, Zou Z 2009 Energy Environ. Sci 2 745
[57]	Sekizawa K, Maeda K, Domen K, Koike K, Ishitani O 2013 J. Am. Chem. Soc. 135 4596
[58]	Song G, Xin F, Chen J, Yin X 2014 Applied Catalysis A: General 473 90
[59]	Liu Y, Ji G, Dastageer M A, Zhu L, Wang J, Zhang B, Changa X, Gondal M A 2014 RSC Adv. 4 56961
[60]	Carey J H, Lawrence J, Tosine H M 1976 Bulletin of Environmental Contamination Toxlcology 16 697
[61]	Fujihira M, Satoh Y, Osa T 1981 Nature 293 206
[62]	Liu Z, Zhao Z G, Miyauchi M 2009 J. Phys. Chem. C 113 17132
[63]	Wang X, Li S, Ma Y, Yu H, Yu J 2011 J. Phys. Chem. C 115 14648
[64]	Ye L, Liu J, Gong C, Tian L, Peng T, Zan L 2012 ACS Catal. 2 1677
[65]	Lin H, Cao J, Luo B, Xu B, Chen S 2012 Catalysis Communications 21 91
[66]	Hou J, Yang C, Wang Z, Ji Q, Li Y, Huang G, Jiao S, Zhu H 2013 Applied Catalysis B: Environmental 142-143 579
[67]	Miyauchi M, Nukui Y, Atarashi D, Sakai E 2013 ACS Appl. Mater. Interfaces 5 9770
[68]	Chen Z, Wang W, Zhang Z, Fang X 2013 J. Phys. Chem. C 117 19346
[69]	Katsumata H, Sakai T, Suzuki T M, Kaneco S 2014 Ind. Eng. Chem. Res. 53 8018
[70]	Min Y, He G, Xu Q, Chen Y 2014 J. Mater. Chem. A. 2 1294
[71]	Cheng H, Hou J, Zhu H, Guo X M 2014 RSC Adv. 4 41622
[72]	Pu Y C, Lin W H, Hsu Y J 2015 Applied Catalysis B: Environmental 163 343

Cited By

[1]	Chen X, Shen S, Guo L, Mao S 2010 Chem. Rev. 110 6503
[2]	Fujishima A, Honda K 1972 Nature 238 37
[3]	Maeda K, Domen K 2007 J. Phys. Chem. C 111 7851
[4]	Zhang Z, Zhang L, Hedhili M N, Zhang H, Wang P 2013 Nano Lett. 13 14
[5]	Wang Z, Huang B, Dai Y, Liu Y, Zhang X, Qin X, Wang J, Zheng Z, Cheng H 2012 CrystEngComm 14 1687
[6]	Zhou P, Yu J, Jaroniec M 2014 Adv. Mater. 26 4920
[7]	Sun W T, Yu Y, Pan H Y, Gao X F, Chen Q, Peng L M 2008 J. Am. Chem. Soc. 130 1124
[8]	Cheng H, Huang B, Dai Y, Qin X, Zhang X 2010 Langmuir : the ACS journal of surfaces and colloids 26 6618
[9]	Su J, Zou X X, Li G D, Wei X, Yan C, Wang Y N, Zhao J, Zhou L J, Chen J S 2011 J. Phys. Chem. C 115 8064
[10]	Hou Y, Wen Z, Cui S, Guo X, Chen J 2013 Adv. Mater. 25 6291
[11]	Zhong M, Ma Y, Oleynikov P, Domen K, Delaunay J J 2014 Energy Environ. Sci. 7 1693
[12]	Tachibana Y, Vayssieres L, Durrant J R 2012 Nat. Photonics 6 511
[13]	Li H, Zhou Y, Tu W, Ye Y, Zou Z 2014 Adv. Funct. Mater. DOI: 10.1002adfm.201401636
[14]	Sayama K, Yoshida R, Kusama H, Okabe K, Abe Y, Arakawa H 1997 Chem Phys Lett 277 387
[15]	Miseki Y, Fujiyoshi S, Gunji T, Sayama K 2013 Catal. Sci. Technol. 3 1750
