Research progress of materials and devices for room-temperature Na-ion batteries

Lu Ya-Xiang; Zhao Cheng-Long; Rong Xiao-Hui; Chen Li-Quan; Hu Yong-Sheng

doi:10.7498/aps.67.20180847

Abstract

Among various electrochemical energy storage technologies, room-temperature Na-ion batteries (NIBs) are regarded as ideal candidates in large-scale energy storage field due to advantages of abundant resources and low material cost in addition to their characteristics of high energy density and long cycle life. Since 2011, the Institute of Physics, Chinese Academy of Sciences (IOP-Chinese Academy of Sciences) has devoted to developing the cost-effective and environmental-safe NIBs, and attained many original achievements in the research of cathode, anode and electrolyte materials, and also developed Na-ion pouch cells with capacities of 1 Ah. For instance, the highly reversible Cu2+/Cu3+ redox was discovered for the first time and the low cost Na-Cu-Fe-Mn-O layered oxide cathodes have been designed accordingly; the anthracite-derived carbon anodes have been exploited via a simple one-step carbonization process with a high performance-to-price ratio; a new type of NaFSI sodium salt was first used in the non-aqueous carbonate electrolyte to significantly improve the performance of electrode materials, etc. This review summarizes the important progress and breakthroughs achieved in IOP-Chinese Academy of Sciences for materials and devices of NIBs. We hope that these contributions conduce to realizing the industrialization of NIBs.

Keywords:

Authors and contacts

1.
Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China

Corresponding author: Hu Yong-Sheng, yshu@iphy.ac.cn

Funds: Project supported by the National Key RD Program of China (Grant No. 2016YFB0901500) and the National Natural Science Foundation of China (Grant Nos. 51725206, 51421002).

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[37]	Mu L, Lu Y, Wu X, Ding Y, Hu Y S, Li H, Chen L, Huang X 2017 Green Energy Environ. 3 63
[38]	Wu X, Jin S, Zhang Z, Jiang L, Mu L, Hu Y S, Li H, Chen X, Armand M, Chen L, Huang X 2015 Sci. Adv. 1 e1500330
[39]	Jian Z, Han W, Lu X, Yang H, Hu Y S, Zhou J, Zhou Z, Li J, Chen W, Chen D, Chen L 2013 Adv. Energy Mater. 3 156
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[43]	Ma Q, Liu J, Qi X, Rong X, Shao Y, Feng W, Nie J, Hu Y S, Li H, Huang X, Chen L, Zhou Z 2017 J. Mater. Chem. A 5 7738

