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Dye pollution,one of the most serious problems in water pollution,has attracted the attention of scientists.There are many methods,such as chemical oxidation,physical adsorption,biodegradation,photocatalysis,etc.,that have been adopted to handle the crisis of dye polultion. Compared with other strategies,photocatalysis has its unique advantages including low energy consumption,environment amicableness and high efficiency.Tungsten trioxide (WO3),a semiconductor with a band gap of 2.8 eV,has unique physical and chemical properties,and it has been applied to the area of photocatalysis to solve the problem of water pollution in recent years.However,the photocatalytic efficiency of bulk tungsten oxide fails to reach the expected.In this paper,a one-dimensional complex of tungstun trioxide and silver oxide (WO3/Ag2O) is synthesized via a simple hydrothermal method for photocatalytic degradation of methylene blue.The crystal structure,morphology and photocatalytic degradation ability towards methylene blue are characterized and analyzed via X-ray diffraction,scanning electron microscopy,transmission electron microscope,X-ray photoelectron spectroscopy,and UV-Vis spectrophotometer.Silver oxide (Ag2O),with a band gap of 1.2 eV,is found to be sensitive to visible light.The combination of tungsten trioxide and silver oxide promotes its photocatalytic efficiency dramatically under visible light illumination. Results show that WO3 nanorods in the composite possess a one-dimensional,hexagonal structure with an average length of 4μm and a diameter of 200 nm.The Ag2O attached to WO3 nanorods forms hexagonal nanoparticles and their average diameter reaches 20 nm.It is observed that WO3/Ag2O composite displays a loose structure and a high specific surface area,which provides more reactive sites.Comparing with single component,UV-Vis spectrophotometry shows that the composite has a highabsorbance in the range of visible light.The combination of tungsten trioxide and silver oxide can change the band gap of the photocatalyst whereas the photocatalytic efficiency of the composite reaches 98% in 60 min under visible light.Therefore,the synergistic effect of WO3 and Ag2O plays a vital role in enhancing the photocatalytic performance.Moreover,the stability of photocatalyst is one of the most important indicators of its recycling and long-term effectiveness,and the present WO3/Ag2O composite has good catalytic and chemical stability.This investigation proves that the combination of wide bandgap photocatalysts with visible-light sensitive metal oxide with large specific area will improve photocatalytic activity efficiently under visible light.
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Keywords:
- tungsten oxide /
- silver oxide /
- photocatalytic /
- semiconductor heterostructure
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[1] Gupta V K, Mohan D, Sharma S, Sharma M 2000 Sep. Sci. Technol. 35 2097
[2] Zhou Q 2001 Bull. Environ. Contam. Toxicol. 66 784
[3] Reddy S S, Kotaiah B, Reddy N S P 2008 Bull. Chem. Soc. Ethiopia 22 146
