Search

Article

x

留言板

尊敬的读者、作者、审稿人, 关于本刊的投稿、审稿、编辑和出版的任何问题, 您可以本页添加留言。我们将尽快给您答复。谢谢您的支持!

姓名
邮箱
手机号码
标题
留言内容
验证码

Color-tunableness of Er3+/Eu3+ co-doped BiOCl phosphors for near ultraviolet excitation

Li Yong-Jin Huang Yang-Bin Liu Qun Qiu Jian-Bei Yin Zhao-Yi Song Zhi-Guo

Citation:

Color-tunableness of Er3+/Eu3+ co-doped BiOCl phosphors for near ultraviolet excitation

Li Yong-Jin, Huang Yang-Bin, Liu Qun, Qiu Jian-Bei, Yin Zhao-Yi, Song Zhi-Guo
PDF
Get Citation

(PLEASE TRANSLATE TO ENGLISH

BY GOOGLE TRANSLATE IF NEEDED.)

  • In this paper, Er3+/Eu3+ co-doped BiOCl phosphors are synthesized by the conventional solid state method at 500℃, which are characterized by XRD, SEM, absorption spectra, excitation spectra and emission spectra. XRD analysis indicates that the samples exhibit pure tetragonal phase BiOCl. In SEM pictures, the samples exhibit smooth plate-like particles. The absorption spectra indicate that Er3+/Eu3+ ion dopants result in an impurity energy level, and the excitation spectra show that the sample has excellent broadband near ultraviolet (NUV)-exciting ability, which is due to the electronic transitions of the BiOCl bandgap. Under at 380 nm excitation, the emission bands located at 410 nm (2H9/2→4I15/2), 525 nm (2H11/2→4I15/2), 554 nm (4S3/2→4I15/2), 673 nm (4F9/2→4I15/2) of Er3+ ions, and 581 nm (5D0→7F0), 594 nm (5D0→7F1), 622 nm (5D0→7F2), 653 nm (5D0→7F3), 699 nm (5D0→7F4) of Eu3+ ions can be observed, respectively. Moreover, contrary to most of the Er3+/Eu3+-activated phosphors, the Er3+/Eu3+ co-doped BiOCl phosphor shows the unique and effective emission of the violet (Er3+) and far-red (Eu3+), which results from the particular structure of BiOCl crystals. The tunability in color of emitted radiation has been visualized by using chromaticity diagram on changing the doping concentration. Results show that the Er3+/Eu3+ co-doped BiOCl is a promising phosphor for near UV white LEDs.
      Corresponding author: Song Zhi-Guo, songzg@kmust.edu.cn
    • Funds: Project supported by the National Natural Science Foundation of China (Grant Nos. 61465006, 61265007).
    [1]

    Wang Y H, Zhu G, Xin S Y, Wang Q, Li Y Y, Wu Q S, Wang C, Wang X C, Ding X, Geng W Y 2015 J. Rare Earths 33 1

    [2]

    Bandi V R, Grandhe B K, Woo H, Jang K, Shin D, Yi S, Jeong J 2012 J. Alloys Compd. 538 85

    [3]

    Sun X Y, Zhang J H, Zhang X, Lu S Z, Wang X J 2007 J. Lumin. 122 955

    [4]

    Liu H L, Hao Y Y, Xu B S 2013 Acta Phys. Sin. 62 108504 (in Chinese) [刘红利, 郝玉英, 许并社 2013 物理学报 62 108504]

    [5]

    Cui H, Zhu P F, Zhu H Y, Li H D, Cui Q L 2014 Chin. Phys. B 23 057801

    [6]

    Ye S, Xiao F, Pan Y X, Ma Y Y, Zhang Q Y 2010 Materials Science and Engineering R: Reports 71 1

    [7]

    Dai Q L, Foley M E, Breshike C J, Lita A, Strouse G F 2011 J. Am. Chem. Soc. 133 15475

    [8]

    Liang Z Q, Zhao S L, Cui Y, Tian L J, Zhang J J, Xu Z 2015 Chin. Phys. B 24 037801

    [9]

    Ma C S, Jiao Q, Li L J, Zhou D C, Yang Z W, Song Z G, Qiu J B 2014 Chin. Phys. B 23 057802

    [10]

    Zhang X, Ai Z H, Jia F L, Zhang L Z 2008 J. Phys. Chem. C 112 747

    [11]

    Ye L Q, Deng K J, Xu F, Tian L H, Peng T Y, Zan L 2012 Phys. Chem. Chem. Phys. 14 82

    [12]

    Dash A, Sarkar S, Adusumalli V N, Mahalingam V 2014 Langmuir 30 1401

    [13]