[16]	Zhu H, Yang B, Xu J, Fu Z, Wen M, Guo T, Fu S, Zuo J, Zhang S 2009 Applied Catalysis B: Environmental 90 463
[17]	Fujihara K, Ohno T, Matsumura M 1998 J. Chem. Soc. Faraday Trans. 94 3705
[18]	Kato H, Hori M, Konta R, Shimodaira Y, Kudo A 2004 Chemistry Letters 33 1348
[19]	Abe R, Sayama K, Sugihara H 2005 J. Phys. Chem. B 109 16052
[20]	Tada H, Mitsui T, Kiyonaga T, Akita T, Tanaka K 2006 Nat Mater. 5 782
[21]	Liu C, Tang J, Chen H M, Liu B, Yang P 2013 Nano Lett. 13 2989
[22]	Kudo A, Miseki Y 2009 Chem. Soc. Rev. 38 253
[23]	Sasaki Y, Nemoto H, Saito K, Kudo A 2009 J. Phys. Chem. C 113 17536
[24]	Kato H, Sasaki Y, Shirakura N, Kudo A 2013 J. Mater. Chem. A 1 12327
[25]	Zhang L, Wong K H, Chen Z, Yu J C, Zhao J, Hu C, Chan C Y, Wong P K 2009 Applied Catalysis A: General 363 221
[26]	Iwase A, Ng Y H, Ishiguro Y, Kudo A, Amal R 2011 J. Am. Chem. Soc. 133 11054
[27]	Wang X, Liu G, Wang L, Chen Z, Lu G Q, Cheng H 2012 Adv. Energy Mater. 2 42
[28]	Sayama K, Mukasa K, Abe R, Abe Y, Arakawa H 2001 Chem. Commu. 2416
[29]	Abe R, Sayama K, Domen K, Arakawa H 2001 Chemical Physics Letters 344 339
[30]	Abe R, Takata T, Sugihara H, Domen K 2005 Chem. Commun. 3829
[31]	Kim H G, Jeong E D, Borse P H, Jeon S, Yong K, Lee J S, Li W, Oh S H 2006 Appl. Phys. Lett. 89 064103
[32]	Sayama K, Abe R, Arakawa H, Sugihara H 2006 Catalysis Communications 7 96
[33]	Maeda K, Terashima H, Kase K, Higashi M, Tabata M, Domen K 2008 Bull. Chem. Soc. Jpn 81 927
[34]	Higashi M, Abe R, Teramura K, Takata T, Ohtani B, Domen K 2008 Chemical Physics Letters 452 120
[35]	Sasaki Y, Iwase A, Kato H, Kudo A 2008 Journal of Catalysis 259 133
[36]	Abe R, Shinmei K, Hara K, Ohtani B 2009 Chem. Commun. 3577
[37]	Maeda K, Higashi M, Lu D, Abe R, Domen K 2010 J. Am. Chem. Soc. 132 5858
[38]	Tabata M, Maeda K, Higashi M, Lu D, Takata T, Abe R, Domen K 2010 Langmuir : the ACS journal of surfaces and colloids 26 9161
[39]	Yun H J, Lee H, Kim N D, Lee D M, Yu S, Yi J 2011 ACS Nano 5 4084
[40]	Maeda K, Abe R, Domen K 2011 J. Phys. Chem. C 115 3057
[41]	Hara S, Yoshimizu M, Tanigawa S, Ni L, Ohtani B, Irie H 2012 J. Phys. Chem. C 116 17458
[42]	Ma S S, Maeda K, Hisatomi T, Tabata M, Kudo A, Domen K 2013 Chem. Eur. J. 19 7480
[43]	Sasaki Y, Kato H, Kudo A 2013 J. Am. Chem. Soc. 135 5441
[44]	Ding L, Zhou H, Lou S, Ding J, Zhang D, Zhu H, Fan T 2013 Int J Hydrogen Energy 38 8244