Cited By

[1]	Zhao L, Hu Y S, Li H, Chen L Q 2011 Chinese Patent ZL2011103263772 (in Chinese)[赵亮, 胡勇胜, 李泓, 陈立泉 2011 中国专利 ZL2011103263772]
[2]	Hu Y S, Wang Y S, Xu S Y, Li H, Chen L Q 2012 Chinese Patent ZL2012101071363 (in Chinese)[胡勇胜, 王跃生, 徐淑银, 李泓, 陈立泉 2012 中国专利 ZL2012101071363]
[3]	Hu Y S, Wang Y S, Liu P, Chen L Q 2012 Chinese Patent ZL2012101765232 (in Chinese)[胡勇胜, 王跃生, 刘品, 陈立泉 2012 中国专利 ZL2012101765232]
[4]	Hu Y S, Wang Y S, Xu S Y, Li H, Chen L Q 2012 Chinese Patent ZL2012102721231 (in Chinese)[胡勇胜, 王跃生, 徐淑银, 李泓, 陈立泉 2012 中国专利 ZL2012102721231]
[5]	Hu Y S, Mu L Q, Chen L Q, Huang X J 2014 Chinese Patent ZL201410490257X (in Chinese)[胡勇胜, 穆林沁, 陈立泉, 黄学杰 2014 中国专利 ZL201410490257X]
[6]	Hu Y S, Xu S Y, Wang Y S, Li Y M, Chen L Q, Huang X J 2014 Chinese Patent ZL2014101955310 (in Chinese)[胡勇胜, 徐淑银, 王跃生, 李云明, 陈立泉, 黄学杰 2014 中国专利 ZL2014101955310]
[7]	Hu Y S, Wu X Y, Mu L Q, Ding Y J, Chen L Q, Huang X J 2014 Chinese Patent ZL2014102450296 (in Chinese)[胡勇胜, 吴晓燕, 穆林沁, 丁月君, 陈立泉, 黄学杰 2014 中国专利 ZL2014102450296]
[8]	Hu Y S, Li Y M, Xu S Y, Wang Y S, Chen L Q, Huang X J 2014 Chinese Patent ZL2014103425412 (in Chinese)[胡勇胜, 李云明, 徐淑银, 王跃生, 陈立泉, 黄学杰 2014 中国专利 ZL2014103425412]
[9]	Hu Y S, Xu S Y, Li Y M, Chen L Q, Huang X J 2014 Chinese Patent ZL2014103479357 (in Chinese)[胡勇胜, 徐淑银, 李云明, 陈立泉, 黄学杰 2014 中国专利 ZL2014103479357]
[10]	Hu Y S, Wang Y S, Chen L Q, Huang X J 2014 Chinese Patent ZL2014103642414 (in Chinese)[胡勇胜, 王跃生, 陈立泉, 黄学杰 2014 中国专利 ZL2014103642414]
[11]	Hu Y S, Mu L Q, Chen L Q 2014 Chinese Patent ZL2014105498969 (in Chinese)[胡勇胜, 穆林沁, 陈立泉 2014 中国专利 ZL2014105498969]
[12]	Hu Y S, Zhang Z Z, Xu K Q, Chen L Q, Huang X J 2014 Chinese Patent ZL2014107729525 (in Chinese)[胡勇胜, 章志珍, 徐凯琪, 陈立泉, 黄学杰 2014 中国专利 ZL2014107729525]
[13]	Hu Y S, Li Y M, Chen L Q 2015 Chinese Patent ZL2015100300759 (in Chinese)[胡勇胜, 李云明, 陈立泉 2015 中国专利 ZL2015100300759]
[14]	Hu Y S, Wang Y S, Chen L Q 2015 Chinese Patent ZL2015101700142 (in Chinese)[胡勇胜, 王跃生, 陈立泉 2015 中国专利 ZL2015101700142]
[15]	Hu Y S, Li Y M, Chen L Q 2015 Chinese Patent ZL2015107086328 (in Chinese)[胡勇胜, 李云明, 陈立泉 2015 中国专利 ZL2015107086328]
[16]	Hu Y S, Wang Y S, Liu P, Chen L Q, Huang X J 2015 Chinese Patent ZL2015109471194 (in Chinese)[胡勇胜, 王跃生, 刘品, 陈立泉, 黄学杰 2015 中国专利 ZL2015109471194]
[17]	Hu Y S, Li Y M, Xu S Y, Wang Y S, Chen L Q, Huang X J 2016 Japanese Patent JP2016-537294 A
[18]	Hu Y S, Mu L Q, Chen L Q 2017 US Patent US9 728 780 B2
[19]	Mu L, Xu S, Li Y, Hu Y S, Li H, Chen L, Huang X 2015 Adv. Mater. 27 6928
[20]	Li Y, Yang Z, Xu S, Mu L, Gu L, Hu Y S, Li H, Chen L 2015 Adv. Sci. 2 1500031