    Li G Q, Zhang X C, Ding G Y, Fan C M, Liang Z H, Han P D 2013 Acta Phys. Sin. 62 127301 (in Chinese) [李国旗, 张小超, 丁光月, 樊彩梅, 梁镇海, 韩培德 2013 物理学报 62 127301]

    [14]

    Saraf R, Shivakumara C, Behera S, Dhananjaya N, Nagabhushana H 2015 RSC Adv. 5 9241

    [15]

    Li Y J, Song Z G, Li C, Wan R H, Qiu J B, Yang Z W, Yin Z Y, Yang Y, Wang X, Wang Q 2013 Ceram. Int. 39 8911

    [16]

    Li Y J, Song Z G, Li C, Wan R H, Qiu J B, Yang Z W, Yin Z Y, Yang Y, Zhou D C, Wang Q 2013 Appl. Phys. Lett. 103 231104

    [17]

    Kuang Q L, Li Y J, Qiu J B, Yin Z Y, Yang Z W, Song Z G, Wan R H, Liu Q, Zhou Y T 2015 Spectroscopy and Spectral Analysis 35 889 (in Chinese) [邝庆亮, 李永进, 邱建备, 尹兆益, 杨正文, 宋志国, 万荣华, 刘群, 周玉婷 2015 光谱学与光谱分析 35 889]

    [18]

    Li Y J, Zhao Z Y, Song Z G, Wan R H, Qiu J B, Yang Z W, Yin Z Y, Liu X E, Liu Q, Zhou Y T 2015 J. Am. Ceram. Soc. 98 2170

    [19]

    Peng S J, Li L L, Zhu P N, Wu Y Z, Srinivasan M, Mhaisalkar S G, Ramakrishna S, Yan Q Y 2013 Chem. Asian J. 8 258

    [20]

    Zhao Z Y, Dai W W 2014 Inorg. Chem. 53 13001

    [21]

    Yi J, Zhao Z Y 2014 J. Lumin. 156 205

    [22]

    Ferreira R S, Nobre S S, Granadeiro C M, Nogueira H, Carlos L D, Malta O L 2006 J. Lumin. 121 561

    [23]

    Ozawa T C, Fukuda K, Akatsuka K, Ebina Y, Sasaki T, Kurashima K, Kosuda K 2008 J. Phys. Chem. C 112 17115

  • [1]

    Wang Y H, Zhu G, Xin S Y, Wang Q, Li Y Y, Wu Q S, Wang C, Wang X C, Ding X, Geng W Y 2015 J. Rare Earths 33 1

    [2]

    Bandi V R, Grandhe B K, Woo H, Jang K, Shin D, Yi S, Jeong J 2012 J. Alloys Compd. 538 85

    [3]

    Sun X Y, Zhang J H, Zhang X, Lu S Z, Wang X J 2007 J. Lumin. 122 955

    [4]

    Liu H L, Hao Y Y, Xu B S 2013 Acta Phys. Sin. 62 108504 (in Chinese) [刘红利, 郝玉英, 许并社 2013 物理学报 62 108504]

    [5]

    Cui H, Zhu P F, Zhu H Y, Li H D, Cui Q L 2014 Chin. Phys. B 23 057801

    [6]

    Ye S, Xiao F, Pan Y X, Ma Y Y, Zhang Q Y 2010 Materials Science and Engineering R: Reports 71 1

    [7]

    Dai Q L, Foley M E, Breshike C J, Lita A, Strouse G F 2011 J. Am. Chem. Soc. 133 15475

    [8]

    Liang Z Q, Zhao S L, Cui Y, Tian L J, Zhang J J, Xu Z 2015 Chin. Phys. B 24 037801

    [9]

    Ma C S, Jiao Q, Li L J, Zhou D C, Yang Z W, Song Z G, Qiu J B 2014 Chin. Phys. B 23 057802

    [10]

    Zhang X, Ai Z H, Jia F L, Zhang L Z 2008 J. Phys. Chem. C 112 747

    [11]

    Ye L Q, Deng K J, Xu F, Tian L H, Peng T Y, Zan L 2012 Phys. Chem. Chem. Phys. 14 82

    [12]

    Dash A, Sarkar S, Adusumalli V N, Mahalingam V 2014 Langmuir 30 1401

    [13]

    Li G Q, Zhang X C, Ding G Y, Fan C M, Liang Z H, Han P D 2013 Acta Phys. Sin. 62 127301 (in Chinese) [李国旗, 张小超, 丁光月, 樊彩梅, 梁镇海, 韩培德 2013 物理学报 62 127301]

    [14]

    Saraf R, Shivakumara C, Behera S, Dhananjaya N, Nagabhushana H 2015 RSC Adv. 5 9241

    [15]