[45]	Zhao W, Maeda K, Zhang F, Hisatomi T, Domen K 2014 Phys.Chem.Chem.Phys., 16 12051
[46]	Tu W, Zhou Y, Liu Q, Tian Z, Gao J, Chen X, Zhang H, Liu J, Zou Z 2012 Adv. Funct. Mater. 22 1215
[47]	Li P, Zhou Y, Tu W, Wang R, Zhang C, Liu Q, Li H, Li Z, Dai H, Wang J, Yan S, Zou Z 2013 CrystEngComm 15 9855
[48]	Wang F, Zhou Y, Li P, Li H, Tu W, Yan S, Zou Z 2014 RSC Adv. 4 43172
[49]	Habisreutinger S N, Schmidt-Mende L, Stolarczyk J K 2013 Angew. Chem. Int. Ed. 52 7372
[50]	Li P, Zhou Y, Tu W, Liu Q, Yan S, Zou Z 2013 ChemPlusChem 78 274
[51]	Inoue T, Fujishima A, Konishi S, Honda K 1979 Nature 277 637
[52]	Tu W, Zhou Y, Liu Q, Yan S, Bao S, Wang X, Xiao M, Zou Z 2013 Adv. Funct. Mater. 23 1743
[53]	Sato S, Arai T, Morikawa T, Uemura K, Suzuki T M, Tanaka H, Kajino T 2011 J. Am. Chem. Soc. 133 15240
[54]	Arai T, Sato S, Kajino T, Morikawa T 2013 Energy Environ. Sci. 6 1274
[55]	Qin S, Xin F, Liu Y, Yin X, Ma W 2011 Journal of colloid and interface science 356 257
[56]	Li P, Zhou Y, Li H, Xu Q, Meng X, Wang X, Xiao M, Zou Z 2009 Energy Environ. Sci 2 745
[57]	Sekizawa K, Maeda K, Domen K, Koike K, Ishitani O 2013 J. Am. Chem. Soc. 135 4596
[58]	Song G, Xin F, Chen J, Yin X 2014 Applied Catalysis A: General 473 90
[59]	Liu Y, Ji G, Dastageer M A, Zhu L, Wang J, Zhang B, Changa X, Gondal M A 2014 RSC Adv. 4 56961
[60]	Carey J H, Lawrence J, Tosine H M 1976 Bulletin of Environmental Contamination Toxlcology 16 697
[61]	Fujihira M, Satoh Y, Osa T 1981 Nature 293 206
[62]	Liu Z, Zhao Z G, Miyauchi M 2009 J. Phys. Chem. C 113 17132
[63]	Wang X, Li S, Ma Y, Yu H, Yu J 2011 J. Phys. Chem. C 115 14648
[64]	Ye L, Liu J, Gong C, Tian L, Peng T, Zan L 2012 ACS Catal. 2 1677
[65]	Lin H, Cao J, Luo B, Xu B, Chen S 2012 Catalysis Communications 21 91
[66]	Hou J, Yang C, Wang Z, Ji Q, Li Y, Huang G, Jiao S, Zhu H 2013 Applied Catalysis B: Environmental 142-143 579
[67]	Miyauchi M, Nukui Y, Atarashi D, Sakai E 2013 ACS Appl. Mater. Interfaces 5 9770
[68]	Chen Z, Wang W, Zhang Z, Fang X 2013 J. Phys. Chem. C 117 19346
[69]	Katsumata H, Sakai T, Suzuki T M, Kaneco S 2014 Ind. Eng. Chem. Res. 53 8018
[70]	Min Y, He G, Xu Q, Chen Y 2014 J. Mater. Chem. A. 2 1294
[71]	Cheng H, Hou J, Zhu H, Guo X M 2014 RSC Adv. 4 41622
[72]	Pu Y C, Lin W H, Hsu Y J 2015 Applied Catalysis B: Environmental 163 343

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Vol. 64, Issue 9 - 2015-05-05

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