[4] Cao H Y, Bi H C, Xie X, Su S, Sun L T 2016 Acta Phys. Sin. 65 146802 (in Chinese) [曹海燕, 毕恒昌, 谢骁, 苏适, 孙立涛 2016 物理学报 65 146802]
[5] Sirés I, Brillas E 2012 Environ. Int. 40 212
[6] Camargo J A 1994 Environ. Int. 20 229
[7] Jiang R, Zhu H Y, Li X D, Xiao L 2009 Chem. Eng. J. 152 537
[8] Wang W, Zhu W, Xu H 2008 J. Phys. Chem. C 112 16754
[9] Jang J S, Kim H G, Lee J S 2012 Catal. Today 185 270
[10] Chen X, Burda C 2008 J Am. Chem. Soc. 130 5018
[11] Ohno T, Akiyoshi M, Umebayashi T, Asai K, Mitsui T, Matsumura M 2004 Water Sci. Technol. 49 159
[12] Arabatzis I M, Stergiopoulos T, Bernard M C, Labou D, Neophytides S G, Falaras P 2003 Appl. Catal. B: Environ. 42 187
[13] Ishibai Y, Sato J, Nishikawa T, Miyagishi S 2008 Appl. Catal. B: Environ. 79 117
[14] Li G, Zhang D Q, Yu J C 2008 Chem. Mater. 20 3983
[15] Yang J, An S, Park W, Yi G, Choi W 2004 Adv. Mater. 16 1661
[16] Bera R, Kundu S, Patra A 2015 ACS Appl. Mater. Interfaces 7 13251
[17] Zhu T, Chong M N, Chan E S 2015 ChemSuschem 7 2974
[18] Chen G S, Chen J H, Kuo J, Chen Y W, Niu H 2013 Mater. Lett. 109 217
[19] Ohashi T, Sugimoto T, Sako K, Hayakawa S, Katagiri K, Inumaru K 2015 Catal. Sci. Technol. 5 1163
[20] Li X L, Liu J F, Li Y D 2003 Inorg. Chem. 42 921
[21] Yu J, Yu H, Guo H, Li M, Mann S 2008 Small 4 87
[22] Xi G, Yue B, Cao J, Ye J H 2011 Chem. Eur. J. 17 5145
[23] Xi G, Ouyang S, Li P, Ye J H, Ma Q, Su N, Bai H, Wang C 2012 Angew. Chem. Int. Ed. 51 2395
[24] Gao X Q, Yang C, Xiao F, Zhu Y, Wang J D, Su X T 2012 Mater. Lett. 84 151
[25] Kim H, Kim H, Weon S, Moon G, Kim J H, Choi W 2016 ACS Catalysis 6 8350
[26] Robert D 2007 Catal. Today 122 20
[27] Sheng H, Ji H W, Ma W, Chen C, Zhao J 2013 Angew. Chem. Int. Ed. 52 9686
[28] Strukul G 1992 Catalytic Oxidations with Hydrogen Peroxide as Oxidant(Vol. 9) (Dordrecht: Kluwer Academic Publishers) p101
[29] Arai T, Yanagida M, Konishi Y, Iwasaki Y, Sugihara H, Sayama K 2007 J. Phys. Chem. C 111 7574
[30] Irie H, Miura S, Kamiya K, Hashimoto K 2008 Chem. Phys. Lett. 457 202
[31] Arai T, Horiguchi M, Yanagida M, Gunji T, Sugihara H, Sayama K 2008 Chem. Commun. 43 5565
[32] Abe R, Takami H, Murakami N, Ohtani B 2008 J. Am. Chem. Soc. 130 7780
[33] Xiang Q, Meng G F, Zhao H B, Zhang Y, Li H, Ma W J, Xu J Q 2010 J. Phys. Chem. C 114 2049
[34] Arai T, Yanagida M, Konishi Y, Iwasaki Y, Sugihara H, Sayama K 2008 Catal. Commun. 9 1254
[35] Tang Y, Wee P, Lai Y, Wang X, Gong D, Kanhere P D 2012 J. Phys. Chem. C 116 2772
[36] Zhou W J, Liu H, Wang J Y, Liu D, Du G, Cui J 2010 ACS Appl. Mater. Interfaces 2 2385
[37] Sarkar D, Ghosh C K, Mukherjee S, Chattopadhyay K K 2013 ACS Appl. Mater. Interfaces 5 331
[38] Chen F T, Liu Z, Liu Y, Fang P, Dai Y 2013 Chem. Eng. J. 221 283
[39] Fang F, Li Q, Shang J K 2011 Surf. Coat. Technol. 205 2919
[40] Miao X, Lei H, Dong S J 2013 ACS Appl. Mater. Interfaces 5 12533
[41] Huang Z F, Song J J, Pan L, Zhang X W, Wang L, Zou J J 2015 Adv. Mater. 27 5309
[42] Li Y J, Xue Y J, Tian J, Song X J 2017 Sol. Energy Mater. Sol. Cells 168 100
[43] Lu Y Y, Liu G, Zhang J, Feng Z C, Li C, Li Z 2016 Chin. J. Catal. 37 349
[44] Reiss P, Protière M, Li L 2009 Small 5 154
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