    Li Y J, Song Z G, Li C, Wan R H, Qiu J B, Yang Z W, Yin Z Y, Yang Y, Wang X, Wang Q 2013 Ceram. Int. 39 8911

    [16]

    Li Y J, Song Z G, Li C, Wan R H, Qiu J B, Yang Z W, Yin Z Y, Yang Y, Zhou D C, Wang Q 2013 Appl. Phys. Lett. 103 231104

    [17]

    Kuang Q L, Li Y J, Qiu J B, Yin Z Y, Yang Z W, Song Z G, Wan R H, Liu Q, Zhou Y T 2015 Spectroscopy and Spectral Analysis 35 889 (in Chinese) [邝庆亮, 李永进, 邱建备, 尹兆益, 杨正文, 宋志国, 万荣华, 刘群, 周玉婷 2015 光谱学与光谱分析 35 889]

    [18]

    Li Y J, Zhao Z Y, Song Z G, Wan R H, Qiu J B, Yang Z W, Yin Z Y, Liu X E, Liu Q, Zhou Y T 2015 J. Am. Ceram. Soc. 98 2170

    [19]

    Peng S J, Li L L, Zhu P N, Wu Y Z, Srinivasan M, Mhaisalkar S G, Ramakrishna S, Yan Q Y 2013 Chem. Asian J. 8 258

    [20]

    Zhao Z Y, Dai W W 2014 Inorg. Chem. 53 13001

    [21]

    Yi J, Zhao Z Y 2014 J. Lumin. 156 205

    [22]

    Ferreira R S, Nobre S S, Granadeiro C M, Nogueira H, Carlos L D, Malta O L 2006 J. Lumin. 121 561

    [23]

    Ozawa T C, Fukuda K, Akatsuka K, Ebina Y, Sasaki T, Kurashima K, Kosuda K 2008 J. Phys. Chem. C 112 17115