[21]	Mu L Q, Qi X G, Hu Y S, Li H, Chen L Q, Huang X J 2016 Energy Storage Sci. Tech. 5 324 (in Chinese)[穆林沁, 戚兴国, 胡勇胜, 李泓, 陈立泉, 黄学杰 2016 储能科学与技术 5 324]
[22]	Wang Y, Liu J, Lee B, Qiao R, Yang Z, Xu S, Yu X, Gu L, Hu Y S, Yang W, Kang K, Li H, Yang X Q, Chen L, Huang X 2015 Nat. Commun. 6 6401
[23]	Xu S, Wang Y, Ben L, L Y, Song N, Yang Z, Li Y, Mu L, Yang H T, Gu L, Hu Y S, Li H, Cheng Z H, Chen L, Huang X 2015 Adv. Energy Mater. 5 1501156
[24]	Wang Y, Mu L, Liu J, Yang Z, Yu X, Gu L, Hu Y S, Li H, Yang X Q, Chen L, Huang X 2015 Adv. Energy Mater. 5 1501005
[25]	Rong X, Liu J, Hu E, Liu Y, Wang Y, Wu J, Yu X, Page K, Hu Y S, Yang W, Li H, Yang X Q, Chen L, Huang X 2017 Joule 2 125
[26]	Li Y, Xu S, Wu X, Yu J, Wang Y, Hu Y S, Li H, Chen L, Huang X 2015 J. Mater. Chem. A 3 71
[27]	Li Y, Hu Y S, Titirici M M, Chen L, Huang X 2016 Adv. Energy Mater. 6 1600659
[28]	Li H B, Shen F, Luo W, Dai J Q, Han X G, Chen Y N, Yao Y G, Zhu H L, Fu K, Hitz E, Hu L B 2016 ACS Appl. Mater. Inter. 8 2204
[29]	Li Y, Hu Y S, Qi X, Rong X, Li H, Huang X, Chen L 2016 Energy Storage Mater. 5 191
[30]	Zhao L, Pan H L, Hu Y S, Li H, Chen L Q 2012 Chin. Phys. B 21 028201
[31]	Yu X, Pan H, Wan W, Ma C, Bai J, Meng Q, Ehrlich S N, Hu Y S, Yang X Q 2013 Nano Lett. 13 4721
[32]	Sun Y, Zhao L, Pan H, Lu X, Gu L, Hu Y S, Li H, Armand M, Ikuhara Y, Chen L, Huang X 2013 Nat. Commun. 4 1870
[33]	Wang Y, Yu X, Xu S, Bai J, Xiao R, Hu Y S, Li H, Yang X Q, Chen L, Huang X 2013 Nat. Commun. 4 2365
[34]	Wang Y, Xiao R, Hu Y S, Avdeev M, Chen L 2015 Nat. Commun. 6 6954
[35]	Zhao C, Avdeev M, Chen L, Hu Y S 2018 Angew. Chem. Int. Ed. https://doi.org/10.1002/anie.201801923
[36]	Zhao L, Zhao J, Hu Y S, Li H, Zhou Z, Armand M, Chen L 2012 Adv. Energy Mater. 2 962
[37]	Mu L, Lu Y, Wu X, Ding Y, Hu Y S, Li H, Chen L, Huang X 2017 Green Energy Environ. 3 63
[38]	Wu X, Jin S, Zhang Z, Jiang L, Mu L, Hu Y S, Li H, Chen X, Armand M, Chen L, Huang X 2015 Sci. Adv. 1 e1500330
[39]	Jian Z, Han W, Lu X, Yang H, Hu Y S, Zhou J, Zhou Z, Li J, Chen W, Chen D, Chen L 2013 Adv. Energy Mater. 3 156
[40]	Zhang Z, Zhang Q, Shi J, Chu Y S, Yu X, Xu K, Ge M, Yan H, Li W, Gu L, Hu Y S, Li H, Yang X Q, Chen L, Huang X 2017 Adv. Energy Mater. 7 1601196
[41]	Qi X, Ma Q, Liu L, Hu Y S, Li H, Zhou Z, Huang X, Chen L 2016 ChemElectroChem 3 1741
[42]	Ma Q, Hu Y S, Li H, Chen L, Huang X, Zhou Z 2018 Acta Phys.-Chim. Sin. 34 213 (in Chinese)[马强, 胡勇胜, 李泓, 陈立泉, 黄学杰, 周志彬 2018 物理化学学报 34 213]
[43]	Ma Q, Liu J, Qi X, Rong X, Shao Y, Feng W, Nie J, Hu Y S, Li H, Huang X, Chen L, Zhou Z 2017 J. Mater. Chem. A 5 7738

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Vol. 67, Issue 12 - 2018-06-20

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