  • [1] Gao Wei, Dong Jun, Wang Rui-Bo, Wang Zhao-Jin, Zheng Hai-Rong. Upconversion flourescence characteristics of Er3+/Yb3+ codoped NaYF4 and LiYF4 microcrystals. Acta Physica Sinica, 2016, 65(8): 084205. doi: 10.7498/aps.65.084205
    [2] Huang Jing, Huang Yan-Tang, Wu Tian-Jiao, Huang Yu, Zhang Pei-Jin, Guo Chang-Lei. Luminescent properties of Er3+/Yb3+ co-doped oxyfluoride glass ceramic microsphere with the tapered fiber-microsphere coupling system. Acta Physica Sinica, 2014, 63(12): 127802. doi: 10.7498/aps.63.127802
    [3] Wang Sen, Zhou Ya-Xun, Dai Shi-Xun, Wang Xun-Si, Shen Xiang, Chen Fei-Fei, Xu Xing-Chen. The fabrication of Er3+/Ce3+ co-doped tellurite- bismuth glasses and the improvement of spectroscopic properties. Acta Physica Sinica, 2012, 61(10): 107802. doi: 10.7498/aps.61.107802
    [4] Qin Qing-Song, Yu Ming-Hui, Zhou Hong-Liang, Zhou Mei-Jiao, Xiang Xiao-Tian, Li Xiao-Di, Zeng Jun-Xi, Zhang Jia-Chi. Electronic structure and photoluminescence properties of Ca2GeO4 ∶Eu3+ in ultraviolet and vacuum ultraviolet region. Acta Physica Sinica, 2011, 60(6): 067802. doi: 10.7498/aps.60.067802
    [5] Liu Li-Sha, Lü Shu-Chen, Sun Jiang-Ting. Spectroscopic properties and up-conversion luminescence Er3+/Yb3+ co-doped TeO2-WO3-Bi2O3 glass. Acta Physica Sinica, 2010, 59(9): 6637-6641. doi: 10.7498/aps.59.6637
    [6] Xu Wei, Li Cheng-Ren, Chen Bao-Jiu, Feng Zhi-Qing. Optical property of Bi3+∶Eu3+-codoped borosilicate glass with Eu3+ ions as probe. Acta Physica Sinica, 2010, 59(2): 1328-1332. doi: 10.7498/aps.59.1328
    [7] Dong Li-Qiang, Huang Shi-Hua, Jia Xiao-Xia, Chen Bao-Jiu. Studies on the dynamic process of up-conversion green emission from Er3+ under square wave excitation. Acta Physica Sinica, 2009, 58(3): 2061-2066. doi: 10.7498/aps.58.2061
    [8] Dong Li-Qiang, Huang Shi-Hua, Wen Hong-Yu, Yang Yan-Min, Wang Da-Wei, Duan Xiao-Xia. Excitation processes of up-conversion green emission for Er3+ and Yb3+ codoped tellurite glass. Acta Physica Sinica, 2009, 58(12): 8617-8622. doi: 10.7498/aps.58.8617
    [9] Luo Jian-Qiao, Sun Dun-Lu, Zhang Qing-Li, Liu Wen-Peng, Gu Chang-Jiang, Wu Lu-Sheng, Yin Shao-Tang. Up-conversion luminescence in Er3+/Yb3+-codoped Gd3Sc2Ga3O12 laser crystals. Acta Physica Sinica, 2008, 57(12): 7712-7716. doi: 10.7498/aps.57.7712
    [10] Li Xu-Jie, Nie Qiu-Hua, Dai Shi-Xun, Xu Tie-Feng, Shen Xiang, Zhang Xiang-Hua. Low temperature emission characteristics of an ytterbium sensitized erbium-doped tellurite glass. Acta Physica Sinica, 2008, 57(5): 3001-3005. doi: 10.7498/aps.57.3001
    [11] Ding Jun, Yang Qiu-Hong, Tang Zai-Feng, Xu Jun, Su Liang-Bi. Spectroscopic properties of Er3+/Yb3+ co-doped transparent yttrium lanthanum oxide ceramic. Acta Physica Sinica, 2007, 56(4): 2207-2211. doi: 10.7498/aps.56.2207
    [12] Jia Xiang-Hua, Lü Shu-Chen. Spectroscopic properties of Er3+and Er3+/Yb3+ co-doped bismuth glasses. Acta Physica Sinica, 2007, 56(8): 4971-4976. doi: 10.7498/aps.56.4971
    [13] Li Jia-Cheng, Xue Tian-Feng, Fan You-Yu, Li Shun-Guang, Hu He-Fang. Effect of introducing Ce3+ on the emission properties of Er3+/Yb3+-doped TeO2-WO3-ZnO glasses. Acta Physica Sinica, 2006, 55(2): 923-928. doi: 10.7498/aps.55.923
    [14] Li Tao, Zhang Qin-Yuan, Jiang Zhong-Hong. Effects of Ce3+ ions on the spectroscopic properties of fluorophosphate glasses codoped with Er3+/Yb3+. Acta Physica Sinica, 2006, 55(8): 4298-4303. doi: 10.7498/aps.55.4298
    [15] Ding Qing-Lei, Xiao Si-Guo, Zhang Xiang-Hua, Xia Yan-Qin, Liu Zheng-Wei. The upconversion luminescent of Er3+/Yb3+ co-doped ZrO2-Al2O3 powders. Acta Physica Sinica, 2006, 55(10): 5140-5144. doi: 10.7498/aps.55.5140
    [16] Shen Xiang, Nie Qiu-Hua, Xu Tie-Feng, Gao Yuan. Investigation of spectral properties and thermal stability of Er3+/Yb3+ co-doped tungsten-tellurite glasses. Acta Physica Sinica, 2005, 54(5): 2379-2384. doi: 10.7498/aps.54.2379
    [17] Yang Zhong-Min, Zhang Qin-Yuan, Liu Yue-Hui, Jiang Zhong-Hong. Mechanism of the enhanced upconversion emissions in Yb3+/Er3+-codoped germanate-tellurite glasses. Acta Physica Sinica, 2005, 54(5): 2013-2018. doi: 10.7498/aps.54.2013
    [18] Wu Zhao-Hui, Song Feng, Liu Shu-Jing, Qin Bin, Su Jing, Tian Jian-Guo, Zhang Guang-Yin. Influence of upconversion effect on Er3+, Yb3+co-doped phosphate glass lasers. Acta Physica Sinica, 2005, 54(12): 5637-5641. doi: 10.7498/aps.54.5637
    [19] Wang Ji-You, Guo Wei-Lin, Lin Zhi-Ming, Song Guang-Zhi, Zhao Li-Juan, Zhang Cun-Zhou, Zhang Guang-Yin. . Acta Physica Sinica, 2002, 51(8): 1861-1864. doi: 10.7498/aps.51.1861
    [20] ZHAO XIAO-HONG, CHEN TING, ZHANG GUI-LAN, CHEN WEN-JU, SUN DA-LIANG, SONG YONG-YUAN, CHEN HUAN-CHU. ENERGY TRANSFER OF Eu3+ EXCITED STATES IN SBN CRYSTAL. Acta Physica Sinica, 1989, 38(11): 1896-1900. doi: 10.7498/aps.38.1896
Metrics
  • Abstract views:  5257
  • PDF Downloads:  190
  • Cited By: 0
Publishing process
  • Received Date:  23 March 2015
  • Accepted Date:  13 May 2015
  • Published Online:  05 September 2015

/

返回文章
返回